A 300-kyr record of aridity and wind strength in southwestern Africa: inferences from grain-size distributions of sediments on Walvis Ridge, SE Atlantic

The terrigenous fraction of sediments recovered from Walvis Ridge, SE Atlantic Ocean, reveals a history of southwestern African climate of the last 300 kyr. End-member modelling of a data set of grain-size distributions (n=428) results in three end members. The two coarsest end members are interpreted as eolian dust, the third end member as hemipelagic mud. The ratio of the two eolian end members reflects the eolian grain size and is attributed to the intensity of the SE trade winds. Trade winds were intensified during glacials compared to interglacials. Changes in the ratio of the two eolian end members over the hemipelagic one are interpreted as variations in southwestern African aridity. Late Quaternary southwestern African climate was relatively arid during the interglacial stages and relatively humid during the glacial stages, owing to meridional shifts in the atmospheric circulation system. During glacials the polar front shifted equatorward, resulting in a northward displacement of the zone of westerlies, causing increased rainfall in southwestern Africa. The equatorward shift of the polar front is coupled with an increase of the meridional pressure gradient, leading to enhanced atmospheric circulation and increased trade-wind intensity.     

可持续发展背景下区域旅游业竞争力评价研究

如何评价区域旅游业竞争力水平是区域旅游业进行旅游规划和提高竞争力水平的基础和出发点.在可持续发展背景下以竞争力理论、旅游系统理论等为依据,从旅游业基础竞争力、竞争业绩、竞争潜力3个层面构建了区域旅游业竞争力评价指标体系,运用层次分析法来确定指标权重,在此基础上以我国30个省级行政区为研究对象进行了应用,对我国区域旅游业竞争力水平进行了较为深入的分析.提出的指标体系和层次分析法可以为区域旅游业竞争力研究提供一定的借鉴.     

Application of a mixing-ratios based formulation to model mixing-driven dissolution experiments

We address the question of how one can combine theoretical and numerical modeling approaches with limited measurements from laboratory flow cell experiments to realistically quantify salient features of complex mixing-driven multicomponent reactive transport problems in porous media. Flow cells are commonly used to examine processes affecting reactive transport through porous media, under controlled conditions. An advantage of flow cells is their suitability for relatively fast and reliable experiments, although measuring spatial distributions of a state variable within the cell is often difficult. In general, fluid is sampled only at the flow cell outlet, and concentration measurements are usually interpreted in terms of integrated reaction rates. In reactive transport problems, however, the spatial distribution of the reaction rates within the cell might be more important than the bulk integrated value. Recent advances in theoretical and numerical modeling of complex reactive transport problems [De Simoni M, Carrera J, Sanchez-Vila X, Guadagnini A. A procedure for the solution of multicomponent reactive transport problems. Water Resour Res 2005;41:W11410. doi: 10.1029/2005WR004056, De Simoni M, Sanchez-Vila X, Carrera J, Saaltink MW. A mixing ratios-based formulation for multicomponent reactive transport. Water Resour Res 2007;43:W07419. doi: 10.1029/2006WR005256] result in a methodology conducive to a simple exact expression for the space–time distribution of reaction rates in the presence of homogeneous or heterogeneous reactions in chemical equilibrium. The key points of the methodology are that a general reactive transport problem, involving a relatively high number of chemical species, can be formulated in terms of a set of decoupled partial differential equations, and the amount of reactants evolving into products depends on the rate at which solutions mix. The main objective of the current study is to show how this methodology can be used in conjunction with laboratory experiments to properly describe the key processes that occur in a complex, geochemically-active system under chemical equilibrium conditions. We model three CaCO₃ dissolution experiments reported in Singurindy et al. [Singurindy O, Berkowitz B, Lowell RP. Carbonate dissolution and precipitation in coastal environments: Laboratory analysis and theoretical consideration. Water Resour Res 2004;40:W04401. doi: 10.1029/2003WR002651, Singurindy O, Berkowitz B, Lowell RP. Correction to Carbonate dissolution and precipitation in coastal environments: laboratory analysis and theoretical consideration. Water Resour Res 2005;41:W11701. doi: 10.1029/2005WR004433], in which saltwater and freshwater were mixed in different proportions. The integrated reaction rate within the cell estimated from the experiments are modeled independently by means of (a) a state-of-the-art reactive transport code, and (b) the uncoupled methodology of [12, 13], both of which use dispersivity as a single, adjustable parameter. The good agreement between the results from both methodologies demonstrates the feasibility of using simple solutions to design and analyze laboratory experiments involving complex geochemical problems.     

Sm–Nd isotopic mapping of lithospheric growth and stabilization in the eastern Kaapvaal craton

Whole-rock Sm–Nd isotope systematics of 79 Archean granitoids from the eastern Kaapvaal craton, southern Africa, are used to delineate lithospheric boundaries and to constrain the timescale of crustal growth, assembly and geochemical differentiation c. 3.66–2.70 Ga. Offsets in ε_Nd values for 3.2–3.3 Ga granitoids across the Barberton greenstone belt (BGB) are consistent with existing models for c. 3.23 Ga accretion of newly formed lithosphere north of the BGB onto pre-existing c. 3.66 Ga lithosphere south of the BGB along a doubly verging subduction margin. The Nd isotopic signature of c. 3.3–3.2 Ga magmatic rocks show that significant crustal growth occurred during subduction–accretion. After c. 3.2 Ga, however, the Nd signature of intrusive rocks c. 3.1 and 2.7 Ga is dominated by intracrustal recycling rather than by new additions from the mantle, signalling cratonic stability.     

Petrographic,fluid inclusion and isotopic study of the Dikulushi Cu–Ag deposit,Katanga (D.R.C.): implications for exploration

The Dikulushi Cu–Ag vein-type deposit is located on the Kundelungu Plateau, in the southeastern part of the Democratic Republic of Congo (D.R.C.). The Kundelungu Plateau is situated to the north of the Lufilian Arc that hosts the world-class stratiform Cu–Co deposits of the Central African Copperbelt. A combined petrographic, fluid inclusion and stable isotope study revealed that the mineralisation at Dikulushi developed during two spatially and temporally distinct mineralising episodes. An early Cu–Pb–Zn–Fe mineralisation took place during the Lufilian Orogeny in a zone of crosscutting EW- and NE-oriented faults and consists of a sequence of sulphides that precipitated from moderate-temperature, saline H₂O–NaCl–CaCl₂-rich fluids. These fluids interacted extensively with the country rocks. Sulphur was probably derived from thermochemical reduction of Neoproterozoic seawater sulphate. Undeformed, post-orogenic Cu–Ag mineralisation remobilised the upper part of the Cu–Pb–Zn–Fe mineralisation in an oxidising environment along reactivated and newly formed NE-oriented faults in the eastern part of the deposit. This mineralisation is dominated by massive Ag-rich chalcocite that precipitated from low-temperature H₂O–NaCl–KCl fluids, generated by mixing of moderate- and low-saline fluids. The same evolution in mineralisation assemblages and types of mineralising fluids is observed in three other Cu deposits on the Kundelungu Plateau. Therefore, the recognition of two distinct types of (vein-type) mineralisation in the study area has a profound impact on the exploration in the Kundelungu Plateau region. The identification of a Cu–Ag type mineralisation at the surface could imply the presence of a Cu–Pb–Zn–Fe mineralisation at depth.     

Methods and code for ‘classical’ age-modelling of radiocarbon sequences

Age–depth models form the backbone of most palaeoenvironmental studies. However, procedures for constructing chronologies vary between studies, they are usually not explained sufficiently, and some are inadequate for handling calibrated radiocarbon dates. An alternative method based on importance sampling through calibrated dates is proposed. Dedicated R code is presented which works with calibrated radiocarbon as well as other dates, and provides a simple, systematic, transparent, documented and customizable alternative. The code automatically produces age–depth models, enabling exploration of the impacts of different assumptions (e.g., model type, hiatuses, age offsets, outliers, and extrapolation).     

Efficiency of different mesh sizes for isolating fossil chironomids for stable isotope and radiocarbon analyses

We examined the effects of sieving with different mesh sizes on the efficiency of processing fossil chironomids from lake sediments for isotope analyses. Results obtained for three different sediments indicate that each of the studied sieve fractions (100–150, 150–200, 200–250, 250–300, >300 μm) contain a similar proportion of the overall mass of chironomid fossils in a sample. However, the sorting time needed to separate chironomids from other sieve residue is disproportionately large for smaller mesh sizes. Employing sieves with a 200-μm rather than the 100-μm mesh commonly used for standard palaeoecological analyses of fossil chironomids decreased processing time for a given mass of fossils by 30–58% in our study. For optimizing the efficiency of chironomid sample processing for stable isotope and radiocarbon analysis we therefore recommend a 200-μm mesh size sieve, although the sorting of all >100-μm fractions may be necessary in sediments with low chironomid abundances. Excluding certain small taxa from isotope analysis, may structurally bias isotope values of samples. Therefore, further studies on taxon-specific isotope analysis are required to quantify these effects.     

Phytoplankton,protozooplankton and nutrient dynamics in the Bornholm Basin (Baltic Sea) in 2002–2003 during the German GLOBEC Project

From March 2002 to until April 2003 we investigated the seasonal nutrient and phytoplankton dynamics in the central Bornholm Basin (Baltic Sea) within the framework of the German GLOBEC Project. We choose a nested approach consisting of vertical fluorescence profiles, phytoplankton counts and nutrient analyses. The Fluoroprobe (MultiProbe, BBE Moldaenke) is capable of distinguishing four algal groups (Cryptophyceae, Cyanophyceae, Chlorophyceae, Bacillariophyceae + Dinophyceae). Winter nutrient concentrations were about 5 μM NO₃ and 0.5 μM PO₄ in the central Basin. The spring phytoplankton bloom was dominated by the diatom Skeletonema sp. and reached a maximum of about 270 μg C/l before the onset of the seasonal stratification. Protozooplankton was dominated by the Mesodinium rubrum (a phototrophic ciliate = Myrionecta rubra) and reached a maximum biomass of about 200–300 μg C/l about 2 weeks after the demise of the diatom spring bloom. During summer, the water column was stratified and a subsurface maximum developed near the thermocline consisting of Bacillariophyceae, Cryptophycea and other phototrophic flagellates. Phytoplankton and protozooplankton biomass was generally low. Nutrient concentrations point towards a nitrogen limitation during this period. The stratification period ended during September and surface nutrient concentrations increased again. Protozooplankton reached a second maximum during September. With the Fluoroprobe small scale structures in the plankton community could be detected like a subsurface Cryptophyceae maximum near the thermocline that however, could not be confirmed by cell counts. The chlorophyll a estimate of the Fluoroprobe was in good agreement with the phytoplankton biomass estimated from counts. We conclude that only by combining modern sensing technology with microscopy, the small-scale dynamics and taxonomic spectrum of the plankton can be fully captured.     

Water transport at subtidal frequencies in the Marsdiep inlet

Long-term time series of subtidal water transport in the 4-km wide Marsdiep tidal inlet in the western Dutch Wadden Sea have been analysed. Velocity data were obtained between 1998 and the end of 2002 with an acoustic Doppler current profiler that was mounted under the hull of the ferry ‘Schulpengat’. Velocities were integrated over the cross-section and low-pass filtered to yield subtidal water transport. A simple analytical model of the connected Marsdiep and Vlie tidal basins was extended to include wind stress and water-level and density gradients and applied to the time series of subtidal water transport. In accordance with the observations, the model calculates a mean throughflow from the Vlie to the Marsdiep basin. The mean water transport through the Marsdiep inlet consists of an export due to tidal stresses and freshwater discharge and an import due to southwesterly winds. In contrast, the variability in the subtidal water transport is mainly governed by wind stress. In particular, southwesterly winds that blow along the main axis of the Marsdiep basin force a throughflow from the Marsdiep to the Vlie basin, whereas northwesterly winds that blow along the main axis of the Vlie basin force a smaller mean water transport in the opposite direction. The contribution of remote sea-level change to the water transport, or coastal sea-level pumping, has been found to be much smaller than the contribution of local wind stress.     

Fast reconnaissance of carbonate dissolution based on the size distribution of calcareous ooze on Walvis Ridge, SE Atlantic Ocean

We present a new index of carbonate fragmentation based on the size distribution of bulk sediments in core MD962094 from Walvis Ridge (SE Atlantic Ocean). The carbonate fragmentation index is constructed by taking a ratio of the two coarsest fractions in the grain size distributions of the bulk calcareous ooze. The coarsest two fractions (25–90 μm and >90 μm) of the bulk sediments consist primarily of complete shells and fragments of adult foraminifera shells, and juvenile foraminifera shells and fragments, respectively. The ratio of the proportions of the two fractions is interpreted as a measure of fragmentation of the foraminifera shells caused by carbonate dissolution. Downcore changes in our carbonate fragmentation index compare very well with those in the coarse-carbonate fragmentation index in sediments from a nearby core on Walvis Ridge. The latter commonly used fragmentation index is defined as a ratio of foraminifera fragments over whole foraminifera in the >150-μm fraction as seen with a light microscope. Fragmentation is relatively high during glacial stages and relatively low during interglacial stages during the last 300 kyr, caused by the combined effect of wind-driven upwelling of corrosive water and increased production of organic matter, decreasing the preservation potential of carbonates both during and after deposition. The carbonate fragmentation index we present here provides a precise and fast method to establish a downcore fragmentation record. It can be applied to bulk sediments that are carbonate-rich (CaCO₃>68%) and to all other deep-marine sediments of which the grain size distribution of the carbonate-free fraction is available.