Global travertine deposition modulated by oscillations in climate

Travertine deposits are important records of past fluid flow in the Earth's crust, and document fluid migration through both tectonic activity and changes in climate. While many studies hint at possible relationships between travertine formation and global climate, none have investigated these connections on a global scale. Here we compile 1649 published travertine ages from six continents to test the hypothesis that global and/or regional changes in climate regulate travertine deposition. Peaks in bedded travertine ages occur with main frequencies that correspond to 100‐kyr changes in global climate, where most peaks occur during glacial terminations or interglacial periods, including a large peak that coincides with the Early Holocene climatic optimum. Time–series analysis also suggests a possible connection with 41‐kyr obliquity cycles. At regional scales, many peaks also correspond with local times of high precipitation or wet conditions. This can be attributed to higher groundwater recharge rates, providing the necessary water to form travertine. Many bedded travertine‐depositing systems may therefore be water‐limiting and sufficient CO₂ may be present even during times of no travertine deposition. Exceptions to this conclusion are banded vein travertine deposits, which typically form during times of dry climate when water tables are low. Copyright © 2019 John Wiley & Sons, Ltd.     

海水中微量元素无机离子交换动力学研究——液膜递进模型理论 Ⅰ.天然海水条件下

最近十几年来,海水物理化学中关于海水的化学热力学研究已较广泛地开展,并已有一些重要的研究结果报导。但是,关于海水中化学动力学的研究,至今却基本上仍属空白。然而这正是海洋中许多化学过程(特别像海水化学资源开发、海洋污染和防治等实践性比较强的领域中)要解决的关键问题。本文是我们从事这一方面研究工作的第一篇报导,讨论的内容是海洋中最重要的过程之一——无机离子交换过程。     

海洋动物体石油烃污染评价标准参考值的探讨

目前,国内外尚无颁布任何海洋生物石油污染评价标准,为了满足海洋生物石油污染评价的需要,本文采用综合分析与毒理学分析相结合的方法,探讨和提出了海洋动物石油污染评价标准参考值,海洋鱼类、贝类和甲壳类的石油污染评价标准参考值（干重）分别为１５、７０ 和２５ ｍ ｇ／ｋｇ。     

Mineralogical, chemical, and crystallographic properties of supergene jarosite-group minerals from the Xitieshan Pb-Zn sulfide deposit, northern Tibetan Plateau, China

Supergene jarosite-group minerals are widespread in weathering profiles overlying Pb-Zn sulfide ores at Xitieshan, northern Tibetan Plateau, China. They consist predominantly of K-deficient natrojarosite, with lesser amounts of K-rich natrojarosite and plumbojarosite. Electron microprobe (EMP) analyses, scanning electron microcopy (SEM) investigation, and X-ray mapping reveal that the jarosite-group minerals are characterized by spectacular oscillatory zoning composed of alternating growth bands of K-deficient and K-bearing natrojarosite (K₂O >1 wt.%). Plumbojarosite, whenever present, occurs as an overgrowth in the outermost bands, and its composition can be best represented by K_0.29Na_0.19Pb_0.31Fe_2.66Al_0.22(SO₄)_1.65(PO₄)_0.31(AsO₄)_0.04(OH)_7.37. The substitution of monovalent for divalent cations at the A site of plumbojarosite is charge balanced by the substitution of five-valent for six-valent anions in XO₄ at the X site. Thermogravimetric analysis (TGA) of representative samples reveal mass losses of 11.46 wt.% at 446.6 °C and 21.42 wt.% at 683.4 °C due to dehydroxylation and desulfidation, respectively. TGA data also indicate that the natrojarosite structure collapses at 446.6 °C, resulting in the formation of NaFe(SO₄)₂ and minor hematite. The decomposition products of NaFe(SO₄)₂ are hematite and Na₂SO₄. Powder X-ray diffraction (XRD) analyses show that the jarosite-group minerals have mean unit-cell parameters of a?=?7.315 Å and c?=?016.598 Å. XRD and EMP data support the view that substitutions of Na for K in the A site and full Fe occupancy in the B site can considerably decrease the unit-cell parameter c, but only slightly increase a. The results from this study suggest that the observed oscillatory zoning of jarosite-group minerals at Xitieshan resulted mainly from substitutions of K for Na at the A site and P for S at the X site.     

鄂尔多斯西南缘前陆盆地沉降和沉积过程模拟

本文将东祁东逆冲带与鄂尔多斯西南缘晚三叠世前陆盆地相结合，研究了逆冲带内部变形特征，前陆盆地中层序地层格架特征及其反映的盆缘构造性质和幕式逆作作用。     

南海东北部冷泉区沉积物中有机质来源的生物标志物分析与环境指示意义

Multi-biomarker indexes were analyzed for two piston cores from potential cold seep areas of the South China Sea off southwestern Taiwan. Total organic carbon(TOC) normalized terrestrial(n-alkanes) and marine(brassicasterol, dinosterol, alkenones and iso-GDGTs) biomarker contents and ratios(TMBR, 1/Pmar-aq, BIT) were used to evaluate the contributions of terrestrial and marine organic matter(TOM and MOM respectively) to the sedimentary organic matter, indicating that MOM dominated the organic sources in Core MD052911 and the sedimentary organic matter in Core ORI-_(86)0-22 was mainly derived from terrestrial inputs, and different morphologies were the likely reason for TOM percentage differences. BIT results suggested that river-transported terrestrial soil organic matter was not a major source of TOM of sedimentary organic matter around these settings.Diagnostic biomarkers for methane-oxidizing archaea(MOA) were only detected in one sample at 172 cm depth of Core ORI-_(86)0-22, with abnormally high iso-GDGTs content and Methane Index(MI) value(0.94). These results indicated high anaerobic oxidation of methane(AOM) activities at or around 172 cm in Core ORI-_(86)0-22.However in Core MD052911, MOA biomarkers were not detected and MI values were lower(0.19–0.38), indicated insignificant contributions of iso-GDGTs from methanotrophic archaea and the absence of significant AOM activities. Biomarker results thus indicated that the discontinuous upward methane seepage and insufficient methane flux could not induce high AOM activities in our sampling sites. In addition, the different patterns of TEX_(86) and U_(37)~(K′) temperature in two cores suggested that AOM activities affected TEX_(86)37 temperature estimates with lower values in Core ORI-_(86)0-22, but not significantly on TEX_(86) temperature estimates in Core MD052911.     

煤层冲刷带预测方法评述

介绍了沉积分析法、矿井物探法以及地质统计法三种煤层冲刷带预测方法.实例证明,根据煤矿生产的具体情况,选择一种或综合运用几种方法,能较好地预测冲刷带的位置和范围.     

东北及内蒙古东部地区显生宙构造演化的有关问题

以国家油气资源战略选区项目研究成果为基础,结合近年来该区积累的大量区域地质调查资料和已发表的数据,对东北及内蒙古东部地区早古生代以来的大地构造性质及其演化进行综合对比分析。东北地区晚古生代以来的构造演化以稳定的大陆地块为主体,而非两大板块间多岛洋演化形成的造山带。东北地区的各地块均具有前寒武纪—早前寒武纪、甚至是太古宙的古老基底,它们在早古生代早期(490～510Ma)同时遭受了区域变质作用和花岗质岩浆侵入。350～450Ma,各地块均处于相对稳定的构造环境,以普遍缺失这一时期的花岗质岩浆活动记录为标志。从早古生代晚期开始,东北及内蒙古东部地区至少已存在2个早古生代早期固结的微陆块,即额尔古纳—兴安微陆块和松嫩—佳木斯微陆块,这2个微陆块向北分别与俄罗斯境内的额尔古纳微陆块和布列亚微陆块相连。二者在早石炭世沿北北东向展布的开鲁—嫩江—黑河—诺拉—索霍提(Nora-Soukhotin)一线碰撞拼合,形成统一的东北亚晚古生代大陆板块。西拉沐伦河断裂西端被北北东向构造所截,向东延至开鲁—嫩江断裂,并没有延伸到松辽盆地内,说明西拉沐伦河断裂可能与开鲁—嫩江碰撞带的形成有关。从晚石炭世开始,东北亚大陆板块整体处于伸展构造背景,至少在中国境内具有北陆南海的构造-沉积古地理格局,早期发育以火山岩为主的断陷盆地,到中二叠世演化成一个规模巨大的海相沉积盆地。中生代以来,东北地区的构造体制转换及物质成分演化不仅仅是古亚洲洋构造域和西太平洋构造域叠加转换的结果,蒙古—鄂霍茨克构造域的演化对该区现今构造体制的形成也具有重要影响。地质和地球物理综合证据显示,大兴安岭北部的得尔布干断裂、内蒙古中部的贺根山断裂和黑龙江省东部的跃进山断裂可能并不是具有一定深度规模的构造分区断裂。东北地区的中、新生代盆地之下并非都是变质结晶基底,而是存在一个规模巨大的晚古生代海相沉积盆地。     

山东新城金矿床的叠加晕模式

１９８７年研究了Ⅰ号矿体地球化学异常特征,下部异常显示有深部盲矿前缘晕叠加,１９９４年探明的Ⅴ号矿体正好与其对应。１９９７年继续研究和建立了新城金矿的原生叠架晕模式,并用模式进行了预测。     

“一带一路”区域可持续发展生态环境遥感监测

2013年9月和10月,习近平主席在出访中亚和东南亚国家期间,先后提出了共建"丝绸之路经济带"和"21世纪海上丝绸之路"(简称"一带一路")的重大倡议。要全面保护"一带一路"区域生态环境,实现2030年可持续发展目标,是一个具有挑战性的问题。遥感技术对生态环境监测与评价发挥着十分重要的作用。本研究利用多尺度、多源遥感数据,对2015年"一带一路"区域的生态环境状况进行监测和分析,旨在提供可持续发展目标生态环境遥感监测的本底。本文选取了几个重要的生态环境方面开展监测与分析,主要包括宏观生态系统结构和植被状况、太阳能资源分布、水资源平衡、主要生态环境限制因素对经济走廊建设的影响、主要城市生态环境质量等。监测区域覆盖亚洲、非洲、欧洲和大洋洲的陆上区域。研究结果为生态环境评价与保护提供了有效的决策依据,有助于"一带一路"建设积极推进。