Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.     

T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.     

Spectral Simulation and Conditioning to Local Continuity Trends in Geologic Modeling

Spectral simulation has gained application in building geologic models due to the advantage of better honoring the spatial continuity of petrophysical properties, such as reservoir porosity and shale volume. Distinct from sequential simulation methods, spectral simulation is a global algorithm in the sense that a global density spectrum is calculated once and the inverse Fourier transform is performed on the Fourier coefficient also only once to generate a simulation realization. The generated realizations honor the spatial continuity structure globally over the whole field instead of only within a search neighborhood, as with sequential simulation algorithms. However, the disadvantage of global spectral simulation is that it traditionally cannot account for the local information such as the local continuity trends, which are often observed in reservoirs and hence are important to be accounted for in geologic models. This disadvantage has limited wider application of spectral simulation in building geologic models. In this paper, we present ways of conditioning geologic models to the relevant local information. To account for the local continuity trends, we first scale different frequency components of the original model with local-amplitude spectrum ratios that are specific to the local trend. The sum of these scaled frequency components renders a new model that displays the desired local continuity trend. The implementation details of this new method are discussed and examples are provided to illustrate the algorithm.     

中国MODIS卫星影像彩色镶嵌图制作

本文介绍了大范围卫星影像彩色镶嵌图的制作流程．对于大范围卫星影像彩色镶嵌图制作的技术难点（去云、拼接、调色），文章进行了重点介绍并提出技术解决办法．利用MODIS卫星数据制作了两幅全国彩色影像镶嵌图：一幅为红波段（B1）、绿波段（B4）和蓝波段（B3）构成的真彩色合成影像：一幅为红波段（B1）．近红外波段（B2）和蓝波段（B3）构成的假彩色合成影像．两幅影像色彩精美，信息量丰富．     

淄博市洪山、寨里煤矿地下水串层污染形成原因及防治

淄博市洪山、寨里煤矿区隐伏的奥陶系灰岩裂隙岩溶水污染严重。水质污染突发于矿坑全面闭坑以后，污染范围与矿坑水区一致，地下水污染组份与矿坑水的高含量组份相同。水质恶化主要由矿坑水串层污染所致。在此针对串层污染形成原因及影响因素，提出了防治对策。     

韧性剪切变形对岩石地球化学行为的制约——以北阿尔金巴什考供韧性剪切带为例

韧性剪切变形对岩石地球化学行为的制约一直是地质学家们探讨的课题。本文以构成北阿尔金红柳沟——拉配泉俯冲碰撞杂岩带与北阿尔金地块边界的巴什考供斜向逆冲型韧性剪切带为例，通过对韧性剪切带内花岗岩变形前后不同变形强度构造岩的地球化学组成进行对比，确定等比线斜率，探讨韧性变形对岩石体积和成分变异的影响。计算结果表明，在糜棱岩化过程中，糜棱岩化花岗岩体积亏损21％，花岗质糜棱岩体积亏损31％。质量平衡计算结果和等比线图表明，韧；陛剪切作用导致SiO2，流失量最大，A12O3、K2O及Ba、Rb、Sr等都有不同程度的丢失，显示出较强的活动性，MnO、P2O5、Sc位于等比线上或附近，表现出相对的稳定性。岩石中活动组分的变异是流体渗滤作用引起的，不活动组分的变异是体．积亏损造成的。     

摄影测量数据库的设计与建立

摄影测量数据库主要存储和管理数字地图成果数据，包括数字高程模型数据（DEM）、数字矢量地图数据（DLG）、数字影像地图数据（DOM）和数字栅格地图数据（DRG）。本文主要介绍了摄影测量数据库的设计、建立以及应用分析等内容。     

基于遥感信息的华北冬小麦区域生长模型及模拟研究

卫星遥感估产和作物生长模拟在作物监测和产量预测方面有各自不可替代的优势。但是,遥感估产难以揭示作物生长发育和产量形成的内在机理,作物模拟在区域应用时初始值的获取和参数的区域化遇到很多困难。如何利用二者的互补性使其相互结合受到人们关注。该文在Wofost模型本地化和区域化的基础上,首次利用同化法的思路探讨了MODIS遥感信息与华北冬小麦生长模拟模型结合的可行性和方法,初步建立了潜在生产水平(水分适宜条件)下区域遥感-作物模拟框架模型(WSPFRS模型)。模拟结果显示:WSPFRS模型对区域尺度的出苗期重新初始化后,模拟的开花期、成熟期空间分布的准确性比Wofost模拟结果有所改进;利用遥感信息对区域尺度上返青期生物量重新初始化后,模拟贮存器官干重的空间分布更接近实际单产的分布,贮存器官干重的高值区与实际高产区基本相符。该研究将为下一步实际水分供应条件下基于遥感信息的冬小麦区域生长模拟研究奠定了基础。     

福建若干基础地质问题及研究方向探讨

就当前福建基础地质调查研究中涉及的华夏古陆，岩浆构造活动，地质构造等有关问题研究现状及各自不同认识作初步归纳。并对其进一步研究方向作粗浅探讨。