Calcite Dissolution Kinetics

We compare the canonical treatment of calcite’s dissolution rate from the literature in a closed system, particle batch reactor, with the alternative approach suggested by Truesdale (Aquat Geochem, 2015). We show that the decay of rate over time can be understood in terms of the evolution and distribution of reactive sites on the surface of these particles. We also emphasize that interpretation of observed rates must not exclude the fundamental role of crystal defects, whose importance is already implicitly reflected in the common form of rate laws in geochemistry. The empirical behavior of overall rate in closed systems, such as those described by Truesdale, may thus reflect relationships between defect centers and the generation of steps over the calcite surface (previously documented for silicates), such that below a critical free energy limit, there is insufficient driving force to open hollow cores and thus a loss of reaction mechanism. Dissolution in this very-near-equilibrium regime will be dependent on the distribution of extant steps and the energetics of new kink site nucleation. However, these sensitivities are complicated in the case of particle systems by grain boundaries, edges, corners, and other terminations. Such discontinuities constitute a defect class whose overall kinetic importance will be strongly tied to particle diameter and which can act independently of the internal strain field imposed by screw and edge dislocations.     

Turning points in black holes astrophysics

Black hole astrophysics is expected to have a major breakthrough any day. Theoretical understanding is well advanced, so the breakthrough has to come from observers. Conclusive and direct evidence of event horizons, signatures of tidal deformation of gas clouds (and eventual disappearance of matter behind horizons) could be obtained in matter of months. At this juncture, we wish to summarize how the subject came to this stage and what is the state-of-the-art flow solution around a black hole. We touch upon the most crucial issue of (un)predictability of this subject. We believe that if viscosity is roughly what MRI simulations are pointing to us, we still require very detailed knowledge of properties of the companion, especially time dependent mass transfer from the companion to the black hole.     

Progressive failure leading to the 3 December 2013 rockfall at Puigcercós scarp (Catalonia,Spain)

A detailed analysis of the pre-failure behavior of the 3 December 2013 rockfall (1,012 m³) occurred on Puigcercós pilot study area (Catalonia, Spain) is presented. The exact date of failure was obtained based on a photographic monitoring performed every 4 h. The long-term monitoring (2,217 days) of the rock slope carried out by a Terrestrial LiDAR allowed the early detection of both pre-failure deformation and precursory rockfalls preceding the final failure. By means of the analysis of the pre-failure deformation, four different deformed areas were detected and the tertiary creep phase was observed in three of them. An attempt to predict the time to failure was performed using the Fukuzono’s (1985) method. Furthermore, the temporal evolution of the precursory rockfalls occurred in those four areas during the progressive failure showed a close resemblance with the exponential pattern of the cumulated displacements at tertiary creep stage. Finally, the study of the meteorological conditions did not show any single triggering factor associated with the final failure. Reversely, the increase in the occurrence of precursory rockfalls on several areas of the slope together with the observed acceleration on the deformation pattern reinforce the role of a progressive degradation of the stability conditions, which ultimately leaded to the 3 December rockfall event.     

Refractory Black Carbon Results and a Method Comparison between Solid-state Cutting and Continuous Melting Sampling of a West Antarctic Snow and Firn Core

This work presents the refractory black carbon(rBC)results of a snow and firn core drilled in West Antarctica(79°55'34.6"S,94°21'13.3"W)during the 2014?15 austral summer,collected by Brazilian researchers as part of the First Brazilian West Antarctic Ice Sheet Traverse.The core was drilled to a depth of 20 m,and we present the results of the first 8 m by comparing two subsampling methods—solid-state cutting and continuous melting—both with discrete sampling.The core was analyzed at the Department of Geological Sciences,Central Washington University(CWU),WA,USA,using a single particle soot photometer(SP2)coupled to a CETAC Marin-5 nebulizer.The continuous melting system was recently assembled at CWU and these are its first results.We also present experimental results regarding SP2 reproducibility,indicating that sample concentration has a greater influence than the analysis time on the reproducibility for low rBC concentrations,like those found in the Antarctic core.Dating was carried out using mainly the rBC variation and sulfur,sodium and strontium as secondary parameters,giving the core 17 years(1998?2014).The data show a well-defined seasonality of rBC concentrations for these first meters,with geometric mean summer/fall concentrations of 0.016μg L^?1 and geometric mean winter/spring concentrations of 0.063μg L^?1.The annual rBC concentration geometric mean was 0.029μg L^?1(the lowest of all rBC cores in Antarctica referenced in this work),while the annual rBC flux was 6.1μg m^?2 yr^?1(the lowest flux in West Antarctica records so far).     

Decreasing precipitation occurs in daily extreme precipitation intervals across China in observations and model simulations

Extreme precipitation response to increasing temperature includes not only changes of frequency and intensity, but also changes of extreme precipitation interval (EPIV) and the precipitation during the neighboring daily extreme precipitations interval (EPIP). These changes have not been fully evaluated yet in observations or climate model simulations although they are very useful to understand variations of extreme precipitation. We used daily precipitation data from 669 meteorological stations during the past five decades across China and projections of 19 general circulation models from CMIP5 under the RCP4.5 and RCP8.5 scenarios to investigate variations of EPIV and EPIP. We found the national average annual EPIV increased across China during the last five decades, while annual EPIP significantly decreased. The decreases mainly occurred in southwest China, east China, and southeast China. At national and regional scales, the average annual EPIV and EPIP showed greater decreases under the RCP8.5 scenario than those under the RCP4.5 scenario from 2006 to 2100. Annual EPIP showed a stronger correlation with extreme precipitation intensity than EPIV. The national average annual EPIP had a significant positive correlation with the Western Pacific Subtropical High Area Index. The abnormal geopotential heights over western Mongolia and the western Pacific at 500 hpa as well as the abnormal SSTs in Japan Sea and the western of Pacific in rainy seasons would result in abnormal annual EPIVs and EPIPs in China. This study may provide references for flooding prediction, water resources management, and disaster prevention and mitigation.