Freshwater calcite precipitates from in vitro mesocosm flume experiments: a case for biomediation of tufas

Freshwater carbonates (tufas) develop today from the Arctic to the tropics, many being localized about springs and upper water courses. Some Quaternary tufas, especially in the Mediterranean region, extend over tens of square kilometres and exceed 30 m in thickness. Radiometric dating of Holocene deposits shows that many have accumulated at an average rate of 1 mm year^?1. However, local precipitation may be much faster and some Holocene deposits may even have outpaced their tropical marine carbonate counterparts. Recently, the study of active sites has attempted to quantify the precipitation mechanisms which lead to tufa deposition. However, field observation and sampling procedures suffer from the inherent disadvantages of uncontrolled fluctuations in environmental conditions during the study programme. These disadvantages compromise any interpretations, particularly where controls on spar versus micrite precipitation are concerned. Many of these problems have been overcome in the current study by the construction and operation of laboratory mesocosm flumes which simulate the natural conditions (e.g. pH, flow rate, ambient temperature and daylight) in which freshwater carbonate (tufa) is deposited. Three mesocosms were supplied with natural river water from tufa precipitating streams and two mesocosms were supplied with UV‐treated (sterile) river water from the same source. One of the untreated flume mesocosms was linked with a calcium reactor, which replaced calcium ions removed during the precipitation process in order to maintain tufa growth over extended experimental runs. Low‐magnesium calcite precipitates (both rhombic sparite grown from long‐crystallite dendrites and short‐crystallite dendrite triad precursors) and micrite peloids (grown from spherulitic precursors) were precipitated in intimate association with biofilm (extracellular polymeric substances) within the four mesocosms supplied with natural river water. Virtually, no tufa‐like precipitate was obtained from the flumes supplied with UV‐treated river water. A second extended run flume experiment was also carried out for comparison purposes using a calcium hydroxide solution in deionized water. Collectively, these experiments provide convincing evidence confirming that the presence of a microbial biofilm strongly influences the precipitation of carbonates in riverine freshwater settings. In particular, experimental results show that micro‐peloidal micrite and short‐crystallite calcite dendrites are only produced in the presence of microbial extracellular polymeric substances.     

High-frequency cyclicity (Milankovitch and millennial-scale) in slope-apron carbonates: Zechstein (Upper Permian), North-east England

The Upper Permian (Zechstein) slope carbonates in the Roker Formation (Zechstein 2nd‐cycle Carbonate) in North‐east England consist of turbidites interbedded with laminated lime‐mudstone. Studies of turbidite bed thickness and relative proportion of turbidites (percentage turbidites in 20 cm of section) reveal well‐developed cyclicities consisting of thinning‐upward and thickening‐upward packages of turbidite beds. These packages are on four scales, from less than a metre, up to 50 m in thickness. Assuming that the laminae of the hemipelagic background sediment are annual allows the durations of the cycles to be estimated. In addition, counting the number and thickness of turbidite beds in 20 cm of laminated lime‐mudstone, which is approximately equivalent to 1000 years (each lamina is 200 μm), gives the frequencies of the turbidite beds, the average thicknesses and the overall sedimentation rates through the succession for 1000 year time‐slots. Figures obtained are comparable with modern rates of deposition on carbonate slopes. The cyclicity present in the Roker Formation can be shown to include: Milankovitch‐band ca 100 kyr short‐eccentricity, ca 20 kyr precession and ca 10 kyr semi‐precession cycles and sub‐Milankovitch millennial‐scale cycles (0·7 to 4·3 kyr). Eccentricity and precession‐scale cycles are related to ‘highstand‐shedding’ and relative sea‐level change caused by Milankovitch‐band orbital forcing controlling carbonate productivity. The millennial‐scale cycles, which are quasi‐periodic, probably are produced by environmental changes controlled by solar forcing, i.e. variations in solar irradiance, or volcanic activity. Most probable here are fluctuations in carbonate productivity related to aridity–humidity and/or temperature changes. Precession and millennial‐scale cycles are defined most strongly in early transgressive and highstand parts of the larger‐scale short‐eccentricity cycles. The duration of the Roker Formation as a whole can be estimated from the thickness of the laminated lithotype as ca 0·3 Myr.     

XRF Determination of 19 Trace Elements In International Geochemical Reference Samples

Routine XRF determination of 19 trace elements in 23 international standards using the method of Leake et al is examined. Agreement of results for 15 well-established international reference samples is generally good, showing that this method gives comparable results to other techniques. New trace element data using this method are presented for the 8 USGS III standards.     

Quantifying velocity and turbulence structure in depositing sustained turbidity currents across breaks in slope

Two-dimensional experiments investigating sediment transport and turbulence structure in sustained turbidity currents that cross breaks in slope are presented as analogue illustrations for natural flows. The results suggest that in natural flows, turbulence generation at slope breaks may account for increased sand transport into basins and that the formation of a hydraulic jump may not be necessary to explain features such as the occurrence of submarine plunge pools and the deposition of coarser-grained beds in the bottomsets of Gilbert-type fan deltas. Experimental flows were generated on 0°, 3°, 6° and 9° slopes of equal length which terminated abruptly on a horizontal bed. Two-component velocities were measured on the slope, at the slope break and downstream of the slope break. Flows were depositional and non-uniform, visibly slowing and thickening with distance downstream. One-dimensional continuous wavelet transforms of velocity time series were used to produce time-period variance maps. Peaks in variance were tested against a background red-noise spectrum at the 95% level; a significant period banding occurs in the cross-wavelet transform at the slope break, attributed to increased formation of coherent flow structures (Kelvin–Helmholtz billows). Variance becomes distributed at progressively longer periods and the shape of the bed-normal-velocity spectral energy distribution changes with distance downstream. This is attributed to a shift towards larger turbulent structures caused by wake stretching. Mean velocity, Reynolds shear stress and turbulent kinetic energy profiles illustrate the mean distribution of turbulence through the currents. A turbulent kinetic energy transfer balance shows that flow non-uniformity arises through the transfer of mean streamwise slowing to mean bed-normal motion through the action of Reynolds normal stresses. Net turbulence production through the action of normal stresses is achieved on steeper slopes as turbulence dissipation due to mean bed-normal motion is limited. At the slope break, an imbalance between the production and dissipation of turbulence occurs because of the contrasting nature of the wall and free-shear boundaries at the bottom and top of the flows, respectively. A rapid reduction in mean streamwise velocity predominately affects the base of the flows and steeper proximal slope flows have to slow more at the break in slope. The increased turbulent kinetic energy, limited bed-normal motion and strong mixing imposed by steep proximal slopes means rapid slowing enhances turbulence production at the break in slope by focusing energy into coherent flow structures at a characteristic period. Thus, mean streamwise slowing is transferred into turbulence production at the slope break that causes increased transport of sediment and a decrease in deposit mass downstream of the slope break. The internal effects of flow non-uniformity therefore can be separated from the external influence of the slope break.     

The origin and tectonic significance of asymmetrical meander-belts

In the Hebgen lake area of SW Montana, the Madison and South Fork Rivers occupy the northeast sides of their respective meander-belts. The form of the abandoned meander-loops within these asymmetric meander-belts indicates that they were produced by gradual northeast migration of the active channels. This progressive migration can be related to tectonic tilting produced by regional extensional faulting at a high angle to the original channel-belt axis which ran down a gently sloping outwash cone. Asymmetric channel sandstone bodies in the rock record can be recognized by the preferred dip of successive lateral accretion units in meander loops. Together with soft sediment deformation, facies and thickness variations they may indicate tectonic deformation of the sedimentary surface.     

Seasonal succession and microlamina formation in a meromictic lake displaying varved sediments

In a small meromictic lake near Toronto, Canada, a mass mortality of photosynthetic bacteria followed the ventilation of the chemocline during fall (autumn) and resulted in 3–8 g m^-2 day^-1 of organic matter being deposited as a dark layer in sediment traps which were suspended in the permanently anaerobic zone. This mass mortality of photosynthetic bacteria occurred in late autumn following the annual thermal destratification of the lake's mixolimnion. Wind mixing during this period of homeothermy resulted in the introduction of low levels of dissolved oxygen into the lake's chemocline. The ensuing mass mortality of photosynthetic bacteria resulted in the release of elemental sulphur as the sulphur-rich bacteria decomposed and sank to the bottom of the lake. The ferrous ions in the water below a depth of 15 m in Crawford Lake reacted with this sulphur to form black ferrous sulphides and pyrite which formed a dark microlamina on the lake floor. Each dark microlamina was overlain by a light coloured (calcite-rich) layer which was deposited each spring and summer during the 3 yr period of this study. The mechanism of microlamina formation elucidated here has been based on the examination of bi-weekly sediment trap information. This approach has permitted an explanation of the mechanisms by which specific events such as calcite precipitation and phytoplankton seasonal succession are transcribed into the sediment record.     

Sediment suspension dynamics and a new criterion for the maintenance of turbulent suspensions

The vertical component of the turbulent flow acceleration term, , is used to determine the net positive vertical force that may support a suspended sediment load. A dimensionless criterion, Λ, is proposed for the maintenance of suspension, defined as the ratio of the maximum vertical turbulent stress to immersed weight of the suspended load above a unit bed area. In order that a suspension be maintained: where v ′ is instantaneous vertical turbulent velocity, σ and ρ are solid and fluid densities, respectively and m is the suspended load dry mass. The Λ criterion is dynamic, being a ratio of stresses and is analogous in this respect to Shields dimensionless stress criterion, θ, for the initiation of bedload motion. The new criterion is successful in predicting the maintenance of steady-state suspended sediment transport in open channel shear flow and deposition from non-uniform particulate density flows of wall jet type.