De nouveaux éléments structuraux du complexe aquifère profond du bassin du Rharb (Maroc) : implications hydrogéologiques

The Rharb basin is located in northwestern Morocco. It is a part of one of the most important hydrogeological basins of Morocco, and extends over some 4000 km². The nature of its Plio-Quaternary sedimentary fill and its structural and palaeoenvironmental contexts are reflected by great variations in aerial and temporal facies distribution. This distribution, in turn, is a direct cause of the observed complexity in the geometry of potentially water-bearing beds. In the present work, we present an image of potential new hydrogeological reservoirs and define new structures that partially explain their architecture. To cite this article: M. Kili et al., C. R. Geoscience 338 (2006).     

阿尔泰额尔齐斯带东段酸性岩墙群地球化学特征及其地质意义

野外地质调查发现在阿尔泰南缘额尔齐斯构造带东段、额尔齐斯活动断裂与富蕴-锡泊渡断裂之间发育了一套未变形的酸性岩墙群.岩墙群侵位于海西期片麻岩化花岗岩和上石炭统深变质的额尔齐斯组岩层中,薄片鉴定和岩石地球化学分析确定为具有细晶结构的流纹斑岩.岩石的SiO2含量为70.9%～75.38%,K2O＋Na2O含量为7.55%～8.99%;大部分样品Na2O＞K2O,里特曼指数值为1.8～2.5之间,Al2O3=12.80%～14.53%,A/CNK=0.9～1.1,NK/A=0.7～0.9,具有准铝质-弱过铝质、低镁、高钾钠、低钙和锶、高（Fe）mol/（Mg）mol特点,具A型花岗岩类特点,属于亚碱性脉岩.岩石轻稀土富集,大离子亲石元素相对富集,具有明显的中等负铕异常,壳源特征明显.锆石U-Pb二次粒子微探针测年显示岩墙群形成于277～286Ma.推断岩墙是阿尔泰海西期造山运动结束后,在拉张构造环境下的地壳局部熔融产物.     

Degradation of 2, 4, 6-trinitotoluene in aqueous solution by ozonation and multi-stage ozonation biological treatment

The objective of this study was to explore the extent of 2,4,6-trinitrotoluene synthetic solution and red water mineralization by comparing conventional direct ozonation and multi-stage ozonation-biological treatment process. The alkaline hydrolysis was used for remediation 2, 4, 6-trinitrotoluene and red water at pH = 10.9. Nevertheless, the hydroxyl radicals would be generated by ozone decomposition with ozone dose of 0.177 g/L. The samples were subjected to chemical oxygen demand and total organic carbon analysis to monitor pollutants removal. The rate of 2, 4, 6-trinitrotoluene and red water pollutants degradation were quantified using high performance liquid chromatography. 2, 4, 6-trinitrotoluene synthetic solution resulted 55.5 % chemical oxygen demand removal by 3 h direct ozonation. Following direct ozonation the biological treatment twenty four hours chemical oxygen demand reached 98.9 % and 98.7 % removal using humic acid and river water 1 % ( v/v) inoculation singly and respectively. Conventional direct ozonation showed non significant change in total organic carbon degradation. While on using multi-stage ozone-biological treatment process where humic acid and/or river water were used as inoculums singly and respectively, total organic carbon fulfilled 73 % and 98.3 % removal. The process was one hour direct ozonation and followed by three days multi-stage ozone-biological treatment. In multi-stage ozone-biological treatment process, ozonation was effective to decompose total organic carbon and to produce biodegradable dissolved organic carbon easily removed by ozone oxidation up to 98.3 % in 2,4,6-trinitrotoluene synthetic solution. Pollutants removal achieved 99 % in authentic red water effluent using river inoculation 1 % (v/v) in 5 days. Nuclear Magnetic Resonance and Fourier Transformation Infra Red methods were performed to confirm types of pollutants content in red water.     

A comparison of surface fitting algorithms for geophysical data

Many treatments in geophysics require regular grids of data. Since the data are generally recorded irregularly (e.g. gravity measurements along roads) or even on tracks (e.g. satellite measurements), it is necessary to grid the observed data. We present the result of a comparison of various surface fitting algorithms carried out in order to check their reliability. Two different types of sampling have been verified: (i) clouds of points and (ii) points along tracks. Five algorithms have been extensively tested: (1) polynomial fit, (2) algorithm using a combination of spline-laplace, (3) krigeage (4) least-squares fitting method, and (5) finite element method. The suitability of each method for different sets of data and the limitations (in terms of amplitude and gradient) are discussed.     

Anhydrite pseudomorphs and the origin of stratiform Cu–Co ores in the Katangan Copperbelt (Democratic Republic of Congo)

The stratiform Cu–Co ore mineralisation in the Katangan Copperbelt consists of dispersed sulphides and sulphides in nodules and lenses, which are often pseudomorphs after evaporites. Two types of pseudomorphs can be distinguished in the nodules and lenses. In type 1 examples, dolomite precipitated first and was subsequently replaced by Cu–Co sulphides and authigenic quartz, whereas in type 2 examples, authigenic quartz and Cu–Co sulphides precipitated prior to dolomite and are coarse-grained. The sulphur isotopic composition of the copper–cobalt sulphides in the type 1 pseudomorphs is between −10.3 and 3.1‰ relative to the Vienna Canyon Diablo Troilite, indicating that the sulphide component was derived from bacterial sulphate reduction (BSR). The generation of during this process caused the precipitation and replacement of anhydrite by dolomite. A second product of BSR is the generation of H₂S, resulting in the precipitation of Cu–Co sulphides from the mineralising fluids. Initial sulphide precipitation occurred along the rim of the pseudomorphs and continued towards the core. Precipitation of authigenic quartz was most likely induced by a pH decrease during sulphide precipitation. Fluid inclusion data from quartz indicate the presence of a high-salinity (8–18 eq. wt.% NaCl) fluid, possibly derived from evaporated seawater which migrated through the deep subsurface. ⁸⁷Sr/⁸⁶Sr ratios of dolomite in type 1 nodules range between 0.71012 and 0.73576, significantly more radiogenic than the strontium isotopic composition of Neoproterozoic marine carbonates (⁸⁷Sr/⁸⁶Sr = 0.7056–0.7087). This suggests intense interaction with siliciclastic sedimentary rocks and/or the granitic basement. The low carbon isotopic composition of the dolomite in the pseudomorphs (−7.02 and −9.93‰ relative to the Vienna Pee Dee Belemnite, V-PDB) compared to the host rock dolomite (−4.90 and +1.31‰ V-PDB) resulted from the oxidation of organic matter during BSR.     

Adaptation to climate change in desertified lands of the marginal regions in Egypt through sustainable crop and livestock diversification systems

Environmental degradation resulting from current climate changes, including prolonged drought, land degradation, desertification, and loss of biodiversity, is presenting enormous challenges to achieve ...     

Paläoklimatische Information im Isotopengehalt14C-datierter Saharawässer: Kontinentaleffekt in D und18O

Zusammenfassung In den¹⁴C-Altern der Saharawässer spiegelt sich die wechselnde Abfolge von Feucht- und Trockenphasen während des späten Pleistozäns und Holozäns wider. Außerdem zeigt sich ein West-Ost-Gefälle in ihrem D- und¹⁸O-Gehalt, das als Kontinentaleffekt im Grundwasser gedeutet wird. Dieser Kontinentaleffekt setzt voraus, daß das nordafrikanische Klimageschehen vergangener Feuchtphasen von der Westdrift bestimmt wurde, die regenbringende atlantische Luftmassen weit ins Saharainnere getrieben hat. Ein einfaches mathematisches Modell, das den Kontinentaleffekt durch eine Rayleigh-Kondensation beschreibt, ergibt die beste Anpassung an die Meßwerte, wenn für die Sahara (ähnlich wie heute in Europa) ein West-Ost-Gefälle in den Paläo-Winterniederschlagsmengen von –30% pro 1000 km angenommen wird. Unter der Annahme ehemaliger Winterniederschläge (Sept.-März) von 600 mm (entspricht Lissabon heute) für das Gebiet an der nordafrikanischen Atlantikküste ergibt diese Modellrechnung z. B. 250 mm für die Paläo-Winterniederschläge im Gebiet des Murzuk-Beckens.

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The¹⁴C-age distribution of Saharian groundwaters shows the alternating sequence of humid and arid periods in the late Pleistocene and Holocene. The observed west-east decrease of the D- and¹⁸O-content of the Sahara waters is interpreted to be the Continental Effect in rain and groundwater. The paleoclimatic situation during ground-water formation therefore was controlled by the western drift carrying wet Atlantic air masses across the Sahara. The best fit of a simple Rayleigh condensation model of the continental effect to the experimental data is obtained with a west-east decrease of the Saharian paleo-winter precipitation of –30% per 1000 km (similar to the one in Europe today). With an annual winter precipitation rate (Sept.-March) of 600 mm (corresponding to the one of Lisboa today) for the Northafrican coastal area at the Atlantic Ocean a previous winter precipitation rate of 250 mm is obtained for the Murzuq Basin.

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Résumé Une succession de périodes humides et arides à la fin du Pléistocène et à l'Holocène se réflète dans la distribution des âges¹⁴C d'eaux souterraines du Sahara. Les teneurs en D et¹⁸O diminuent d'Ouest en Est, ce qui est interprété comme un effet continental dans l'eau souterraine. Celui-ci signifie que la climatologie des phases pluviales passées, dans l'Afrique du Nord, était déterminée par des vents d'Ouest qui apportaient des masses d'air atlantique humide à l'intérieur du Sahara. Un modèle mathématique simple décrivant l'effet continental par une condensation du type Rayleigh, reproduit avec la meilleure conformité les valeurs expérimentales, pour autant qu'on admette que les pluies hivernales au Sahara diminuaient anciennement d'Ouest en Est de 30% par 1000 km (comme à présent en Europe). En supposant qu'autrefois la quantité de pluie hivernale, de septembre à mars à la côte atlantique de l'Afrique du Nord était de 600 mm (comme aujourd'hui à Lisbonne), on obtient à l'aide de ce modèle une précipitation hivernale ancienne de 250 mm dans le bassin du Mourzouk.

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, ¹⁴C, . , ¹⁸O, , . , , , , . , Rayleigh, — , — — 30 % 1000 . , - , . . , 600 , — —, 250 .

     

Quantifying land use/land cover spatio-temporal landscape pattern dynamics from Hyperion using SVMs classifier and FRAGSTATS®

This study aims to quantify the landscape spatio-temporal dynamics including Land Use/Land Cover (LULC) changes occurred in a typical Mediterranean ecosystem of high ecological and cultural significance in central Greece covering a period of 9 years (2001–2009). Herein, we examined the synergistic operation among Hyperion hyperspectral satellite imagery with Support Vector Machines, the FRAGSTATS^® landscape spatial analysis programme and Principal Component Analysis (PCA) for this purpose. The change analysis showed that notable changes reported in the experimental region during the studied period, particularly for certain LULC classes. The analysis of accuracy indices suggested that all the three classification techniques are performing satisfactorily with overall accuracy of 86.62, 91.67 and 89.26% in years 2001, 2004 and 2009, respectively. Results evidenced the requirement for taking measures to conserve this forest-dominated natural ecosystem from human-induced pressures and/or natural hazards occurred in the area. To our knowledge, this is the first study of its kind, demonstrating the Hyperion capability in quantifying LULC changes with landscape metrics using FRAGSTATS^® programme and PCA for understanding the land surface fragmentation characteristics and their changes. The suggested approach is robust and flexible enough to be expanded further to other regions. Findings of this research can be of special importance in the context of the launch of spaceborne hyperspectral sensors that are already planned to be placed in orbit as the NASA’s HyspIRI sensor and EnMAP.