Rotation of the Iberian arc: Palaeomagnetic results from North Spain

NRM directions measured from 32 sites in Middle Cambrian, Upper Silurian/Lower Devonian and Lower Carboniferous redbeds follow the trend of the Variscan arc in North Spain. Thermal demagnetisation does not significantly alter this pattern. Fold tests show that the NRM is earlier than the ?₁ folds which form the arc; consistency of angle between bedding and the tilt-corrected NRM inclination (22–28°), similarity of the corresponding palaeolatitudes to Carboniferous values and microscopic evidence of Variscan redistribution of hematite indicates that the magnetisation is post-Lower Carboniferous. A statistical plot of the orientation of ?₁ fold traces against angle between ?₁ fold traces and declination of NRM shows that where these folds curve through 165° the NRM has been rotated through 110°: the arc is an orocline. Restoration of this rotation, and that needed to close the Bay of Biscay, brings the calculated mean palaeomagnetic pole reasonably close to the Upper Carboniferous part of the apparent polar wander path for Europe.     

Hurricane-borne African Locusts (Schistocerca gregaria) on the Windward Islands

The research applies a geographic perspective to the interface of biotic, atmospheric and socio-economic factors. Wind as a factor in biotic distributions helps explain the existence and quality of life on many isolated islands. In the late summer of 1988, there were reports of African desert Locust (Schistocerca gregaria) invasion of the Windward Islands. The event was historically unprecedented, and agricultural experts in the eastern Caribbean were alarmed. A tentative hypothesis was that Hurricane Joan provided the transport mechanism. An alternative hypothesis is suggested here. The discussion helps explain why transatlantic African Desert Locust migrations are so unusual. Analysis is based on primary and secondary data sources that include synoptic weather maps, formal and informal scientific reports, written correspondence with agricultural experts in the impact area, and newspaper coverage of the invasion.     

晚新生代以来青藏高原东缘的剥蚀过程:来自裂变径迹的证据

本文以青藏高原东缘的三级地貌(川西高原、龙门山和四川盆地)单元为基础,利用裂变径迹定年数据分区块研究了该地区的晚新生代以来的剥蚀速率。研究结果表明,晚白垩世以来青藏高原东缘经历了一个由平缓到突然加速的剥蚀过程,其转折点为中新世。在整个时间段内的平均剥蚀速率,川西高原为0.26mm/yr,龙门山为0.72mm/yr,四川盆地为0.20mm/yr。龙门山的剥蚀速率大约是川西高原的2.8倍,间接反映边缘山脉的隆升并不等同于高原内部的隆升,边缘山脉的隆升可能是构造隆升和剥蚀隆升相叠加的结果。     

Cell-Specific Alkaline Phosphatase Expression by Phytoplankton from Winyah Bay,South Carolina,USA

Alkaline phosphatase expression by phytoplankton from two sites in Winyah Bay, SC, USA was investigated using nutrient-addition bioassays and cell-specific enzyme-labeled fluorescence (ELF) measurements. Our aim was to determine whether expression was group- or species-specific within the phytoplankton community. Diatoms dominated the riverine site in May, the coastal site in July, and both sites in August. Phytoplankton growth was limited by nitrogen (N) availability at the coastal site in May and the riverine site in August, but phosphate limitation was not observed. Alkaline phosphatase expression ranged from ∼30% of cells enumerated to less than 1% and was significantly reduced by inorganic phosphorus (P; 10 μM P) additions. Expression was restricted to species with low abundance, and there were no shifts in community composition consistent with alkaline phosphatase expression. Lack of phosphate limitation at higher-than-Redfield N/P ratios (up to 40:1), however, points to a potentially wider role of dissolved organic phosphorus in nutrition of Winyah Bay phytoplankton than indicated by the ELF assay.     

Strontium isotopic geochemistry of Pan-African/Brasiliano rocks,Chapada copper deposit,Goiás,Brazil

Whole rock and mineral Rb-Sr isochrons from the upper amphibolite grade metamorphic host rocks of the Chapada copper deposit in Goiás, Brazil, yield an age of 561±9 Ma, with a⁸⁷Sr/⁸⁶Sr initial (I) of 0.70414±0.00005, for the crystallization of pre-metamorphic volcanic and igneous rocks and 532 ±1 Ma for their metamorphism during the Pan-African/Brasiliano orogeny (700-450 Ma). A porphyritic diorite stock which intruded the host schists yields a mineral isochron age of 534±16 Ma (I=0.70415±0.00004). The low I values determined from these isochrons suggest that the host schists at Chapada were derived from upper mantle or lower crust material and are characteristic of magmatic products associated with island arcs. The Early Cambrian age of the host rocks at Chapada contradicts the previously assigned mid-Proterozoic age and suggests that Pan-African/Brasiliano magmatic activity may have been more extensive in central Brazil than previously thought.

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Zusammenfassung Das Trägergestein der Chapada Kupferlagerstätte in Goiás ist in metamorpher Hoch-Amphibolitfazies ausgebildet. Gesamtgesteins- und individuelle Mineral Rb-Sr-Isochronen mit einem⁸⁷Sr/⁸⁶Sr-Initialwert (I) von 0,70414±0.00005 ergeben für die Kristallisation der Vulkanite und Magmatite, die die Metamorphose vordatieren, ein Alter von 561±9 Mio Jahre. Die Datierung der Metamorphose während der panafrikanisch/brasilianischen Orogenese (700 bis 450 Mio Jahre) ergibt 532±1 Mio Jahre. Das Mineral-Isochronenalter eines Dioritkörpers porphyrischen Gefüges, der in die Schiefer intrudierte, beträgt 534±16 Mio Jahre (I=0,70415 ±0,00004). Das Ergebnis niedriger Initial-Werte dieser Isochronen ergibt für die Schiefer bei Chapada ein Ausgangs-Material im Bereich des oberen Mantels oder der tieferen Kruste; diese Ausgangswerte sind charakteristisch für magmatische Tätigkeit in Verbindung mit Inselbögen. Das unterkambrische Alter des Trägergesteins bei Chapada steht im Widerspruch zu dem bisher angenommenen mittelproterozoischen Alter und ist ein Hinweis auf eine mögliche Phase intensiverer pan-afrikanisch/brasilianischer magmatischer Aktivität in Zentral-Brasilien als ursprünglich angenommen wurde.

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Résumé Les roches qui contiennent le gisement de cuivre de Chapada (Goias, Brésil) sont des schistes cristallins appartenent au facies dupérieur des amphibolites. Dans des volcanites et des roches orthomagmatiques appartenant à cet ensemble, des isochrones Rb-Sr sur roches totales et sur minéraux donnent un âge de 561±9 Ma avec un rapport initial de 0,70414±0,00005 pour la cristallisation pré-métamorphique et un âge de 532±1 Ma pour le métamorphisme, lié à l'orogenèse pan-africaine / brésilienne. Un pluton de diorite porphyrique, qui intrude les schistes cristallins donne, par isochrone sur minéraux, un âge de 534±16 Ma (rapport initial de 0,70415±0,00004). Les valeurs basses des rapports initiaux de ces diverses roches suggèrent que les schistes de Chapada sont dérivés de matériaux mantelliques ou crustaux profonds et présentent les caractères des produits magmatiques associés aux arcs insulaires. Leur âge éo-cambrien, en contradiction avec l'âge mésoprotérozoïque admis jusqu'ici, permet de penser que l'activité magmatique pan-africaine/brésilienne dans le centre du Brésil a été plus intense que ce qu'on croyait jusqu'ici.

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Chapada Gois . 0,70414±0,00005, 561± 9 , 532±1 , . . - / 700 450 /. , , 534±16 / 1 = 0,70415 = 0,00004 /. , Chapada , . . - ; , . , - - , , , .

     

Extreme variations in strontium initial ratios in ore-related fluids

Magmato-hydrothermal cassiterite-topaz ore at the Carboniferous East Kemptville (EK) greisenhosted tin deposit (Nova Scotia, Canada) is cross-cut by veins containing apatite, triplite, vivianite and fluorite. Initial ⁸⁷Sr/⁸⁶Sr ratios of these minerals have an extreme range (0.7135 to 0.8284). The initial ratios of the host rocks, EK quartz-topaz rock and Davis Lake biotite monzogranite (0.729±0.001, 0.727±0.004), are also high. The adjacent Meguma Group metasedimentary rocks are more typical of crustal material (0.712–0.719 at 330 Ma). Rb and Sr contents of EK fluorite (max.: 13.0, 1420 ppm) and apatite (max.: 88.1, 6660 ppm) are unusually high and variable. Unexpectedly, high Sr contents correlate positively with the high initial ⁸⁷Sr/⁸⁶Sr ratios. Fluorite and phosphate minerals from the first set of post-greisen veins at East Kemptville reflect the unusual chemistry of a high ⁸⁷Sr/⁸⁶Sr fluid present in the deposit after ore formation. The most extreme composition of this fluid was characterized by ⁸⁷Sr/⁸⁶Sr>0.8284, high Rb/Sr, high P, Rb, Cu, Zn and Fe contents, but low abundances of Ca, Pb and Sn with respect to the Davis Lake monzogranite. Such a fluid could have been derived from the greisen fluid and modified by reaction with the overlying Meguma metawacke. A second alternative, which cannot be well constrained at present, is that an extremely radiogenic fluid entered the deposit after ore formation and mixed with the postore fluid. In either case, the modified fluid subsequently mixed with meteoric water and precipitated the minerals with much lower ⁸⁷Sr/⁸⁶Sr ratios and Rb and Sr contents.     

Garnet-peridotite stability and occurrence in crust and mantle

The boundary between the spinel- and garnet-lherzolite mineral facies is strongly curved between 1300° C and 1450° C; below 1200° C it lies almost parallel to the temperature axis of the T-P diagram.Pressure of at least 12 kb is required to stabilise garnet-peridotite on the geothermal gradient and the depth at which the boundary is encountered is not sensitive to variations in the geotherm.Garnet-peridotite is metastable with respect to spinel-peridotite in normal continental crust. Natural occurrences are mantle derived and have either suffered rapid upward transit in diatremes or, in orogenic zones, either they were emplaced after upward tectonic transport through tens of kilometres, or have originated by in situ metamorphism of pre-existing crustal peridotite in an orogenic root downfolded to depths of at least 40 km.     

Asia-Pacific mussel watch: monitoring contamination of persistent organochlorine compounds in coastal waters of Asian countries

Contamination of persistent organochlorines (OCs) such as PCBs (polychlorinated biphenyls), DDT and its metabolites (DDTs), HCH (hexachlorocyclohexane) isomers (HCHs), chlordane compounds (CHLs), and HCB (hexachlorobenzene) were examined in mussels collected from coastal waters of Asian countries such as Cambodia, China, Hong Kong, India, Indonesia, Japan, Korea, Malaysia, Philippines, Far East Russia, Singapore, and Vietnam in 1994, 1997, 1998, 1999, and 2001 to elucidate the contamination status, distribution and possible pollution sources and to assess the risks on aquatic organisms and human. OCs were detected in all mussels collected from all the sampling sites investigated. Considerable residue levels of p,p(')-DDT and alpha-HCH were found in mussels and the concentrations of DDTs and HCHs found in mussels from Asian developing countries were higher than those in developed nations suggesting present usage of DDTs and HCHs along the coastal waters of Asian developing countries. On the other hand, lower concentrations of PCBs detected in mussels from Asian developing countries than those in developed countries indicate that PCBs contamination in mussels is strongly related to industrial and activities. To our knowledge, this is a first comprehensive report on monitoring OCs pollution in the Asia-Pacific region.