Water quality in New Zealand rivers: current state and trends

River water quality, particularly in lowland catchments, is a matter of concern to the New Zealand public. We assessed river water quality and biological state and trends using data from more than 900 monitoring sites. Parallel state and trend analyses were carried out using all sites and a subset of lowland river sites. Median water-quality state in urban and pastoral land-cover classes was poorer than in exotic forest and natural land-cover classes, and lowland sites in the urban and pastoral classes had the poorest water quality. Nutrient and Escherichia coli concentrations increased and visual clarity and Macroinvertebrate Community Index scores decreased as proportions of catchments in high-intensity agricultural and urban land cover increased. Ten-year trends (2004–2013) indicated recent improvements in ammoniacal nitrogen, dissolved reactive phosphorus and total phosphorus in the pastoral and urban classes, possibly reflecting improved land management. In contrast, trends in nitrate-nitrogen in the exotic forest and cool-dry/pastoral classes indicated worsening conditions.     

Riverine dominance of a nearshore marine demersal food web: evidence from stable isotope and C/N ratio analysis

The Thukela Bank, KwaZulu-Natal, supports a diverse ecosystem and South Africa’s only prawn fishery. Oceanographic studies suggest riverine input is not important for the biology of this system, whereas biological studies suggest the contrary, with prawn catches increasing with increased fluvial run-off. The aim of this study was to determine (i) the importance of riverine and marine organic matter for the Thukela Bank food web; and (ii) whether there are seasonal changes in the Thukela River stable isotope values, and, if so, whether these are reflected in the isotope values of demersal organisms. Estuarine organic matter, sediments and demersal organisms were collected from several sites across the bank in the wet and dry seasons of 2008, 2009 and 2010. Marine particulate organic matter was also collected in 2010 and analysed for δ13C and δ15N, as well as C/N ratios. There were strong seasonal changes in isotopic values of organic matter and fauna, especially faunal δ13C. There was an apparent time-lag in organisms assimilating riverine organic matter isotopic values, with the isotopic signature of demersal organisms reflecting that of riverine organic matter from the previous season, which is likely the result of tissue turnover time. In 2010, Thukela Bank sediment organic matter was of riverine origin and this maintained the demersal food web. We conclude that Thukela River organic matter is an important input to the food web of the Thukela Bank, indicating that any future damming of the catchment area could have serious consequences for this ecosystem.     

Stratigraphic,sedimentological and palaeoenvironmental constraints on the rise of the Urgonian platform in the western Swiss Jura

Urgonian‐type carbonates are a characteristic feature of many late Early Cretaceous shallow‐marine, tropical and subtropical environments. The presence of typical photozoan carbonate‐producing communities including corals and rudists indicates the prevalence of warm, transparent and presumably oligotrophic conditions in a period otherwise characterized by the high density of globally occurring anoxic episodes. Of particular interest, therefore, is the exploration of relationships between Urgonian platform growth and palaeoceanographic change. In the French and Swiss Jura Mountains, the onset and evolution of the Urgonian platform have been controversially dated, and a correlation with other, better dated, successions is correspondingly difficult. It is for this reason that the stratigraphy and sedimentology of a series of recently exposed sections (Eclépens, Vaumarcus and Neuchâtel) and, in addition, the section of the Gorges de l’Areuse were analysed. Calcareous nannofossil biostratigraphy, the evolution of phosphorus contents of bulk rock, a sequence‐stratigraphic interpretation and a correlation of drowning unconformities with better dated sections in the Helvetic Alps were used to constrain the age of the Urgonian platform. The sum of the data and field observations suggests the following evolution: during the Hauterivian, important outward and upward growth of a bioclastic and oolitic carbonate platform is documented in two sequences, separated by a phase of platform drowning during the late Early Hauterivian. Following these two phases of platform growth, a second drowning phase occurred during the latest Hauterivian and Early Barremian, which was accompanied by significant platform erosion and sediment reworking. The Late Barremian witnessed the renewed installation of a carbonate platform, which initiated with a phase of oolite production, and which progressively evolved into a typical Urgonian carbonate platform colonized by corals and rudists. This phase terminated at the latest in the middle Early Aptian, due to a further drowning event. The evolution of this particular platform segment is compatible with that of more distal and well‐dated segments of the same northern Tethyan platform preserved in the Helvetic zone of the Alps and in the northern subalpine chains (Chartreuse and Vercors).     

Desert dust aerosol air mass mapping in the western Sahara, using particle properties derived from space-based multi-angle imaging

Coincident observations made over the Moroccan desert during the Sahara mineral dust experiment (SAMUM) 2006 field campaign are used both to validate aerosol amount and type retrieved from multi-angle imaging spectroradiometer (MISR) observations, and to place the suborbital aerosol measurements into the satellite's larger regional context. On three moderately dusty days during which coincident observations were made, MISR mid-visible aerosol optical thickness (AOT) agrees with field measurements point-by-point to within 0.05–0.1. This is about as well as can be expected given spatial sampling differences; the space-based observations capture AOT trends and variability over an extended region. The field data also validate MISR's ability to distinguish and to map aerosol air masses, from the combination of retrieved constraints on particle size, shape and single-scattering albedo. For the three study days, the satellite observations (1) highlight regional gradients in the mix of dust and background spherical particles, (2) identify a dust plume most likely part of a density flow and (3) show an aerosol air mass containing a higher proportion of small, spherical particles than the surroundings, that appears to be aerosol pollution transported from several thousand kilometres away.     

New insights into Holocene atmospheric circulation dynamics in central Scandinavia inferred from oxygen‐isotope records of lake‐sediment cellulose

St. Amour, N. A., Hammarlund, D., Edwards, T. W. D. & Wolfe, B. B. 2010: New insights into Holocene atmospheric circulation dynamics in central Scandinavia inferred from oxygen‐isotope records of lake‐sediment cellulose. Boreas, Vol. 39, pp. 770–782. 10.1111/j.1502‐3885.2010.00169.x. ISSN 0300‐9843 Cellulose‐inferred lakewater oxygen‐isotope records have been obtained from two hydrologically open basins (Lake Spåime and Lake Svartkälstjärn), located on a west–east transect across central Sweden, to investigate changes in atmospheric circulation patterns during the Holocene. The Lake Spåime δ¹⁸O record is sensitive to changes in the seasonal distribution of precipitation in the Scandes Mountains of west‐central Sweden, and thus generally portrays variations in δ¹⁸O of precipitation (δ¹⁸O_P) that are governed predominantly by the influence of air masses originating from the North Atlantic. In contrast, the Lake Svartkälstjärn δ¹⁸O record appears to reflect the varying influence of air masses delivering moisture from the North Atlantic and the Baltic Sea. A comparison of inferred changes in δ¹⁸O_P over the Holocene between the two sites reveals systematic patterns of variability over widely different time scales. These include: (1) a previously recognized long‐term regional decline in δ¹⁸O_P, possibly in response to the declining vigour of Northern Hemisphere atmospheric circulation related to decreasing summer solar insolation; (2) newly identified inverse centennial‐ to millennial‐scale δ¹⁸O_P fluctuations at the two sites that may be linked to changes in modes of atmospheric circulation analogous to those described at interannual to multidecadal time scales by the North Atlantic Oscillation (NAO) index; and (3) a prolonged interval of apparent climatic stability in the mid‐Holocene (c. 6300–4200 cal. yr BP) characterized by persistently negative NAO‐like circulation.     

COMPUTATIONS OF NETWORK MODELS OF POROUS MEDIA*

In a paper presented at last year's Amsterdam meeting (viz. Geophysical Prospecting 14 (1966), 3, 301–341), J. R. Schopper derived formulas relating formation factor, permeability and porosity, by means of a statistical-network approach and by treating the electric and hydraulic resistance analogously. The model of the porous medium consists of a network of branch resistors, their values being statistically distributed about a mean R_o with a relative standard deviation (variation coefficient) s. A properly defined total resistance R of the network can be expressed by the relationship: ((1′)) Here α is a geometrical factor dependent only on the shape of the network (i.e. the number of meshes in the longitudinal and transversal direction), ε is a characteristical constant dependent only on the individual mesh shape (i.e. the number of nodes and branches within a mesh). This network constant ε enters the equations relating formation factor, permeability and porosity, ε had been found to be in the range zero to one by calculating algebraically two special limiting network cases. However, for a better understanding of which value exactly this constant will have in actual porous media, networks with various mesh shapes have to be treated generally. Because of the basically statistical approach, the networks have to be large so that a general algebraic treatment is precluded. Hence numerical methods using digital computers must be applied. The determination of the total resistance R of any resistance network leads to the problem of solving a system of linear, inhomogeneous equations; i.e. Ohm's law written in matrix form: ((2′))

• (R) is the matrix of the coefficients, composed of the individual branch resistances.
• (I) is the column vector, its components being fictitious circular mesh currents.
• (U) is the inhomogeneity column, its components being source voltages within the individual meshes.

The matrix (R) has characteristic properties that depend on the mesh shape on the one hand and on the number and arrangement of the meshes on the other hand. With the regular arrangement of identical meshes investigated here, the matrix always has a banded structure and is symmetrical with respect to the main diagonal, positive definite, and non-singular. For the numerical determination of the wanted constant ε the coefficients matrix is provided with values having a known distribution. Here, in particular, a computer-generated pseudorandom homogeneous distribution is used. The system, of equations is solved for R by a modified Cholesky method. Equation (1′) can then be solved fore. The main features of an ALGOL program written for this purpose and optimized with respect to storage space requirement and computer time are discussed. Networks of triangular, square and hexagonal meshes have been investigated. The results are discussed.     

Primary production of the northern Barents Sea

The majority of the arctic waters are only seasonally ice covered; the northern Barents Sea, where freezing starts at 80 to 81°N in September, is one such area. In March, the ice cover reaches its greatest extension (74-75°N). Melting is particularly rapid in June and July, and by August the Barents Sea may be ice free. The pelagic productive season is rather short, 3 to 3.5 months in the northern part of the Barents Sea (north of the Polar Front, 75°N), and is able to sustain an open water production during only half of this time when a substantial part of the area is free of ice. Ice algal production starts in March and terminates during the rapid melting season in June and July, thus equalling the pelagic production season in duration.
This paper presents the first in situ measurements of both pelagic and ice-related production in the northern Barents Sea: pelagic production in summer after melting has started and more open water has become accessible, and ice production in spring before the ice cover melts. Judged by the developmental stage of the plankton populations, the northern Barents Sea consists of several sub-areas with different phytoplankton situations. Estimates of both daily and annual carbon production have been based on in situ measurements. Although there are few sampling stations (6 phytoplankton stations and 8 ice-algae stations), the measurements represent both pelagic bloom and non-bloom conditions and ice algal day and night production. The annual production in ice was estimated to 5.3 g Cm^-2, compared to the pelagic production of 25 to 30 g Cm^-2 south of Kvitøya and 12 to 15 g Cm^-2 further north. According to these estimates ice production thus constitutes 16% to 22% of the total primary production of the northern Barents Sea, depending on the extent of ice-free areas.     

Eclogite-Blueschist Relationships as Evidenced by Mineral Equilibria in the High-Pressure Metabasic Rocks of Sifnos (Cycladic Islands), Greece

The northern part of the Cycladic island of Sifnos (Greece)is formed by a coherent sequence of interlayered acid and basicmetavolcanic rocks and metasediments, which underwent a high-pressureblueschist facies metamorphism during the Eocene. The metabasicrocks, including eclogites, blueschists, and actinolite-bearingrocks, are discussed in terms of their mineral assemblages,and bulk-rock and mineral chemistries. Metamorphic conditionsof 470 ? 30 ?C and 15 ? 3 kb are indicated by garnet-omphacitegeothermometry and by the development of deerite in meta-ironstonesand jadeite +quartz in meta-acidites.Mineral textures and systematicelement distributions between coexisting minerals suggest attainmentof chemical equilibrium. A new projection from garnet, epidote,quartz and vapour onto the NaAlO₂-Al₂O₃-CaMgO₂ plane is usedto illustrate equilibrium phase relations between omphacite,glaucophane, actinolite, paragonite, and chloritoid. It is demonstratedthat eclogites, blueschists, and actinolite-bearing metabasitesrepresent different bulk-rock compositions that recrystallizedunder the same fluid pressure and temperature conditions. Eclogitescontaining hydrous minerals such as glaucophane, actinolite,phengite, or paragonite in equilibrium with garnet and omphacitecan occur together with blueschists in high-pressure terraneswithout indicating different metamorphic conditions.     

Pyrite replacement of mollusc shells from the Lower Oxford Clay (Jurassic) of England

Replacement of originally aragonite mollusc shells by pyrite commonly occurs in the Lower Oxford Clay. Petrographic studies show the shells to have constituted complex microenvironments in the sediment. A range of replacement textures is found showing a variable amount of solution of the original aragonite. Three distinct textures were found in crushed pyrite-replaced ammonite shells from heavily pyritized concretions. (1) A texture reflecting the original shell structure due to the replacement of the organic shell-matrix by pyrite. (2) An ovoid texture seen at several stages of replacement reflecting processes occurring at discrete centres of sulphate reduction. (3) Euhedral crystals lining cracks and fractures in the shell. Three types of replacement are found in small gastropods and bivalves from shell bed, some of which may relate to those seen in the ammonites. (1) Replacement of organic shell-matrix by pyrite preserving good shell-microstructure. (2) Replacement showing outwardly good preservation of morphological features but inwardly only the gross structure, such as growth lines, is preserved. (3) Replacement of the shell in a matrix of euhedral pyrite leaving only lines of carbonate inclusions marking the margins of the shell. The replacement textures and types appear to be dependent on the initial structure of the shell and the access of iron and sulphate into the shell. Early stages of replacement appear to proceed by pyrite formation within the organic matrix of the shell, with little or no solution of the carbonate, this produces textures which faithfully mimic the original shell microstructure. It is thought that the lack of carbonate solution is due to a limited availability of iron, brought about by the less intensively reducing nature of the sediment. Later stages of replacement are promoted by the cracking and fracturing of the shell and are, generally, not as faithful to the original shell structure. This is due to the greater availability of iron as the sediment becomes more reducing with burial.