Does upward seepage of river water and storm water runoff determine water quality of urban drainage systems in lowland areas? A case study for the Rhine–Meuse delta

The water quality of urban drainage ditches in lowlands in the Rhine‐Meuse delta was analysed with principal component analysis (PCA) during a dry period and a rain storm, and related to the seepage of polluted river water and effective impervious area (EIA). This was done in order to test the hypothesis that seepage of river water and storm water runoff from impervious areas strongly determine the water quality of urban drainage systems along large lowland rivers. Our analysis revealed that upward seepage of groundwater originating from rivers Rhine and Meuse was positively correlated with nitrate, potassium, sodium and chloride and negatively correlated with alkalinity, calcium, magnesium and iron. EIA was correlated with very few environmental variables (i.e. phosphate, pH and iron in the dry period and iron during the rain storm). Nickel and zinc concentrations generally exceeded the maximum allowable concentrations (MAC), while lead and phosphorus concentrations were just above the nutrient standards and MAC in a few locations during the rain storm. To optimize water quality in urban water systems, attention should be paid to all sources of pollution and not only to EIA. The impact of local groundwater seepage originating from large rivers in lowlands on the chemistry of urban water systems is often underestimated and should be taken into account when assessing water quality and improving water quality status. Copyright © 2009 John Wiley & Sons, Ltd.     

Platinum-group minerals in the Santo Tomas II (Philex) porphyry copper-gold deposit,Luzon Island,Philippines

Mineralized quartz diorites of the Santo Tomas II porphyry copper-gold deposit, carry high Au contents (average: 1.8 ppm) as well as 160 ppb Pd and 38 ppb Pt. Values of other platinum-group elements (PGE) and rhenium are below the analytical detection limits. There is a significant positive correlation between Au and Cu. The highest Pd values were detected in the most Au- and Cu-rich rocks. Platinum-group minerals (PGM) occur exclusively as inclusions in chalcopyrite and bornite. Potential Pd and Pt contents in sulphide concentrates are estimated at 1.5 g/t and 0.4 g/t, respectively. The precious metal assemblages consist of merenskyite (main PGM), kotulskite, moncheite, native gold, electrum, hessite and petzite. Polyphase fluid inclusions in quartz veinlets, associated with a PGM-bearing bornite-chalcopyrite-magnetite assemblage, are characterized by high salinity (35 to > 60 eq. wt% NaCl) and high trapping temperatures (between 380 and 520 °C). They may represent primary magmatic-hydrothermal fluids, which have been responsible for the transport of Pd, Pt and Au as chloride complexes.     

A tectonic model for the metamorphic evolution of the Basal Gneiss Complex, Western South Norway

A review of currently available information relevant to the Basal Gneiss Complex (BGC) of Western South Norway, combined with the authors'own observations, leads to the following conclusions.
1. Most of the BGC consists of Proterozoic crystalline rocks and probably subordinate Lower Palaeozoic cover.
2. The last major deformation of these rocks was during the Caledonian orogeny and involved large-scale thrusting, recumbent folding and doming. The structural development of the BGC is closely tied in with that of the Caledonian allochthon.
3. The whole eclogite-bearing part of the BGC has suffered a high pressure metamorphism with conditions of between 550°C, 12.5 kbar (Sunnfjord) and about 750°C, 20 kbar (Møre og Romsdal) at the metamorphic climax.
4. This metamorphism was of Caledonian age, probably rather early in the Caledonian tectonic history of the BGC and is considered to have been a rather transient event.
By setting these conclusions in a framework provided by geophysical evidence for the deep structure of the crust in southern Norway we have constructed a geotectonic model to explain the recorded metamorphic history of the BGC. It is suggested that considerable crustal thickening was caused by imbrication of the Baltic plate margin during continental collision with the Greenland plate. This resulted in high pressure metamorphism in the resulting nappe stack. Progradation of the suture caused underthrusting of the Baltic foreland below the eclogite-bearing terrain causing it to emerge at the Earth's surface, aided by tectonic stripping and erosion.
Application of isostacy equations to the model shows that eclogites can be formed by in-situ metamorphism in crustal rocks and reappear at the land surface above a normal thickness of crust in a single orogenic episode of approximately 65-70 Ma duration.     

A new interpretation of terraces in the Taranto Gulf: the role of extensional faulting

The Taranto Gulf of southern Italy provides an excellent case where it is possible to document the importance of normal faults in displacing terraced deposits. The study area is located at the front of the southern Apennines, that is a fold-and-thrust belt developed following the closure of the Mesozoic Tethys Ocean, and the deformation of the Adriatic passive margin during Tertiary and Quaternary times. The outer, eastern parts of the belt were structured in Quaternary, i.e. up to Middle Pleistocene times.The front of the chain is partially sealed by Pliocene–Pleistocene foredeep deposits, which represent the infill of the Bradanic Trough. The upper portion of the middle Pleistocene succession consists of marine sands and conglomerates that in the previous literature have been arranged in several orders of terraces. Analysis of aerial photographs and geomorphological mapping has shown the occurrence of prominent geomorphic lineaments, which appear to control the local drainage pattern. Some of these structures coincide with the map trace of normal faults that produce vertical offsets of the marine terrace surfaces in the order of ca. 10 m each. Many of the fault escarpments reduce their elevation and terminate laterally. In other cases fault escarpments are laterally continuous and can be traced for up to 3–4 km. Scarp height is between 2 and 10 m. Their mean trend ranges from NNE–SSW to ENE–WSW and defines an arcuate pattern that mimics the present coastline.An accurate geomorphological, sedimentological and stratigraphic analysis has been carried out in a selected area of the Bradanic Trough (Pisticci transect) to investigate in detail the relationships between normal faults and the development of the terraces. This analysis allowed us to recognise five facies associations related to the upper and lower beachface and to the neritic clays which represent the substratum of the terraces. More importantly, we observed that all the terraced deposits in the Pisticci transect could be referred to a single sedimentary body displaced by faults. The terraced deposits are related to an event of beach progradation, of Middle Pleistocene age, which has been documented in other areas of the Italian peninsula. These results outline an intimate relationship between the arcuate trend of the recognised fault set and the present coastline pattern. The development of the normal faults can be related to large-scale gravitational processes developed after the general tilting towards the SE of the Bradanic Trough.     

Depositional history and sequence stratigraphy of Tirgan formation (Barremian-Aptian) in central Kopet Dagh, NE Iran

The Tirgan Formation (Barremian — Aptian) is exposed in the Kopet Dagh in northeast Iran. Two stratigraphic sections in Radkan and Chenaran were measured. Their thickness are 238 m and 119 m, respectively. This formation in measured sections consists of three parts (including lower carbonate, middle limy shale — marl and upper carbonate rocks). Based on study of 164 thin-sections, 15 carbonate and 2 siliciclastic lithofacies have been identified. Carbonate lithofacies are deposited in a ramp platform in fore shoal, shoal, lagoon and tidal flat environments. Sea level changes during lower Cretaceous led to the formation of different large-scale depositional sequences Radkan (two) and Chenaran (two) respectively. The present study highlights the reconstruction of tectonic history of the area during lower Cretaceous.     

Discharge of biogenic substances with river runoff in Selenga basin

Averaged many-year measurement data on the concentrations of mineral forms of biogenic elements are analyzed, and their total concentrations in the rivers of Selenga, Chikoi, Khilok, Uda, Dzhida, and Temnik are evaluated. The monthly variations of the concentrations of major biogenic substances are characterized, and their ratios within a year are determined. Characteristics of river water runoff and biogenic substance concentrations are used to evaluate their within-year discharge by rivers. Characteristic variations in the ratios between the total and mineral forms of biogenic elements discharged by rivers have been revealed. It is established that the share of mineral components in the total input into the Selenga delta N_tot and P_tot are 82 and 22%, respectively.     

BIFoR FACE: Water–soil–vegetation–atmosphere data from a temperate deciduous forest catchment,including under elevated CO2

The ecosystem services provided by forests modulate runoff generation processes, nutrient cycling and water and energy exchange between soils, vegetation and atmosphere. Increasing atmospheric CO₂ affects many linked aspects of forest and catchment function in ways we do not adequately understand. Global levels of atmospheric CO₂ will be around 40% higher in 2050 than current levels, yet estimates of how water and solute fluxes in forested catchments will respond to increased CO₂ are highly uncertain. The Free Air CO₂ Enrichment (FACE) facility of the University of Birmingham's Institute of Forest Research (BIFoR) is the only FACE in mature deciduous forest. The site specializes in fundamental studies of the response of whole ecosystem patches of mature, deciduous, temperate woodland to elevated CO₂ (eCO₂). Here, we describe a dataset of hydrological parameters – seven weather parameters at each of three heights and four locations, shallow soil moisture and temperature, stream hydrology and CO₂ enrichment – retrieved at high frequency from the BIFoR FACE catchment.     

Chemical spots on the surface of the strongly magnetic Herbig Ae star HD 101412

Due to the knowledge of the rotation period and the presence of a rather strong surface magnetic field, the sharp‐lined young Herbig Ae star HD 101412 with a rotation period of 42 d has become one of the most well‐studied targets among the Herbig Ae stars. High‐resolution HARPS polarimetric spectra of HD 101412 were recently obtained on seven different epochs. Our study of the spectral variability over the part of the rotation cycle covered by HARPS observations reveals that the line profiles of the elements Mg, Si, Ca, Ti, Cr, Mn, Fe, and Sr are clearly variable while He exhibits variability that is opposite to the behaviour of the other elements studied. Since classical Ap stars usually show a relationship between the magnetic field geometry and the distribution of element spots, we used in our magnetic field measurements different line samples belonging to the three elements with the most numerous spectral lines, Ti, Cr, and Fe. Over the time interval covered by the available spectra, the longitudinal magnetic field changes sign from negative to positive polarity. The distribution of field values obtained using Ti, Cr, and Fe lines is, however, completely different compared to the magnetic field values determined in previous low‐resolution FORS 2 measurements, where hydrogen Balmer lines are the main contributors to the magnetic field measurements, indicating the presence of concentration of the studied iron‐peak elements in the region of the magnetic equator. Further, we discuss the potential role of contamination by the surrounding warm circumstellar matter in the appearance of Zeeman features obtained using Ti lines. (© 2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)