Evaluation of ferrous and ferric Mössbauer fractions

The Mössbauer fractions f for various ferrous- and/or ferric-containing oxides and oxyhydroxides, silicates and carbonates were evaluated from the experimental temperature dependence of their center shifts, using the Debye approximation for the second-order Doppler shift. It is concluded that ferrous ions exhibit a lower fraction as compared to ferric ions. Using standard mixtures of -Fe₂O₃ with selected Fe²⁺ or Fe³⁺ compounds, it is found that the calculated Fe³⁺ f values are somewhat overestimated with respect to those of Fe²⁺. Possible explanations for this shortcoming are discussed and it is suggested that a different temperature dependence of the intrinsic isomer shift is the most likely reason. This suggestion is corroborated by analyses of hematite and hedenbergite data which are available for temperatures up to 900 K and 800 K respectively.     

Vibrationally excited molecular hydrogen in circumstellar clouds and the interstellar CH+ abundance

The production of CH⁺ in dense interstellar clouds under intense UV irradiation is discussed. A model applicable to the cloud towards the star 20 Tau is described.     

Nutrient mediated stress on the marine communities of a coastal lagoon (Puerto Galera, Philippines)

Puerto Galera Bay is a coastal lagoon with a variety of marine habitats and high species diversity. It is an area in the Phillippines where the growing influence of human activities is affecting the quality of its marine resources. This study examined the distribution and behaviour of nutrients and the physical hydrography of Puerto Galera Bay and determined how its physico-chemical nature affected the condition of biotic components in the bay. The relative importance of the nitrogen and phosphorus signals were used as indicators to implicate the influence of sewage and run-off into the bay. A nutrient pool accumulated in the bay as a result of low flushing rates. The interaction of hydrodynamic forcing with the biota have implications on the phytoplankton production and coral communities in the area.     

Mineral Composition of Manganese Crusts from Belyaevskii Volcano (Sea of Japan)

Doklady Earth Sciences - The polygenic mineral composition of Mn crusts from Belyaevskii Volcano of the Central Basin of the Sea of Japan is determined. The crusts are found for the first time to...     

Change in the degree of catagenesis and hydrocarbon generation in the sedimentary rocks of the South Sumatra Basin,Indonesia

Temperature and catagenetic history of the South Sumatra Basin in Indonesia is considered by the example of the sedimentary sequence of the Limau graben during its subsidence from the Oligocene to the present time. GALO system for basin modeling was applied for numerical reconstruction of six sedimentary successions in the area of holes Pandan-81, Petanang-1, Tepus-2, Tepus-1, Gambir-1, and Lembak-8 located along the profile cutting across the Limau graben. Modeling suggests significant cooling of the basemen for the last 15–20 Ma from the high initial heat flow of 105 mW/m², which is typical of axial zones of continental rifting, and significant heating of the basin lithosphere during the last 2–5 Ma. Examination of variations in tectonic subsidence of the basin confirms the possible extension of the lithosphere in the Oligocene-Miocene with an amplitude β increasing from 1.12 on the flanks of the Limau graben (Hole Lembak-8) to 1.32 in the central part of the graben (Tepus-1 and 2), Tectonic analysis indicates also the notable thermal activation of the basin in the Pliocene, Pleistocene, and Holocene. This activation is consistent with the high temperature gradient typical of the present-day sedimentary cover of the basin. Numerical modeling of the evolution of the organic matter maturity and hydrocarbon generation by main source formations of the basin confirms good prospects of the inferred source formations (Lemat, Talang Akar, and Gumai) of the South Sumatra basin for the generation of liquid hydrocarbons (HC) in the Limau Graben. It is also demonstrated that the source rocks of the Lemat Formation are ore-generating rocks in the main part of the Limau graben and are gas-generating rocks only in the deepest portions of the graben. The rocks at the base and roof of the Talang Akar Formation could be considered as highly oil-generating rocks, probably except for the upper horizons of the formation in the shallowest portions of the graben (Hole Lembak-8). Oil generation reached peak in the last 5–10 Ma. Modeling showed that intense oil generation by the Gumai Formation may be significant in the most part of the Limau graben and negligible only in the distant flanks of the graben (Hole Lembak-8).     

Characterizing heterogeneous permeable media with spatial statistics and tracer data using sequential simulated annealing

Characterizing heterogeneous permeable media using flow and transport data typically requires solution of an inverse problem. Such inverse problems are intensive computationally and may involve iterative procedures requiring many forward simulations of the flow and transport problem. Previous attempts have been limited mostly to flow data such as pressure transient (interference) tests using multiple observation wells. This paper discusses an approach to generating stochastic permeability fields conditioned to geologic data in the form of a vertical variogram derived from cores and logs as well as fluid flow and transport data, such as tracer concentration history, by sequential application of simulated annealing (SA). Thus, the method incorporates elements of geostatistics within the framework of inverse modeling. For tracer-transport calculations, we have used a semianalytic transit-time algorithm which is fast, accurate, and free of numerical dispersion. For steady velocity fields, we introduce a transit-time function which demonstrates the relative importance of data from different sources. The approach is illustrated by application to a set of spatial permeability measurements and tracer data from an experiment in the Antolini Sandstone, an eolian outcrop from northern Arizona. The results clearly reveal the importance of tracer data in reproducing the correlated features (channels) of the permeability field and the scale effects of heterogeneity.     

THERMALLY DRIVEN SORPTION,DESORPTION, AND MOISTURE MIGRATION IN THE ACTIVE LAYER IN CENTRAL ALASKA

Combined observations of hourly soil temperature and electric potential, the latter converted to a relative index of soil-water solute concentration, yield information on the physical chemistry of near-surface frost effects. Solute concentration near the descending 0° C isotherm in the refreezing active layer above permafrost is divided into three distinct zones: (1) an ion-enriched zone in the unfrozen active layer that precedes the penetrating freezing front; (2) an ion-purified desorbed zone at the freezing front that is the source region of the downward-expelled ions and water; and (3) a hydrologically isolated subfreezing zone of enhanced solute concentration located above the freezing isotherm. High-frequency fluctuations superimposed on these general patterns are traceable to vapor migration driven by surface thermal fluctuations. These effects diminish at temperatures below about -0.4° C, as permeability decreases with soil-ice formation. The combined temperature-solute concentration time series is used to develop sorption curves for the frozen organic and mineral soils, and indicates that approximately half of the pore water present in the mineral soil at -0.4° C had not been converted to ice at -6° C. Gradual soil desiccation over winter appears to result from outward vapor diffusion, possibly through soil cracks. [Key words: Alaska, active layer, frozen ground, soil temperature, soil water, permafrost.]     

An evaluation of methodologies for the generation of stochastic hydraulic conductivity fields in highly heterogeneous aquifers

 Stochastic techniques, such as Monte Carlo experiments, are more and more frequently used for the study of flow and transport in heterogeneous aquifers. When the aquifer is composed of distinct hydrofacies, a common way to model heterogeneity is to first generate equally-possible hydrofacies fields, and then convert these hydrofacies fields into hydraulic conductivity (K) fields by assigning a single K value to each facies. This technique assumes relative homogeneity of K within each facies but may not be appropriate for the most conductive facies that often exhibits substantial variability. In this paper, we assessed the impacts of assigning multiple random K, rather than a uniform K value, to the highly conductive facies on the results of a flow and transport model. A set of fifty stochastic hydrofacies maps depicting an environment similar to the Snake River Plain aquifer (SRPA) in south-east Idaho were generated. Simulations demonstrated that a uniform K value, if carefully chosen, can reasonably reproduce the specific discharges and early particle arrival times produced by multiple K values. Yet, the results obtained with a uniform K value are dramatically less variable than those obtained with multiple K values. It is therefore concluded that stochastic simulations with uniform K assigned to the most conductive and variable facies do not necessarily portray the entire uncertainty in the analyses.     

Estimation of heterogeneous reaction rates for stratospheric trace gases with particular reference to the diffusional uptake of HCl and ClONO2 by polar stratospheric clouds

The stratosphere holds a variety of particulates like polar stratospheric clouds (PSCs) and sulphate aerosols which catalyse chemical reactions. These reactions cause changes in the composition of the stratosphere, including the redistribution of active chlorine which might lead to ozone destruction. As a result during recent years a lot of effort has been directed towards the quantification of the uptake of trace gases like ClONO₂, HCl, etc. into these particulates. However, it has been observed that many of the two and three dimensional models used in such studies are constrained by the lack of adequate rate constant data. This paper describes a theoretical approach to estimate the reaction rate constants for 23 gases on both types of polar stratospheric clouds (type I and II). It is found that for gases like N₂O₅, ClONO₂ and HCl, diffusional uptake is important and contributes significantly to the heterogeneous reaction rate. A complete Lennard-Jones calculation is used to accurately compute the trace gas diffusion coefficients.