A robust algorithm for ellipse-based discrete element modelling of granular materials

With recent research indicating the importance of the rolling mechanism of deformation in granular systems consisting of perfectly round particles, it has become popular to use ellipse-shaped particles in the Discrete Element Method (DEM) numerical model. Inherent in this technique is the need for accurately computing ellipse to ellipse intersection, in order to properly detect contact formation and compute relative contact velocities. However, the commonly used algorithms for computing ellipse-ellipse intersection are generally poorly conditioned and can be inaccurate. An alternate method for computing ellipse-ellipse intersection is developed and presented which results in a well-conditioned, stable and accurate contact detection method. These modification are incorporated into the general DEM algorithm.     

Mantle(?) xenoliths in the carbonatites of northern Transbaikalia

The composition and nature of high-Cr minerals in lithic clasts from the carbonatites of the Veseloe occurrence, northern Transbaikalia, were considered. In order to determine their source, the Cr-bearing phases were compared with chromite, magnetite, and rutile from ultrabasic rocks, mantle xenoliths, and eclogites. It was suggested that the xenoclasts studied were formed at great depths, whereas the carbonatites were directly derived from the mantle rather than formed by the crustal differentiation of a silicate-carbonate melt.     

Solubility of alumina in orthopyroxene plus spinel as a geobarometer in complex systems. Applications to spinel-bearing alpine-type peridotites

The addition of Fe and Cr to the simple system MgO-SiO₂-Al₂O₃ markedly affects the activities of phases involved in the equilibrium

Evidence for focused hot fluid flow within the Britannia Field, offshore Scotland, UK

Fluid inclusion and scanning electron microscope‐cathodoluminescence evidence indicates focused hot, saline, diagenetic fluid flow within the Eastern Flank of the Britannia Field, offshore Scotland, UK. The fluid was sourced from the Andrew Salt Dome, 10 km to the east. The fluids, which promoted quartz cementation of the upper zones within the field, were up to ～30°C hotter and had salinities up to ～10 wt% NaCl equivalent higher than fluids from lower in the reservoir section. During diagenesis hot saline fluids migrated westwards as part of a radiating ‘diagenetic front’ from the Andrew Salt Dome. Structural dip associated with the Eastern Flank of the Fladen Ground Spur impeded the westward movement of the diagenetic fluid. The quartz cements from the upper and lower reservoir zones can be distinguished by morphology. In the upper zones the quartz cements have well‐developed macro‐crystalline zoning and heterogeneous luminescence across the grain. In the lower zones, the cements are much less developed, unzoned and very weakly luminescent. The diagenetic fluids were primarily focused into Zone 45 within the upper reservoir. Furthermore, within the Main Platform Area the most prolific producing zone is Zone 45, indicating the importance of this interval as a permeable flow unit during both diagenetic and production timescales. Within the Eastern Flank, the quartz overgrowths have a major impact on reservoir permeability and thus well productivity. The overgrowths are most extensive in the originally clean sandstones with low clay content. Clay in optimum volumes (5–10%) can inhibit nucleation of the damaging quartz overgrowths without having a detrimental effect on pore connectivity. These observations provide a predictive concept for use in the search for relative reservoir sweetspots within the degraded Eastern Flank.     

Trace-element composition and zoning in clinopyroxene- and amphibole-group minerals: Implications for element partitioning and evolution of carbonatites

The present work is a first comprehensive study of the trace-element composition and zoning in clinopyroxene- and amphibole-group minerals from carbonatites, incorporating samples from 14 localities worldwide (Afrikanda, Aley, Alnö, Blue River, Eden Lake, Huayangchuan, Murun, Oka, Ozernaya Varaka, Ozernyi, Paint Lake, Pinghe, Prairie Lake, Turiy Mys). The new electron-microprobe data presented here significantly extend the known compositional range of clinopyroxenes and amphiboles from carbonatites. These data confirm that calcic and sodic clinopyroxenes from carbonatites are not separated by a compositional gap, instead forming an arcuate trend from nearly pure diopside through intermediate aegirine–augite compositions confined to a limited range of CaFeSi₂O₆ contents (15–45 mol%) to aegirine with < 25 mol% of CaMgSi₂O₆ and a negligible proportion of CaFeSi₂O₆. A large set of LA-ICPMS data shows that the clinopyroxenes of different composition are characterized by relatively low levels of Cr, Co and Ni (≤ 40 ppm) and manifold variations in the concentration of trivalent lithophile and some incompatible elements (1–150 ppm Sc, 26–6870 ppm V, 5–550 ppm Sr, 90–2360 ppm Zr, and nil to 150 ppm REE), recorded in some cases within a single crystal. The relative contribution of clinopyroxenes to the whole-rock Rb, Nb, Ta, Th and U budget is negligible. The major-element compositional range of amphiboles spans from alkali- and Al-poor members (tremolite) to Na–Al-rich Mg- or, less commonly, Fe-dominant members (magnesiohastingsite, hastingsite and pargasite), to calcic–sodic, sodic and potassic–sodic compositions intermediate between magnesio-ferrikatophorite, richterite, magnesioriebeckite, ferri-nyböite and (potassic-)magnesio-arfvedsonite. In comparison with the clinopyroxenes, the amphiboles contain similar levels of tetravalent high-field-strength elements (Ti, Zr and Hf) and compatible transition elements (Cr, Co and Ni), but are capable of incorporating much higher concentrations of Sc and incompatible elements (up to 500 ppm Sc, 43 ppm Rb, 1470 ppm Sr, 1230 ppm Ba, 80 ppm Pb, 1070 ppm REE, 140 ppm Y, and 180 ppm Nb). In some carbonatites, amphiboles contribute as much as 25% of the Zr + Hf, 15% of the Sr and 35% of the Rb + Ba whole-rock budget. Both clinopyroxenes and amphiboles may also host a significant share (~ 10%) of the bulk heavy-REE content. Our trace-element data show that the partitioning of REE between clinopyroxene (and, in some samples, amphibole) and the melt is clearly bimodal and requires a revision of the existing models assuming single-site REE partitioning. Clinopyroxenes and amphiboles from carbonatites exhibit a diversity of zoning patterns that cannot be explained exclusively on the basis of crystal chemistry and relative compatibility of different trace-element in these minerals. Paragenetic analysis indicates that in most cases, the observed zoning patterns develop in response to removal of selected trace elements by phases co-precipitating with clinopyroxene and amphibole (especially magnetite, fluorapatite, phlogopite and pyrochlore). With the exception of magnesiohastingsite–richterite sample from Afrikanda, the invariability of trace-element ratios in the majority of zoned clinopyroxene and amphibole crystals implies that fluids are not involved in the development of zoning in these minerals. The implications of the new trace-element data for mineral exploration targeting REE, Nb and other types of carbonatite-hosted rare-metal mineralization are discussed.