Indirect tensile test assessments for rock materials using 3-D disc-type specimens

Indirect test methods are usually the preferred approach for determining the tensile strength of brittle and quasi-brittle materials such as ceramics, rocks, and concrete. In this paper, the tensile strength of a rock material (Iranian Harsin marble) was obtained indirectly by means of two disc type samples. The test samples were the well-known Brazilian disc and semi-disc specimen under three-point bend loading. Since the existing formula for determining the indirect tensile strength is based on 2-D stress assumption which ignores the effects of specimen thickness, a general 3-D tensile strength formulation was derived for each sample by employing finite element analysis. A series of tensile strength tests were conducted on Harsin white marble using disc and semi-disc specimens with different thicknesses in parallel to finite element analysis. The test results using 3-D formulation showed that the tensile strength of the tested marble depends on the thickness/diameter ratio of the specimen and generally decreases from 11.5 to 7 MPa on increasing the thickness of test samples. The average values of tensile strength were about 8.8 MPa for the Brazilian disc specimen and 9.8 MPa for the semi-disc specimen. The good agreement existing between the results of the two specimens suggests that the semi-disc specimen can also be used for determining the rock tensile strength in addition to using the conventional Brazilian test.     

X-ray absorption contrast images of binary chemical reactions

Low-divergence synchrotron-sourced X-rays enable a radiographic imaging scheme for full characterization of binary chemical reactions and characterization by type of more complex reactions, in situ, in diamond anvil cells (DAC). Spatially resolved reactants are induced to react by laser heating of their interface. The spatially intermediate products are observed through X-ray absorption contrast. Limits to the technique include the ability to maintain controlled experiment geometry during compression and the ability to resolve chemical differences between reactants and products by X-ray absorption. The ability to make in situ observations at experimental pressure and temperature obviates the problem with quenching techniques for capturing liquid compositions in experiments with dimensions smaller than the diffusion length during quenching time. Partially molten Fe-alloy systems, of poor quenchability, are examined at DAC pressures and temperatures for relevance to Earth's core constitution and evolution. Determinations of eutectic melting in Fe–FeS match known results. Of the probable light elements that may alloy with Fe in the Earth's liquid outer core, Fe–FeS experiments show only modest quenching problems, but C and Si alloy experiments are highly vulnerable to quenching artifacts. The observed reactivity of FeS, Fe₃C, FeSi, and FeO(OH) with Fe in DAC makes the observed non-reactivity between Fe and FeO more significant, reducing the probability that oxygen alone is the major alloy in Earth's molten outer core.     

Automated Extraction of a Five‐Year LA‐ICP‐MS Trace Element Data Set of Ten Common Glass and Carbonate Reference Materials: Long‐Term Data Quality,Optimisation and Laser Cell Homogeneity

LA‐ICP‐MS is increasingly applied to obtain quantitative multi‐element data with minimal sample preparation, usually achieved by calibration using reference materials (RMs). However, some ubiquitous RMs, for example the NIST SRM 61× series glasses, suffer from reported value uncertainties for certain elements. Moreover, no long‐term data set of analyses conducted over a range of ablation and tuning conditions exists. Thus, there has been little rigorous examination of the extent to which offsets between measured and reported values are the result of error in these values rather than analytically induced fractionation. We present new software (‘LA‐MINE’), capable of extracting LA‐ICP‐MS data with no user input, and apply this to our system, yielding over 5 years of data (~ 5700 analyses of ten glass and carbonate RMs). We examine the relative importance of systematic analytical bias and possible error in reported values through a mass‐specific breakdown of fourteen of the most commonly determined elements. Furthermore, these data, obtained under a wide range of different ablation conditions, enable specific recommendations of how data quality may be improved, for example the role of diatomic gas, the effect of differential inter‐glass fractionation factors and choice of transport tubing material. Finally, these data demonstrate that the two‐volume Laurin ablation cell is characterised by no discernible spatial heterogeneity in measured trace element ratios.     

Geoarchaeological evidence on a Late Bronze Age earthquake,Ohrid Basin (North Macedonia)

Geoarchaeological investigations on the northeastern shore of Lake Ohrid revealed 3.5 m thick deepwater lacustrine sediments overlying terrestrial vegetation macrofossils, worked wood and abundant potsherds dated to the Late Bronze Age (LBA). Distinct contact of deepwater sediment with the sub-aerial weathered limestone bedrock point to a sudden increase in lake level. According to radiocarbon data, catastrophic flooding occurred shortly after 1214 yr bc. Because the area is located in a highly active seismic zone, we propose that this event was caused by tectonically induced, metre-scale coseismic subsidence related to faults bordering the Ohrid alluvial plain. Moreover, this event coincides well with a dramatic switch in the habitation and settlement strategy in the region. More important, however, is the finding that the age of the proposed massive tectonic event and change in habitation lies within the interval of the proposed ‘earthquake storm’ in the eastern Mediterranean dated to 1225–1175 bc. As the Ohrid-Korça zone belongs to the same tectonic province, a relationship between the abovementioned earthquakes and the proposed event can be expected. This research therefore might provide the first direct evidence of a large-scale earthquake event linkable to the LBA collapse of Europe's first urban civilisation in the Aegean.     

Removal of diazinon pesticide from aqueous solutions using MCM-41 type materials: isotherms,kinetics and thermodynamics

In this research, ordered mesoporous silica, including MCM-41, was synthesized via sol–gel process and a propyl methacrylate-modified ordered mesoporous silica (MPS-MCM-41) was successfully synthesized via a postsynthesis grafting process. Then both MCM-41 and MPS-MCM-41 were characterized using FTIR, XRD, SEM and BET techniques. The synthesized materials were utilized as adsorbent for removal of diazinon pesticide from aqueous solutions. The effects of pH, contact time, adsorbent dose, initial concentration and temperature have been evaluated using removal efficiencies. Also, the kinetic, thermodynamic and isotherm models of diazinon adsorption were studied for the both MCM-41 and MPS-MCM-41. The results showed that the maximum adsorption capacities are 142 and 254 mg g^?1 for the MCM-41 and MPS-MCM-41, respectively, at the initial concentration of 50 mg L^?1, temperature of 298 K and adsorbent dose of 0.1 g L^?1. The highest percentages of diazinon removal are 56.4 and 87.2 (at adsorbent dose of 2 g L^?1 and the temperature of 318 K) for the MCM-41 and MPS-MCM-41, respectively. The Freundlich and Langmuir models are more compatible for describing equilibrium data of the diazinon adsorption capacity on the MCM-41 and MPS-MCM-41, respectively. Thermodynamic study indicated that the adsorption process of diazinon onto MCM-41 and MPS-MCM-41 is exothermic and has a spontaneous nature. The higher adsorption capacity and higher spontaneous nature of MPS-MCM-41 in comparison with MCM-41 might be due to the presence of the both hydrogen bonding and hydrophobic interaction between surface functional groups of MPS-MCM-41 (hydroxyl and propyl methacrylate) and diazinon functional groups.     

Algal Dynamics in Relation to Physico-Chemical Factors in a High Altitude Pond of Shillong,India

A one year phycological study of a high altitude pond has been made with a view to studying the algal dynamics as affected by physico-chemical characteristics of the water. This has revealed the presence of 34 genera of algae belonging to Chlorophyta, Bacillariophyta, Cyanophyta, and Euglenophyta. Chlorophytes were the most dominant and diatoms the most frequent representatives of algae. The community diversity along with water chemistry are indicative of the oligotrophic nature of this pond.     

Impact melting of the Cachari eucrite 3.0 Gy ago

Both the host phase and glass veins of the Cachari eucrite have been analyzed by microprobe and neutron activation analysis for their chemical compositions and by mass spectrometry for their ³⁹Ar-⁴⁰Ar gas retention ages. Cachari is chemically similar to other non-cumulate eucrites. The vesicular glass veins vary from pure glass, to devitrified glass, to areas that are substantially crystalline. The glassy areas have nearly the same concentrations of major and trace elements as the unmelted portions of Cachari, but some differences, probably due to preferential dissolution, occur along melt contacts. The glass formed by shock melting of Cachari host or of rock identical to it. ³⁹Ar-⁴⁰Ar data for the host and glass suggest distinctly different ages of 3.04 ±.07 Gy and 3.47 ±.04 Gy, respectively. The time of glass formation, which may also be the time of brecciation, is most likely given by the 3.0 Gy age of the host. The higher age for the glass is interpreted to represent incomplete Ar degassing during the 3.0 Gy event due to the greater resistance to Ar diffusion shown by the glass compared to the host. Event ages significantly younger than 4.5 Gy have now been determined for several eucrites and howardites and suggest a long dynamic regolith history for the parent body.     

Backward modeling of the rifting kinematics in the Upper Rhine Graben: insights from an elastic-perfect contact law on the restoration of a multi-bloc domain

This paper addresses the problem of volume restoration for 3-D sedimentary basin kinematic deformation. The primary purpose is methodological and concerns the use of contact mechanics with the finite element method, in order to deform a geological multi-bloc domain. This approach is applied to backward model the later stage of rifting of a segment of the southern Upper Rhine Graben (France–Germany border). Preliminary results from our modeling demonstrate the ability of the method not only to handle complex geometries, but also to successfully perform retro-deformation of a complex geological domain. In addition, they provide or confirm crucial information on the rifting evolution and tectonic features of this segment of the Upper Rhine Graben, such as the distribution of deformation, the asymmetry of the graben and a significant left-lateral strike-slip component of displacement.     

Non-Homogeneous Charge-Consistent Model for Acceleration of Iron in the Solar Corona

Acceleration of iron ions by a spherical shock wave moving through non-homogeneous solar corona is considered. The energy dependence of the mean charge of iron, _Fe(E), is determined by the characteristic acceleration time, T _a, trapping time, T _tr, and time for charge changes, T _q. The latter varies along with plasma number density during the propagation of the shock wave in the corona. Our calculations have demonstrated that adiabatic energy changes, Coulomb losses and shock broadening do not sufficiently influence the dependence _Fe(E). According to our estimations, the photoionizing processes can scarcely affect the ionic states of accelerated iron, except probably for the most powerful X10 class events.