From the pore scale to the lab scale: 3-D lab experiment and numerical simulation of drainage in heterogeneous porous media

A well-controlled 3-D experiment with pre-defined block heterogeneities is conducted, where neutron tomography is used to map 3-D water distribution after two successive drainage steps. The material and hydraulic properties of the two sands are first measured in the laboratory with multistep outflow experiments. Additionally, the pore structure of the sands is acquired by means of image analysis of synchrotron tomography data and the structure is used for pore-scale simulation of one- and two-phase flow with Lattice-Boltzmann methods. This gives us another set of material and hydraulic parameters of the sands. The two sets of hydraulic properties (from the lab scale and from the pore scale) are then used in numerical simulations of the 3-D experiment.     

Framboidal sulphides precipitated synthetically

Framboidal sulphides of iron, copper, lead, zinc, nickel and arsenic have been precipitated from aqueous solutions by hydrogen sulphide in the absence of any bacterial agency. The formation of framboids is considered to be a normal result of the precipitation of discrete sulphide particles in suspension from reactants in true solution at a concentration between twice and ten times the solubility of the sulphides. The preservation of framboids demands protection from further access to a solvent within a few days of precipitation. The significance of the formation and preservation of framboids in sedimentary and magmatic rocks and in the genesis of stratiform sulphide ores is discussed and the role of organic material in sediments is suggested.

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Zusammenfassung Eisen-, Kupfer-, Blei-, Zink-, Nickel- und Arsensulfid-Himbeeren wurden durch Schwefelwasserstoff-Fällung, unter Ausschluß von Bakterieneinwirkungen, erhalten. Die Bildung der Himbeeren wird als normales Resultat der Fällung begrenzter Sulfid-Einzelteilchen angesehen, wie sie aus 2- bis 10-fach übersättigten echten Lösungen entstehen. Nach der Fällung bleiben die Himbeeren eine Woche erhalten, danach nur, wenn das Lösungsmittel zu ihnen keinen weiteren Zutritt erlangt. Die Bedeutung der Bildung und Erhaltung von Himbeeren in sedimentären und magmatischen Gesteinen, sowie der Entstehungsprozeß von Sulfiderzschichten, wird besprochen und die Annahme diskutiert, daß organischem Material in Sedimenten eine bestimmte Rolle zukommt.

     

The ionic conductivity in high-pressure polymorphs of calcite

Ionic conductivity of polycrystalline calcite containing varying amounts of PO ₄ ^3? ions was measured in the pressure range of 1–6 GPa and at room temperature. Electrical conductivity increased with pressure corresponding to the phase transition of calcite I to calcite II. The conductivity in calcite III decreased exponentially with pressure. Calculated activation volumes of the conductivity varied with PO ₄ ^3? content in the range of 0.94–5.34 cm³/mol. This variation corresponded to the lattice parameter change of calcite I due to PO ₄ ^3? incorporation and indicated the contribution of CO ₃ ^2? -vacancies associated with PO ₄ ^3? ions to the conductivity.     

Middle Eocene‐Oligocene broken‐foreland evolution in the Andean Calchaqui Valley,NW Argentina: insights from stratigraphic,structural and provenance studies

Two end‐member models have been proposed for the Paleogene Andean foreland: a simple W‐E migrating foreland model and a broken‐foreland model. We present new stratigraphic, sedimentological and structural data from the Paleogene Quebrada de los Colorados (QLC) Formation, in the Eastern Cordillera, with which to test these two different models. Basin‐wide unconformities, growthstrata and changes in provenance indicate deposition of the QLC Formation in a tectonically active basin. Both west‐ and east‐vergent structures, rooted in the basement, controlled the deposition and distribution of the QLC Formation from the Middle Eocene to the Early Miocene. The provenance analysis indicates that the main source areas were basement blocks, like the Paleozoic Oire Eruptive Complex, uplifted during Paleogene shortening, and that delimits the eastern boundary of the present‐day intraorogenic Puna plateau. A comparison of the QLC sedimentary basin‐fill pattern with those of adjacent Paleogene basins in the Puna plateau and in the Santa Bárbara System highlights the presence of discrete depozones. These reflect the early compartmentalization of the foreland, rather than a stepwise advance of the deformation front of a thrust belt. The early Tertiary foreland of the southern central Andes is represented by a ca. 250‐km‐wide area comprising several deformation zones (Arizaro, Macón, Copalayo and Calchaquí) in which doubly vergent or asymmetric structures, rooted in the basement, were generated. Hence, classical foreland model is difficult to apply in this Paleogene basin; and our data and interpretation agree with a broken‐foreland model.     

Numerical Simulation of the Sensitivity of Summer Monsoon Circulation and Rainfall over India to Land Surface Processes

—The influence of soil moisture and vegetation variation on simulation of monsoon circulation and rainfall is investigated. For this purpose a simple land surface parameterization scheme is incorporated in a three-dimensional regional high resolution nested grid atmospheric model. Based on the land surface parameterization scheme, latent heat and sensible heat fluxes are explicitly estimated over the entire domain of the model. Two sensitivity studies are conducted; one with bare dry soil conditions (no latent heat flux from land surface) and the other with realistic representation of the land surface parameters such as soil moisture, vegetation cover and landuse patterns in the numerical simulation. The sensitivity of main monsoon features such as Somali jet, monsoon trough and tropical easterly jet to land surface processes are discussed.¶Results suggest the necessity of including a detailed land surface parameterization in the realistic short-range weather numerical predictions. An enhanced short-range prediction of hydrological cycle including precipitation was produced by the model, with land surface processes parameterized. This parameterization appears to simulate all the main circulation features associated with the summer monsoon in a realistic manner.     

A statistical model for vesuvius and its volcanological implications

The last 300 years of Vesuvius history are reconstructed as a chronological succession of 4 phenomenological states: i) repose, ii) persistent activity, iii) intermediate eruption and iv) final eruption. It turns out that the times of permanence in each state are distributed according to the same exponential law. Vesuvius activity is then described by a Markov chain of these 4 states, with transition probabilities determined from the previous phenomenological analysis. The model reproduces the Vesuvius activity between 1694 and 1872 and possibly also in the 1872–1944 period. It turns out that, at least between 1694 and 1872, the volcano was behaving like a quasistationary system with 4 equilibrium states, perturbed by a stochastic noise responsible for occasional transitions from an equilibrium state to another. Major physical or structural changes of the volcanic system around 1872 and possibly in the whole subsequent period, are clearly shown by the statistical analysis.     

Pile foundation analysis and design using experimental data and 3-D numerical analysis

Capacity based design of pile foundations limits the soil-structure interaction mechanism to group bearing capacity estimation, neglecting, in most cases, the contribution of the raft. On the other hand, a straightforward, nonlinear, 3-D analysis, accounting for soil and structural nonlinearities and the effects arising from pile–soil–pile interaction, would be extremely high CPU-time demanding and will necessitate the use of exceptionally powerful numerical tools. With the aim of investigating the most efficient, precise, and economical design for a bridge foundation, a hybrid method, compatible with the notion of sub-structuring is proposed. It is based on both experimental data and nonlinear 3-D analysis. The first step to achieve these targets is a back-analysis of a static pile load test, fitting values for soil shear strength, deformation modulus, and shear strength mobilization at the soil–pile interface. Subsequently, the response of 2 × 2 and 3 × 3 pile group configurations is numerically established and the distribution of the applied load to the raft and the characteristic piles is discussed. Finally, a design strategy for an optimized design of pile raft foundations subjected to non-uniform vertical loading is proposed.     

The warm pool in the Indian Ocean

The structure of the warm pool (region with temperature greater than 28°C) in the equatorial Indian Ocean is examined and compared with its counterpart in the Pacific Ocean using the climatology of Levitus. Though the Pacific warm pool is larger and warmer, a peculiarity of the pool in the Indian Ocean is its seasonal variation. The surface area of the pool changes from 24 × 10⁶ km² in April to 8 × 10⁶ km² in September due to interaction with the southwest monsoon. The annual cycles of sea surface temperature at locations covered by the pool during at least a part of the year show the following modes: (i) a cycle with no significant variation (observed in the western equatorial Pacific and central and eastern equatorial Indian Ocean), (ii) a single maximum/minimum (northern and southern part of the Pacific warm pool and the south Indian Ocean), (iii) two maxima/minima (Arabian Sea, western equatorial Indian Ocean and southern Bay of Bengal), and (iv) a rapid rise, a steady phase and a rapid fall (northern Bay of Bengal).     

Geochemistry, K–Ar geochronology and Sr–Nd–Pb isotope compositions of pitchstone in Gohado, southwestern Okcheon Belt, South Korea

Abstract Geochemical and Sr–Nd–Pb isotope characteristics, as well as K–Ar geochronology of a massive pitchstone (volcanic glass) stock erupted into Late Cretaceous lapilli tuff and rhyolite in the Gohado area, southwestern Okcheon Belt, South Korea, are reported. The pitchstones are highly evolved with SiO₂ contents ranging from ～72 to 73 wt%, K₂O/Na₂O ratios of 1.04–1.23 and low MgO/FeO^t values (0.17–0.20). The pitchstones are weakly peraluminous and the ASI (molar Al₂O₃/Na₂O + K₂O + CaO) values are significantly lower than 1.1. The pitchstones also display a general calc‐alkaline nature with significant alkali contents. The rare earth elements (REE) compositions show moderately fractionated nature with (La/Yb)_N ranging from 11 to 16. Chondrite normalized REE patterns show relative enrichment of light REE over heavy REE and moderate Eu anomaly (Eu/Eu* ratio varies from 0.53 to 0.57). A distinct negative Nb anomaly is observed for all pitchstones on a primitive mantle normalized trace element diagram, typical of subduction‐related magmatism and crustal‐derived granites. All these features are characteristic of I‐type granites derived from a continental arc. The pitchstones have Zr contents of 98.5–103.5 ppm with zircon thermometry yielding temperatures of 749–755°C (mean 752°C). The K–Ar analyses of representative pitchstone samples yielded ages of 58.7 ± 2.3 and 62.4 ± 2.1 Ma with a mean age of 61 Ma. The rocks show nearly uniform initial ⁸⁷Sr/⁸⁶Sr isotopic ratios of 0.7104–0.7106 and identical ¹⁴³Nd/¹⁴⁴Nd initial ratio of 0.5120. The rocks display negative εNd (61 Ma) values of ?12. The depleted mantle model ages (T_DM) range from 1.54 Ga to 1.57 Ga. The Pb isotope ratios are ²⁰⁶Pb/²⁰⁴Pb = 18.522–18.552, ²⁰⁷Pb/²⁰⁴Pb = 15.642–15.680 and ²⁰⁸Pb/²⁰⁴Pb = 38.794–38.923. These ratios suggest that the Gohado pitchstones were formed in a continental arc environment by partial melting of a 1.54 Ga to 1.57 Ga parental sources of lower crustal rocks probably of mafic or intermediate compositions.