Geochemistry and Crustal Evolution of Volcano-sedimentary Successions and Orthogneisses in the São Gabriel Block, Southernmost Brazil — Relics of Neoproterozoic Magmatic Arcs

Precambrian metaplutonic rocks of the São Gabriel block in southernmost Brazil comprise juvenile Neoproterozoic calc-alkaline gneisses (Cambaí Complex). The connection with associated (ultra-)mafic metavolcanic and metasedimentary rocks (Palma Group) is not well established. The whole complex was deformed during the Brasiliano orogenic cycle. Both metasedimentary and metavolcanic rocks as well as metaplutonic rocks of the Cambaí Complex have been sampled for geochemical analyses in order to get constraints on the tectonic setting of these rocks and to establish a tectonic model for the São Gabriel block and its role during the assembly of West-Gondwana. The major element compositions of the igneous rocks (Palma Group and Cambaí Complex) indicate a subalkaline character; most orthogneisses have a calc-alkaline chemistry; many metavolcanic rocks of the Palma Group show signatures of low-K tholeiitic volcanic arc basalts. Trace element data, especially Ti, Zr, Y, Nb, of most igneous samples from both the lower Palma Group and the Cambaí Complex indicate origin at plate margins, i.e., in a subduction zone environment. This is corroborated by relative enrichment in LREE, low contents of Nb and other high field strength elements and enrichment in LILE like Rb, Ba, and Th. The data indicate the possible existence of two suites, an oceanic island arc and a continental arc or active continental margin. However, some ultramafic samples of the lower Palma Group in the western São Gabriel block indicate the existence of another volcanic suite with intra-plate character which possibly represents relics of oceanic island basalts (OIB). Trace element data indicate contributions from andesitic to mixed felsic and basic arc sources for the metasedimentary rocks. The patterns of chondrite- and N-MORB-normalized spider diagrams resemble the patterns of the igneous rocks, i.e., LILE and LREE enrichment and HFS depletion. The geochemical signatures of most igneous and metasedimentary samples and their low (⁸⁷Sr/⁸⁶Sr)_t ratios suggest only minor contribution of old continental crust.A geotectonic model for the São Gabriel block comprises east-ward subduction and following accretion of an intra-oceanic island arc to the eastern border of the Rio de la Plata Craton at ca. 880 Ma, and westward subduction beneath the newly formed active continental margin between ca. 750 and 700 Ma. The São Gabriel block represents relics of an early Brasiliano oceanic basin between the Rio de la Plata and Kalahari Cratons. This ocean to the east of the Rio de la Plata Craton might be traced to the north and could possibly be linked with Neoproterozoic juvenile oceanic crust in the western Brasília belt (Goiás magmatic arc).     

Geochemical transport modelling of drainage from experimental mine tailings cells covered by capillary barriers

The use of covers with capillary barrier effects (CCBEs) for reducing acid mine drainage (AMD) from sulphidic mine tailings is simulated using the MIN3P finite volume model for coupled groundwater flow, O₂ diffusion and multi-component reactive transport. The model is applied to simulate five pilot-scale in situ test cells containing reactive tailings from the Manitou mine site, Val d’Or, Que., Canada. Four of the cells were constructed with CCBEs over the tailings, while the fifth tailings cell was left uncovered. Observed and simulated discharge from the base of each cell showed that the capillary barrier covers significantly reduced sulphide oxidation and AMD. Compared to acidic discharge from the uncovered cell, discharge from the four CCBE-covered cells had neutral pH levels and 1–7 orders of magnitude lower concentrations of SO₄, Fe, Zn, Cu and Al. The simulations showed that the moisture retaining layer of the CCBEs reduced AMD by inhibiting O₂ diffusion into the underlying reactive wastes. Provided the moisture-retention layer of the CCBE remains close to saturation, its thickness had a relatively minor effect. Under such near-saturated conditions, O₂ availability is limited by its diffusion rate through the bulk porous medium and not by the diffusion rate through the oxidized grain shells. The model is providing important new insights for comparing design alternatives for reducing or controlling AMD.     

3D model of deep structure of the Early Precambrian crust in the East European Craton and paleogeodynamic implications

The integral 3D model of the deep structure of the Early Precambrian crust in the East European Craton is based on interpretation of the 1-EU, 4B, and TATSEIS seismic CDP profiles in Russia and the adjacent territory of Finland (FIRE project). The geological interpretation of seismic images of the crust is carried out in combination with consideration of geological and geophysical data on the structure of the Fennoscandian Shield and the basement of the East European platform. The model displays tectonically delaminated crust with a predominance of low-angle boundaries between the main tectonic units and the complex structure of the crust-mantle interface, allowing correlation of the deep structure of the Archean Kola, Karelian, and Kursk granite-greenstone terrane with the Volgo-Uralia granulite-gneiss terrane, as well as the Paleoproterozoic intracontinental collision orogens (the Lapland-Mid-Russia-South Baltia orogen and the East Voronezh and Ryazan-Saratov orogens) with the Svecofennian accretionary orogen. The lower crustal “layer” at the base of the Paleoproterozoic orogens and Archean cratons was formed in the Early Paleoproterozoic as a result of underplating and intraplating by mantle-plume mafic magmas and granulite-facies metamorphism. The increase in the thickness of this “layer” was related to hummocking of the lower crustal sheets along with reverse and thrust faulting in the upper crust. The middle crust was distinguished by lower rigidity and affected by ductile deformation. The crust of the Svecofennian Orogen is composed of tectonic sheets plunging to the northeast and consisting of island-arc, backarc, and other types of rocks. These sheets are traced in seismic sections to the crust-mantle interface.     

Approaches for comparative evaluation of raster GIS-based landslide susceptibility zonation maps

Evaluation of maps generated from different conceptual models or data processing approaches at spatial level has importance in many geoenvironmental applications. This paper addresses the spatial comparison of different landslide susceptibility zonation (LSZ) raster maps of the same area derived from various procedures.     

Formation Conditions of Runoff and Hydrological–Morphological Processes in Deltas in Permafrost Zone: The Deltas of the Lena and Mackenzie Rivers

Water Resources - The article presents a study of the hydrological regime of the Lena and Mackenzie rivers, flowing in the zone of permafrost rocks of different types. Features typical of river...     

Global plasmaspheric TEC and its relative contribution to GPS TEC

The plasmaspheric electron content is directly estimated from the global positioning system (GPS) data onboard JASON-1 Satellite for the first time. Similarly, the ground-based GPS total electron content (TEC) is estimated using about 1000 GPS receivers distributed around the globe. The relative contribution of the plasmaspheric electron content to the ground-based GPS TEC is then estimated globally using these two independent simultaneous measurements; namely ground-based GPS TEC and JASON-1 GPS TEC. Results presented here include data from 3 months of different solar cycle conditions (October 2003, May 2005, and December 2006). The global comparison between the two independent measurements was performed by dividing the data into three different regions; equatorial, mid- and high-latitude regions. This division is essential as the GPS raypaths traverse different distances through the plasmasphere at different latitudes. The raypath length through the plasmasphere decreases as latitude increases. The relative contribution of the plasmaspheric electron content exhibits a diurnal variation that depends on latitude with minimum contribution (10%) during daytime and maximum (up to 60%) at night. The contribution is also maximum at the equatorial region where the GPS raypath traverses a long distance through the plasmasphere compared to its length in mid- and high-latitude regions. Finally, the solar cycle variation of plasmaspheric contribution is also reported globally.     

Integrating lysimeter drainage and eddy covariance flux measurements in a groundwater recharge model

Abstract

Field-scale water balance is difficult to characterize because controls exerted by soils and vegetation are mostly inferred from local-scale measurements with relatively small support volumes. Eddy covariance flux and lysimeters have been used to infer and evaluate field-scale water balances because they have larger footprint areas than local soil moisture measurements. This study quantifies heterogeneity of soil deep drainage (D) in four 12.5-m² repacked lysimeters, compares evapotranspiration from eddy covariance (ET_EC) and mass balance residuals of lysimeters (ETwb_Lys), and models D to estimate groundwater recharge. Variation in measured D was attributed to redirection of snowmelt infiltration and differences in lysimeter hydraulic properties caused by surface soil treatment. During the growing seasons of 2010, 2011 and 2012, ETwb_Lys (278, 289 and 269 mm, respectively) was in good agreement with ET_EC (298, 301 and 335 mm). Annual recharge estimated from modelled D was 486, 624 and 613 mm for three calendar years 2010, 2011 and 2012, respectively. In summary, lysimeter D and ET_EC can be integrated to estimate and model groundwater recharge.

Editor D. Koutsoyiannis     

Responses of marine phytoplankton in iron enrichment experiments in the northern North Sea and northeast Atlantic Ocean

Short-term iron enrichment experiments were carried out with samples collected in areas with different phytoplankton activity in the northern North Sea and northeast Atlantic Ocean in the summer of 1993. The research area was dominated by high numbers of pico-phytoplankton, up to 70,000 ml⁻¹. Maximum chlorophyll a concentrations varied from about 1.0 μg l⁻¹ in a high-reflectance zone (caused by loose coccoliths, remnants from a bloom of Emiliania huxleyi) and about 3.5 μg l⁻¹ in a zone in which the phytoplankton were growing, to about 0.5 μg l⁻¹ in the northeast Atlantic Ocean. From the high-reflectance zone to the northeast Atlantic Ocean, nitrate concentrations increased from 0.5 μM to 6.0 μM. Concentrations of reactive iron in surface water showed an opposite trend and decreased from about 2.6 nM in the high-reflectance zone to <1.0 nM in the northeast Atlantic Ocean. In the research area, no signs of true iron deficiency were found, but iron enrichments in the high-reflectance zone, numerically dominated by Synechococcus sp., resulted in increased nitrate uptake. Ammonium uptake was hardly affected. Strong support for the effect of Fe on cell physiology is given by the increase in the f-ratio. Net growth rates of the phytoplankton (changes in cell numbers over 24 h) were almost unchanged. Phytoplankton collected from the northeast Atlantic Ocean, did not show changes in the nitrogen metabolism upon addition of iron. Net growth rates in these incubations were low or negative, with only slightly higher values with additional iron.