Surface-water quality for the Salí River watershed in NW Argentina

Spatial and temporal variations of Na, Mg, Si, K, Ca, SO₄^2-, Cl^-, HCO₃^-, Ag, Al, As, Au, B, Ba, Be, Bi, Br, Ce, Cd, Co, Cr, Cs, Cu, Dy, Er, Eu, F, Fe, Ga, Ge, Gd, Hf, Hg, Ho, I, La, Li, Mn, Mo, Nb, Nd, Ni, P, Pb, Pr, Rb, Sb, Sm, Sn, Sr, Ta, Tb, Te, Th, Ti, Tl, U, V, W, Y, Yb, Zn, and Zr were monitored through 37 sampling stations to determine the main aspects influencing the surface-water quality in the Salí River watershed (Tucumán Province, NW Argentina). The influence of the regional geological setting on water chemistry allows to distinguish three sub-basins. The interaction with sedimentary rocks was found to be dominant in the northern and central-eastern sub-basin as well as in the southern sub-basin, whereas the metamorphic-granitic basement of the Pampean Ranges was noted in the central sub-basin. In addition, anthropogenic activities affect the spatial variation of K, P, Mn, Rb, and Pb as well as dissolved oxygen concentrations and Eh. Temporal water-quality variation is related to the spatial distribution of precipitation and to the seasonal character of the main local industries (sugar cane, alcohol, citrus), increasing P and K concentrations and decreasing dissolved oxygen concentration and Eh in winter. Cl^-, Na, SO₄^2-, Al, As, B, Fe, Mn, Se and U concentrations exceed the regulated drinking-water thresholds at several sampling stations.     

Cosmogenic radiocarbon as a means of studying solar activity in the past

A series of yearly data on the concentration of radioactive carbon ¹⁴C in tree rings measured at the Tbilisi State University in 1983–1986 and covering the time interval 1600–1940 is statistically analyzed. We find evidence for a 22-year cyclicity in the intensity of Galactic cosmic rays (GCRs) during the Maunder minimum of the solar activity (1645–1715), testifying that the solar dynamo mechanism continued to operate during this epoch. Variations of Δ¹⁴C on timescales of tens and hundreds of years correlate well with the corresponding variations of the GCR intensity and solar activity, making radiocarbon a reliable source of information on long-timescale variations of solar activity in the past. Short-timescale (<30 years) fluctuations of Δ¹⁴C may be appreciably distorted by time variations not associated directly with solar activity; probable origins of this distortion are discussed.     

Model of a multiscaled MHD dynamo

A simple model for a multiscaled MHD dynamo is suggested. The uppermost tier of the model controls the evolution of the large-scale magnetic field, while the lower tiers are responsible for the evolution of the small-scale velocity and magnetic fields. This approach makes it possible to reproduce, e.g., the evolution of the Galactic magnetic field for realistic magnetic Reynolds numbers, which cannot be done using direct, detailed simulations.     

Mineralized Microbiota: A Possible Indicator of Hydrocarbon Flows in the Rift Zone of Iceland

Relationships of mineralized microbiota with the content of polycyclic aromatic hydrocarbons in hydrothermal systems are considered. It has been established that the mineralized microbiota can serve as an indicator of hydrothermal hydrocarbon flows in present-day and ancient deposits.     

Reliability based risk index for the design of reinforced earth structures

The design methods currently used for earth reinforcement are mostly based on deterministic properties of both the soil and the construction materials used. Nowadays, however, the general trend is designing at a specific degree of reliability. This is even more true where the raw data such as soil properties exhibit significant variation. Deterministic solutions, in this case, may not suffice. Therefore, this paper will attempt to use probabilistic formulations thereby modifying the existing design procedure of reinforced earth retaining walls to account for uncertainties and variabilities. Through a first order Taylor's series expansion about the mean, the mean and variance of the strip reinforcing components, namely width and length, are derived in terms of the variations in the soil properties. Design charts that enable estimation of both mean and variance are developed to avoid extensive partial differentiation involved in the computations. Using appropriate probability distributions along with the mean and variance, the final design outputs are determined for a selected failure probability by introducing what is refered to as 'risk index'. The results indicate that the risk index increases with an increase in the coefficient of variations and a decrease in failure probability. Furthermore, it is shown that in some cases, depending on the variabilities of the soil properties, the classical design technique produced a relatively high failure probability. This revised version was published online in July 2006 with corrections to the Cover Date.     

Simulation of marine boundary layer characteristics using a 1-D PBL model over the Bay of Bengal during BOBMEX-99

The characteristic features of the marine boundary layer (MBL) over the Bay of Bengal during the southwest monsoon and the factors influencing it are investigated. The Bay of Bengal and Monsoon Experiment (BOBMEX) carried out during July–August 1999 is the first observational experiment under the Indian Climate Research Programme (ICRP). A very high-resolution data in the vertical was obtained during this experiment, which was used to study the MBL characteristics off the east coast of India in the north and south Bay of Bengal. Spells of active and suppressed convection over the Bay were observed, of which, three representative convective episodes were considered for the study. For this purpose a one-dimensional multi-level PBL model with a TKE-ε closure scheme was used. The soundings, viz., the vertical profiles of temperature, humidity, zonal and meridional component of wind, obtained onboard ORV Sagar Kanya and from coastal stations along the east coast are used for the study. The temporal evolution of turbulent kinetic energy, marine boundary layer height (MBLH), sensible and latent heat fluxes and drag coefficient of momentum are simulated for different epochs of monsoon and monsoon depressions during BOBMEX-99.The model also generates the vertical profiles of potential temperature, specific humidity, zonal and meridional wind. These simulated values compared reasonably well with the observations available from BOBMEX.     

Age of Detrital Zircons from Sandstones of the Mesozoic Flysch Formation in the South Anyui Suture Zone (Western Chukotka)

The South Anyui fold zone (western Chukotka) is considered a suture zone related to closure of the South Anyui oceanic basin and collision of Eurasia with the Chukotka–Arctic Alaska microcontinent in the Early Cretaceous. The existence of a compensatory sedimentation basin (foredeep) during folding in the terminal Jurassic–initial Cretaceous remains debatable. This work presents first data on age estimates of detrital zircons from Upper Mesozoic terrigenous sequences of the South Anyui suture zone obtained by the fission-track method. The distal flysch of presumably Late Jurassic age and the proximal flysch of probably Late Triassic age were sampled in the Uyamkanda River basin. The fission-track dating showed that sandstones from the flysch sections contain detrital zircons of two different-age populations. Young zircon populations from sandstones of distal turbidites in the upper course of the Uyamkanda River (two samples) are 149 ± 10.2 and 155.4 ± 9.0 Ma old (Late Jurassic), whereas those from coarse-grained proximal turbidites sampled in the lower course of the Uyamkanda River (one sample) is 131.1 ± 7.5 Ma old (Early Cretaceous). The data obtained indicate that the Late Mesozoic folding in the South Anyui suture zone was accompanied by the formation of a marginal sedimentary basin. Sediments accumulated in this basin compose tectonic nappes that constitute a fold–thrust structure with the northern vergence.     

Compression mechanisms of coesite

 The structure of coesite has been determined at ten pressures up to a maximum of 8.68 GPa by single-crystal X-ray diffraction. The dominant mechanism of compression is the reduction of four of the five independent Si–O–Si angles within the structure. There is no evidence of the fifth linkage, Si1–O1–Si1, deviating from 180°. Some Si–O bond distances also decrease by up to 1.6% over the pressure range studied. The pattern of Si–O–Si angle reduction amounts to a rotation of the Si2 tetrahedron around the [001] direction. This rotation induces significant internal deformation of the Si1 tetrahedron. Comparison of the experimental data with rigid-unit distance least-squares simulations of coesite suggests that this pattern of compression, the anomalous positive values of both s₂₃ and K′′ in the equation of state of coesite, its high elastic anisotropy and the unusual straight Si1–O1–Si1 linkage within the structure are all consequences of the connectivity of the tetrahedral framework. Received: 11 July 2002 / Accepted: 14 January 2003 Acknowledgements The help of Christian Baerlocher of ETH Zurich in providing both the DLS-76 software and advice in its use is gratefully acknowledged, as are discussions with Paul Ribbe of Virginia Tech and the comments of two anonymous reviewers. The data analysis was supported by the National Science Foundation under grant EAR-0105864 to N.L. Ross and R.J. Angel.