Research Results on Ecological Hazard Objects in Abrosimov Bay (Novaya Zemlya,Kara Sea)

Oceanology - The article presents results of field research on environmental assessment in Abrosimov Bay (Yuzhny Island of Novaya Zemlya) in connection with the existing RW disposal sites in this...     

Tackling social exclusion in European neighbourhoods: experiences and lessons from the NEHOM project

Disadvantaged urban neighbourhoods with their complex social, economic and physical situations have increasingly become the focus of governmental policies in the EU. The emphasis has shifted from improving physical qualities to building opportunities for social groups in these areas. While physical upgrade is easier to achieve, at least in the short run, initiatives often fail in outcomes on communities and local participation. This paper aims to improve understanding on how to tackle area-based social exclusion and create socially coherent communities. Building on the results of the NEHOM project, the focus is on examining how various interventions have impacted local communities and their opportunities for better inclusion. A comparison between neighbourhoods shows that mixing social groups to a certain degree is likely to be a necessary step towards opening long-term opportunities for a disadvantaged neighbourhood. The planned initiatives should at the same time directly benefit local communities, and the involvement of local groups in the planning and implementation process helps to guarantee that the overall changes are accepted by the local community. However, the proposed guidelines do not provide a universal recipe for a successful renewal suiting each neighbourhood—the contextual matters should always be a starting point when planning an initiative.     

Investigations on the Quaternary Glaciation in the Khumbu Himal (Nepal, East-Himalaya)

Based on geomorphological field work the mapping of former lateral/terminal moraines in the middle segment of the Bhotekoshi Nadi is quite similar to the geomorphological findings of Heuberger (1956: Fig. 2). The deductive calculation of the equilibrium line altitudes is oriented on the reconstructed types of former glaciers. Based on the geomorphological findings of this valley segment the relation of Neoglacial and Late Glacial ice margins of the glaciers of the tributary valleys of the Bhotekoshi Nadi is not conclusive. A post-late glacial maximum snow-line depression of at least 950 m has not obligatory caused an ice fill of the Bhotekoshi Nadi below 3200 m. This revised version was published online in July 2006 with corrections to the Cover Date.     

Contrasting geochemical signatures on land from the Middle and Late Permian extinction events

The end of the Palaeozoic is marked by two mass‐extinction events during the Middle Permian (Capitanian) and the Late Permian (Changhsingian). Given similarities between the two events in geochemical signatures, such as large magnitude negative δ¹³C anomalies, sedimentological signatures such as claystone breccias, and the approximate contemporaneous emplacement of large igneous provinces, many authors have sought a common causal mechanism. Here, a new high‐resolution continental record of the Capitanian event from Portal Mountain, Antarctica, is compared with previously published Changhsingian records of geochemical signatures of weathering intensity and palaeoclimatic change. Geochemical means of discriminating sedimentary provenance (Ti/Al, U/Th and La/Ce ratios) all indicate a common provenance for the Portal Mountain sediments and associated palaeosols, so changes spanning the Capitanian extinction represent changes in weathering intensity rather than sediment source. Proxies for weathering intensity chemical index of alteration, ?W and rare earth element accumulation all decline across the Capitanian extinction event at Portal Mountain, which is in contrast to the increased weathering recorded globally at the Late Permian extinction. Furthermore, palaeoclimatic proxies are consistent with unchanging or cooler climatic conditions throughout the Capitanian event, which contrasts with Changhsingian records that all indicate a significant syn‐extinction and post‐extinction series of greenhouse warming events. Although both the Capitanian and Changhsingian event records indicate significant redox shifts, palaeosol geochemistry of the Changhsingian event indicates more reducing conditions, whereas the new Capitanian record of reduced trace metal abundances (Cr, Cu, Ni and Ce) indicates more oxidizing conditions. Taken together, the differences in weathering intensity, redox and the lack of evidence for significant climatic change in the new record suggest that the Capitanian mass extinction was not triggered by dyke injection of coal‐beds, as in the Changhsingian extinction, and may instead have been triggered directly by the Emeishan large igneous province or by the interaction of Emeishan basalts with platform carbonates.     

Source(s) and cycling of the nonhydrolyzable organic fraction of oceanic particles

A major fraction of particulate organic carbon (POC) in the deep ocean remains molecularly uncharacterized. In an effort to determine the chemical characteristics and source(s) of sinking POC, we studied a nonhydrolyzable fraction of sinking POC using ¹³C NMR (nuclear magnetic resonance) spectroscopy and analytical pyrolysis. ¹³C NMR spectra and products from analytical pyrolysis of the nonhydrolyzable fraction exhibit a strongly aliphatic character that is distinct from that of bulk POC. The aliphatic nature of this fraction is consistent with its low stable carbon isotope values. We hypothesize that the nonhydrolyzable fraction derives to a significant extent from a refractory component of organisms that selectively accumulates, resulting in its manifestation as a major part of POC sinking to the deep ocean and in underlying sediments.     

Polycyclic aromatic hydrocarbons in commercial fish and lobsters from the coastal waters of Madagascar following an oil spill in August 2009

Concentrations of polycyclic aromatic hydrocarbons were determined in species of commercial fish and lobsters following an oil-spill just off the protected Madagascan coastline. Samples were collected along the coastline within and outside the affected area. Summed PAH concentrations ranged from 1.9 μg kg⁻¹ to 63 μg kg⁻¹ wet weight, but with no higher molecular weight PAHs (>202 Da) being detected. All concentrations of benzo[a]pyrene, benz[a]anthracene and dibenz[a,h]anthracene were <0.1 μg kg⁻¹ wet weight, well within the EU and UK set limits for the protection of human health. Additionally, samples were calculated as the benzo[a]pyrene toxic equivalency quotient (TEQ) and found to be well below the level of concern in relation to health of human consumers. Evaluation of the biota PAH data indicated the origin of PAH was predominantly petrogenic with >80% arising from oil sources. Profile studies indicate a low-level multisource petrogenic contamination probably representing a pre-spill background for the area.     

Couplage des équations de transfert de masse et des lois d''interactions solution-solide par l''utilisation des lanthanides comme traceurs — Approche expérimentale

In underground flow tracing studies, the estimation of the nature and the importance of interactions undergone by the substance used very often constitutes an obstacle to good modeling of mass-transfer processes in solution.

We propose a method to quantify these phenomena by the use of lanthanides as tracers.

For this study, we set up an analytical methodology adapted to routine measurements. The quality of five lanthanides as indicators has been examined. We have demonstrated the formation, by substitution, of a carbonate complex which is extremely stable in the natural environment. The field experiments carried out demonstrated the efficiency of those tracers and confirmed their great stability.

Tracer recovery graphs show that, in accord with our hypothesis, convection and dispersion are identical for all the lanthanide elements. Moreover, we have established a direct relation between their fixing rate on earth materials and the value of their stability constants.

Thus, we demonstrate the possibility of correlative multitracing, with known and quantifiable interelement relations.

Résumé

Dans les études de circulations souterraines par traceur, l'estimation de la nature et de l'importance des interactions subies par la substance utilisée constitue, bien souvent, un obstacle à une bonne modélisation des processus de transfert de masse en solution.

Nous proposons une méthode de quantification de ces phénomènes par l'utilisation des lanthanides comme traceurs.

Pour cette étude, nous avons mis au point une méthodologie analytique adaptée aux mesures de routine. Les qualités, en tant qu'indicateurs, de cinq lanthanides ont été examinées. Nous avons démontré la formation, par substitution, d'un complexe carbonaté extrèment stable en milieu naturel. Les expériences de terrain réalisées ont prouvé l'efficacité de ces traceurs et confirmé leur grande stabilité.

Les courbes de restitution obtenues ont montré que, conformément à nos hypothèses, la convection et la dispersion sont identiques pour l'ensemble de ces éléments. De plus, il a été établi une relation directe entre leurs taux de fixation sur le terrain et la valeur de leurs constantes de stabilité.

On dispose ainsi d'une possibilité de multitraçage corrélatif, avec des relations interélémentaires connues et quantifiables.     

Development of statistical seasonal prediction models of Arctic Sea Ice concentration using CERES absorbed solar radiation

Statistical seasonal prediction models for the Arctic sea ice concentration (SIC) were developed for the late summer (August-October) when the downward trend is dramatic. The absorbed solar radiation (ASR) at the top of the atmosphere in June has a significant seasonal leading role on the SIC. Based on the lagged ASR-SIC relationship, two simple statistical models were established: the Markovian stochastic and the linear regression models. Crossvalidated hindcasts of SIC from 1979 to 2014 by the two models were compared with each other and observation. The hindcasts showed general agreement between the models as they share a common predictor, ASR in June and the observed SIC was well reproduced, especially over the relatively thin-ice regions (of one- or multi-year sea ice). The robust predictability confirms the functional role of ASR in the prediction of SIC. In particular, the SIC prediction in October was quite promising probably due to the pronounced icealbedo feedback. The temporal correlation coefficients between the predicted SIC and the observed SIC were 0.79 and 0.82 by the Markovian and regression models, respectively. Small differences were observed between the two models; the regression model performed slightly better in August and September in terms of temporal correlation coefficients. Meanwhile, the prediction skills of the Markovian model in October were higher in the north of Chukchi, the East Siberian, and the Laptev Seas. A strong non-linear relationship between ASR in June and SIC in October in these areas would have increased the predictability of the Markovian model.