Biogeochemical factors influencing the residence time of microconstituents in a large tidal estuary, Delaware Bay

Generally the large tidal estuaries of the eastern United States, such as Delaware Bay, are characterized by rather high suspended particle concentrations at the landward end and high biological activity at the seaward end. As such, these estuaries can be conceptualized as geochemical and biochemical “reactors” for those processes controlling the transmission of trace elements from fresh to the coastal shelf waters. The efficiency of these reaction processes relative to estuarine flushing will control the residence times of microconstituents in such estuaries.Evidence is drawn from the Delaware estuary to illustrate biogeochemical estuarine reaction processes using salinity distribution data and mass balance calculations. The Delaware retains some of its estuarine trace elements as sedimented estuarine particles, while others are more conservative and largely exported. Those retained by sedimenting processes include trace elements in primarily geochemical (particle reactive) chemistries, while those exported appear recycled by biochemical (nutrient reactive) chemistries. Often, the behavior of trace elements (e.g., Fe, Cd) and nutrients (e.g., PO₄) appear biogeochemically linked. Other examples are drawn from mixing studies to illustrate particle interaction, and benthic flux measurements to illustrate limited diagenetic reflux.The residence time of estuarine microconstituents should depend seasonally on the relative turbidity, flushing rate, and primary production of tidally dominated estuaries such as the Delaware. Thus, residence times of the more biogeochemically reactive microconstituents must be substantially shorter (days to weeks) than the average flushing times of these larger estuaries, while the residence times of the less reactive ones should approach such flushing times (weeks to months). True estuarine residence times of microconstituents can only be modeled after using large data sets averaged over time (season, tides) and space (salinity).     

CHARACTERISTICS ON INTERANNUAL VARIATIONS OF NORTH PACIFIC SST AND ITS RELATION TO EAST ASIA CLIMATE

The interannual variations of the monthly sea surface temperature (SST) in the North Pacific (including Equatorial East Pacific) during 1951-1980 are analysed by means of EOF method. The findings are:(1) In the cold and warm ocean current areas, such as the North Pacific Current, the California Current and the Equatorial East Pacific areas, the convergence speeds are the fastest, while in the Kuroshio and the western part of the North Equatorial Current areas they are fast only in winter.(2) The physical features of the first 3 eigenvectors are obvious. The first eigenvector shows that the SST values are high in the south and low in the north in the latitudinal distribution of the SST field. The warm current area, i.e. the northwestern part of the North Pacific is positive and the cold current area, i.e. the southeastern part of the North Pacific including the Eastern Equatorial Pacific is negative. The zero line of the 2nd eigenvector field runs from northeast to southwest, in the same direction as the     

Phytoplankton productivity in relation to light intensity: A simple equation

A simple exponential equation is used to describe photosynthetic rate as a function of light intensity for a variety of unicellular algae and higher plants where photosynthesis is proportional to (1-e^−β1). The parameter β ( ) is derived by a simultaneous curve-fitting method, where I is incident quantum-flux density. The exponential equation is tested against a wide range of data and is found to adequately describe P vs. I curves. The errors associated with photosynthetic parameters are calculated. A simplified statistical model (Poisson) of photon capture provides a biophysical basis for the equation and for its ability to fit a range of light intensities. The exponential equation provides a non-subjective simultaneous curve fitting estimate for photosynthetic efficiency (a) which is less ambiguous than subjective methods: subjective methods assume that a linear region of the P vs. I curve is readily identifiable. Photosynthetic parameters β and a are used widely in aquatic studies to define photosynthesis at low quantum flux. These parameters are particularly important in estuarine environments where high suspended-material concentrations and high diffuse-light extinction coefficients are commonly encountered.     

A stochastic model of the atmospheric precipitation in the coastal zone of the Tropical Atlantic

A stochastic prognostic model of the atmospheric precipitation in the tropical area of the Atlantic Ocean is developed on the basis of a large data array. The data represent a series of monthly precipitation rates for 31 towns in the Republic of Guinea covering a period of 35–64 years as well as satellite data on the meridional displacement of the Intertropical Convergence Zone during 11 years. The model takes into account major regularities of the tropical precipitation: their impulsive periodic regime, trends, and the modulation of the stochastic component by the determined variability.Translated by Mikhai M. Trufanov.     

Joint Soviet-Turkish expedition in the Black Sea

The hydrological and hydrochemical structures of the upper 300 m water column of the Black Sea in autumn 1988 have been studied. Regularities in the distribution of the physico-chemical characteristics in the zone of interaction between aerobic and anaerobic waters as well as the topography of the H₂S zone boundary and its connection with a certain density gradient have been found.Translated by Mikhail M. Trufanov.     

Miocene extensional detachments in the outcropping basement of the northern Alboran Basin (Betics) and their tectonic implications

Whether or not there are extensional detachment faults in the Alboran basement can be tested directly because a part of the Alboran Basin is now emerged. These detachments, related to crustal thinning beneath the Alboran Basin, occurred from the Aquitanian to Tortonian. The resulting extensional geometries can be described in general terms. During the Serravalian a considerable southwest extension of the basin took place, accompanied by south-southeast extension in the northern Gibraltar Arc. Other detachments affected by Serravalian extension can be found. The spreading of the Alboran was nearly coeval with roughly westward migration of the Gibraltar mountain front.     

Well log interpretation and seismic character of the cenozoic sequence in the northern Alboran Sea

Seismic stratigraphic and main lithological features of the sedimentary cover overlying the basement of the Alboran Sea were established via the analysis of commercial multichannel seismic surveys, geophysical well logs, and well data. Six seismic stratigraphics units (VI to I), bounded by unconformities, form the marine sediments that range in age from early Miocene to Quaternary. They are dated by extrapolation of commercial drilling results from the northern Alboran Sea. Volcanic activity is recorded within sedimentary sequences of units V to II. Undercompaction features are detected in the two basal units.     

Carbon disulfide in the estuarine, coastal, and oceanic environments

The concentration of carbon disulfide (CS₂) in surface water and relevant hydrographic parameters were determined in coastal waters of the eastern USA (Delaware Bay and Chesapeake Bay, including the Potomac River; 7–11 September 1986). The CS₂ concentration varied extensively along the cruise track, from 4 to 510 pmol S(CS₂) l⁻¹ (n = 103). The average values in estuarine, shelf, and oceanic waters were found to be 118 ± 100 pmol S(CS₂) l⁻¹ (n = 54), 51 ± 34 pmol S(CS₂) l⁻¹ (n = 14), and 28 ± 12 pmol S(CS₂) l⁻¹ (n = 35), respectively. To help interpret the geochemical behavior of CS₂, we analyzed the depth distribution of CS₂ in the North Atlantic Ocean during an earlier cruise (23 April–2 May 1986). In most cases, these depth profiles show a near-surface maximum at about 10–20 m depth and a relatively steep gradient below this maximum. Based on the distribution pattern in the water column and evidence provided by earlier workers, we propose that diffusion of CS₂ from bottom sediments may contribute to CS₂ levels in surface seawater. The atmospheric concentration of CS₂ was also investigated at some locations during the September cruise. Except during periods when there was a significant anthropogenic input, the concentration of CS₂ in air was generally in the range of 4–15 pptv (parts per trillion by volume) with a mean of 10.4 ± 4.0 pptv (n = 10). The calculated sea-to-air emission rates of CS₂ at each of our sampling stations show a decreasing trend across estuarine, shelf, and oceanic areas, in agreement with the trend in surface water concentrations.