Bedded jaspers of the Ordovician Løkken ophiolite,Norway: seafloor deposition and diagenetic maturation of hydrothermal plume-derived silica-iron gels

Sedimentary beds of jasper (red hematitic chert) in the Ordovician Løkken ophiolite of Norway are closely associated with volcanogenic massive sulphide (VMS) deposits. The jaspers occur in the immediate hangingwall and laterally peripheral to the large Løkken (25–30 Mt) and small Høydal (0.1 Mt) VMS deposits, and are exposed discontinuously for several kilometres along strike. Massive or laminated types predominate; jasper-sulphide debris-flow deposits are also abundant near VMS deposits. The jaspers contain hematite-rich laminae showing soft-sediment deformation structures and microtextural evidence that record the presence of a colloidal precursor and an origin as gels. Early textures include: (1) straight or curved chains of hematitic filaments 3–10 µm in diameter and 20–100 µm long; (2) branching networks of 15–25 µm-thick, tubular structures surrounded by cryptocrystalline hematite and filled with quartz and euhedral hematite; (3) small (up to 10 µm) spherules composed of cryptocrystalline hematite and silica; and (4) up to 50 µm silica spherules with hematitic cores. The small filaments seem to have been deposited in varying proportions in the primary laminae, possibly together with hematitic and siliceous microspheroids. Diagenetic changes are represented by polygonal syneresis cracks, and the presence of cryptocrystalline (originally opaline) silica, chalcedony, quartz, carbonate and cryptocrystalline hematite and/or goethite forming botryoidal masses and spheroids <10 µm to 5 mm in diameter. Coarser euhedral grains of quartz, carbonate, and hematite are integral parts of these textures. Bleached, silica-rich jaspers preserve only small relics of fine-grained hematite-rich domains, and locally contain sparse pockets composed of coarse euhedral hematite±epidote. The jaspers are interpreted to record colloidal fallout from one or more hydrothermal plumes, followed by maturation (ageing) of an Si-Fe-oxyhydroxide gel, on and beneath the Ordovician sea floor. Small hematitic filaments in the jaspers reflect bacteria-catalysed oxidation of Fe ²⁺ within the plume. The larger tubular filaments resulted from either microbial activity or inorganic self-organized mineral growth of Fe-oxyhydroxide within the Si-Fe-oxyhydroxide gel after deposition on the sea floor, prior to more advanced maturation of the gel as represented by the spheroidal and botryoidal silica-hematite textures. Bleaching and hematite±epidote growth are interpreted to reflect heat and fluids generated during deposition of basaltic sheet flows on top of the gels.     

Critical depths for passage in braided rivers,Canterbury, New Zealand

Riffles and points of divergence of branch channels in braided rivers are critical controls upon passage of fish and recreational boats because they are points at which depths are at a minimum. Depths on randomly selected riffles were measured in braided reaches of the Ashley, Hurunui, and Rakaia Rivers and related to discharge; minimum depths encountered in extended reaches of these rivers at a range of flows have also been measured. The data can be used to predict minimum available passage depths at a specified flow, or conversely, to predict the discharge required to maintain a specified minimum passage depth. However, presently available estimates of critical minimum depths required for various instream uses (migration of salmonids, jetboating) appear excessively conservative, and minimum depth requirements must be more accurately determined before instream flow needs can be properly assessed.     

An automatic system for continuous monitoring of CO2, H2S, SO2 and meteorological parameters in the atmosphere of volcanic areas

An automatic system for the continuous monitoring of CO₂, H₂S, SO₂ and meteorological parameters in atmosphere has been developed. The system has been tested in the laboratory in order to verify the stability and reliability of each sensor and of the whole system. A field test for a period of one month, at the Solfatara of Pozzuoli has also been carried out. The acquired data during the field test reveal a correlation between the wind speed and the concentrations of CO₂, H₂S, and SO₂ in the atmosphere. With a wind speed of over 4 ms^-1 the concentration of the three gases reached constant background values of 600 ppm for CO₂ and about 2 ppm vol. for H₂S and SO₂. The different ratios of H₂S/SO₂ measured in the fumaroles (~100) and in the atmosphere (1–0.1) clearly indicate that H₂S is oxidized to SO₂ during the transport.     

Carbon cycling in a shallow turbid estuary of southeast Texas: The use of plant pigment biomarkers and water quality parameters

Particulate organic carbon (POC), dissolved organic carbon (DOC), and plant pigments (chlorophylls and carotenoids) were measured approximately bimonthly from March 1992 to October 1993 in the Sabine-Neches estuary (Sabine Lake region), located on the Texas-Louisiana border. High freshwater inflow into this shallow turbid estuary results in the shortest hydraulic residence time (ca. 7 d) of all Texas estuaries (Baskaran et al. in press). Annual averages of chlorophyll-a (3.0 μg l^?1) and particulate organic carbon (1.1 mg l^?1) in the water column were extremely low in comparison to other shallow estuaries. The highest chlorophyll-a concentrations were observed in October 1993, in the mid and lower regions of the estuary, during the lowest river discharge. Zeaxanthin and fucoxanthin concentrations suggested that much of the chlorophyll-a during this low flow period was represented by cyanobacteria and diatoms that entered from the Gulf of Mexico. The range of DOC concentrations was generally high (4.4–20.9 mg l^?1) and were significantly correlated with POC, but not with chlorophyll-a concentrations. When total suspended particulate (TSP) concentrations were below 20 to 30 mg l^?1, there were significant increases in %POC and %PON of the TSP. The unusually high POC: chlorophyll-a ratios (highest value of 1423) suggested that much of the POC contained low concentrations of chlorophyll-a that had degraded during transport from wetlands in the Sabine and Neches rivers. Based on these data, this estuary can be characterized as a predominantly heterotrophic system, with low light penetrance, short particle-residence times, high DOC, and low inputs from autochthonous carbon sources.     

Responses of marsh fishes and breeding wading birds to low temperatures: A possible behavioral link between predator and prey

In the Everglades of southern Florida, several species of spring- and winter-nesting wading birds (Ciconiiformes) often abandon their nests in response to periods of cold or wet and windy weather. Using stepwise logistic regression of a variety of hydrologic and meteorologic variables on the probability of great egret nest failure, we found that cold temperatures and high wind speeds were most closely associated with nest failure in the Everglades. Water level fluctuation was not a significant correlate of failure. Quantitative visual surveys in the field showed that even moderate cooling events (15°C minimum daily temperature) dramatically altered the observed densities of marsh fishes. In controlled conditions in the laboratory, we observed centrarchid, poeciliid, and cyprinodontid fishes during normal high (19–23°C) and simulated cold snap (8–11°C) temperatures. At low temperatures, the fishes exhibited reduced activity, sought refuge by hiding in vegetation and/or substrate, and fled our approach to the tank at much greater distances. Threshold temperatures for these behaviors varied considerably between the laboratory (9–11°C) and field (15–20°C), and may be explained by differences in the previous thermal experience of the two groups of fishes. We hypothesize that the temperature-induced scarcity of fishes during spring cold snaps is an important cause of disruption of nesting for several species of wading birds in the Everglades.     

Structural Setting of Strong Earthquakes in the Huabei Area of China

— Using P and S arrival times, which occurred within the Huabei seismic network, we carried out a tomographic inversion and compared results with the earthquake catalogue of the last 1000?years in the area. The results are as follows:¶1) The hypocenters of most of the strong shocks are distributed in the transitional zones between high- and low-velocity areas in the crust, especially at edges of high-velocity blocks.¶2) Strong shocks predominantly lie above low-velocity blocks, or in transitional zones between low- and high-velocity areas, in the lower crust.¶3) The tectonic settings for the Tangshan and the Sanhe-Pingu earthquakes are similar. Both are not known near large fault belts, and in zones with a sharp lateral velocity gradient.¶4) The Ninghe, Tangshan and Luanxia earthquakes are located in high-velocity blocks that differ in size and depth. This difference can explain the focal depth distribution of the Tangshan earthquake sequence, i.e., earthquakes are shallower in the northeastern Luanxian area but deeper in the southwestern Ninghe area.     

Negative δO values in Allan Hills 84001 carbonate: Possible evidence for water precipitation on mars

The Martian meteorite ALH84001 contains ∼1% by weight of carbonate formed by secondary processes on the Martian surface or in the shallow subsurface. The major form of this carbonate is chemically and isotopically zoned rosettes which have been well documented elsewhere. This study concentrates upon carbonate regions ∼200 μm across which possess previously unobserved magnesium rich inner cores, interpreted here as rosette fragments, surrounded by a later stage cement containing rare Ca-rich carbonates (up to Ca₈₁Mg₀₇Fe₀₄Mn₀₇) intimately associated with feldspar. High spatial resolution ion probe analyses of Ca-rich carbonate surrounding rosette fragments have δ¹⁸O_V-SMOW values as low as −10‰. These values are not compatible with deposition from a global Martian atmosphere invoked to explain ALH84001 rosettes. The range of δ¹⁸O values are also incompatible with a fluid that has equilibrated with the Martian crust at high temperature or from remobilisation of carbonate of rosette isotopic composition. At Martian atmospheric temperatures, the small CO₂(gas)-CO₂(ice) fractionation makes meteoric CO₂ an unlikely source for −10‰ carbonates. In contrast, closed system Rayleigh fractionation of H₂O can generate δ¹⁸O_H2O −30‰, as observed at high latitudes on Earth. We suggest that atmospheric transport and precipitation of H₂O in a similar fashion to that on Earth provides a source of suitably ¹⁸O depleted water for generation of carbonate with δ¹⁸O_V-SMOW = −10‰.     

Acoustic stratigraphy and hydrothermal activity within Epi Submarine Caldera,Vanuatu, New Hebrides Arc

Geological and geophysical surveys of active submarine volcanoes offshore and southeast of Epi Island, Vanuatu, New Hebrides Arc, have delineated details of the structure and acoustic stratigraphy of three volcanic cones. These submarine cones, named Epia, Epib, and Epic, are aligned east-west and spaced 3.5 km apart on the rim of a submerged caldera. At least three acoustic sequences, of presumed Quaternary age, can be identified on single-channel seismic-reflection profiles. Rocks dredged from these cones include basalt, dacite, and cognate gabbroic inclusions with magmatic affinities similar to those of the Karua (an active submarine volcano off the southeastern tip of Epi) lavas.     

Origin of flooding water through hydrogeochemical identification,the Buenos Aires plain,Argentina

Hydrogeochemical behaviour of samples of surface and groundwater collected on a cross-section from Mendoza to the Buenos Aires provinces was studied based on chemical trends, mass balance and water mixing. Hydrogeochemical modelling included major, minor elements as well as stable isotopes (deuterium and 18-O). The area investigated is located in the “Médanos Longitudinales” (longitudinal dunes) of the northwest of Buenos Aires province, Argentina. The study area is subject to alternating flooding and drought. Rainfall and surface water subsequently transferred by rivers, canals and lagoons have been usually considered responsible for local flooding. For this study, origins of excess water were investigated using physical and chemical characteristics of the water involved. The prevalence of groundwater inflow to rainfall events was proposed based on data interpretation. Groundwater influence of flows of local and intermediate nature were defined and the importance of recharge, transit and discharge zones was highlighted. Lagoon floodwater, as well as groundwater from observation wells and production boreholes, show components of intermediate origin. Regional recharge water was identified in Mendoza and San Luis provinces. Their discharge zone was inferred to be located beyond the Buenos Aires province.     

The IGS VTEC maps: a reliable source of ionospheric information since 1998

The International GNSS Service (IGS) Working Group on Ionosphere was created in 1998. Since then, the Scientific community behind IGS, in particular CODE, ESA, JPL and UPC, have been continuosly contributing to reliable IGS combined vertical total electron content (VTEC) maps in both rapid and final schedules. The details on how these products are being generated, performance numbers, proposed improvement as far as VTEC evolution trends during near one Solar Cycle, are summarized in this paper. The confirmation of (1) the good performance of the IGS combined VTEC maps, and (2) the characteristic VTEC variability periods, are two main results of this work.