A novel strategy using biodegradable EDDS for the chemically enhanced phytoextraction of soils contaminated with heavy metals

For the sake of cost and potential environmental risk, it is necessary to minimize the amount of chelates used in chemically-enhanced phytoextraction. In the present study, a biodegradable chelating agent, EDDS was added in a hot solution at 90℃ to the soil in which garland chrysanthemum （Chrysanthemum coronarium L.） and beans （Phaseolus vulgaris L., white bean） were growing. The application of hot chelate solutions was much more efficient than the application of normal chelate solutions （25℃） in improving the uptake of heavy metals by plants. When 1 mmol kg1 of EDDS as a hot solution was applied to soil, the concentrations ofCu, Zn and Cd and the total phytoextraction by the shoots of the two plant species exceeded or approximated those in the shoots of plants treated with 5 mmol kg^-1 of normal EDTA solution. The concentrations of metals in the shoots of beans were significantly correlated with the relative electrolyte leakage rate of root cells, indicating that the root damage resulting from the hot solution might play an important role in the process of chelate-enhanced metal uptake. The soil leaching study demonstrated that decreasing the dosage of chelate resulted in decreased concentrations of soluble metals in soils. On the 28th day following the application of chelate, the concentrations of soluble metals in the EDDS treated soil were not significantly different from the concentrations in the control soil to which chelates had not been applied.     

Permeable Reactive Barrier for the treatment of contaminated surface water in Katedan industrial development area, Hyderabad, India

Permeable Reactive Barrier （PRB） is an emplacement of inert material （s） in the subsurface, designed to intercept a contaminated plume, provides a preferential flow path through the reactive media, and transforms the contaminant into environmentally acceptable forms to attain concentration remediation goals at the discharge of the barrier. The phenomena, which help in remediation within PRB, are adsorption/sorption, precipitation, oxidation/reduction and biodegradation. Various materials like zero-valent iron, zero-valent bi-metals, natural zeolites, organic carbon, fly ash, zeolites, limestone, activated alumina, apatites, etc. have been tried by many researchers to remove organic and inorganic contaminants. In USA, Canada, and many European countries commercial full-scale and pilot scale PRBs are successfully working. The design and installation of full scale PRBs needs laboratory treatability and dynamic flow column experiments？ The concept of PRB is being applied to treat contaminated surface water in the Katedan industrial area, Hyderabad, India. National Geophysical Research Institute （NGRI）, Hyderabad, India, conducted systematic studies in collaboration with Norwegian Geotechnical Institute （NGI）, Norway, to develop PRB technique to decontaminate the surface water pollution due to industrial effluent. A site assessment study in the Katedan Industrial Area, were carried out and water, soil and sediment from the lakes of the area were found to be polluted with high concentrations of heavy metals like As, Pb, Cr, Cd, Ni, etc. Adsorption studies at NGRI with synthetic samples and in-situ industrial effluent using different reactive media for removing contaminants like arsenic, chromium, cadmium, copper, nickel, lead and zinc have been carried out and yielded satisfactory results. The performance of zero-valent iron and limestone is encouraging in removing As,     

THE INFLUENCE OF FERTILIZERS, NaHCO3,SOIL TYPE ON CHEMISTRY OF FLOODED SOILS AND RICE PLANT GROWTH

1 INTRODUCTIONQuality of chemical properties of flooded soils isgenerally determined by salinity and alkalinity,bothof these acts as inhibiting factors of plant growth.Thecorrelation of electrical conductivity and other analysisindex has been reported by …     

Naturally acidic and metalliferous waters at unmined volcanogenic massive sulfide deposits in the Bonnifield mining district, Alaska Range, east-central Alaska

The Bonnifield district hosts 26 tmmined volcanogenic massive sulfide （VMS） occurrences. Environmental geochemical samples of water and stream sediment were collected at several occurrences, concentrating on the two best-exposed and largest deposits, Red Mountain （RM） and Sheep Creek （SC）. Limited samples were also collected at the poorly exposed WTF deposit. The deposits are Late Devonian to Early Mississippian, and are hosted by felsic metavolcanic and carbonaceous schist members of the Totatlanika Schist or Keevy Peak Fm. Spring and stream waters at RM and SC have pH values commonly 〈3.5 （as low as 2.4 at RM and 2.5 at SC）, high conductivity （up to 11000 μS/cm）, and very high （Is to 100s mg/L） dissolved contents of Al, Cd, Co, Cu, Fe, Ni, and Pb. Waters at RM are characterized by extremely high REE contents （summed REE median 3200 μg/L, n=33）. At both RM and SC, pyrite oxidation and dissolution produce low pH waters that interact with and dissolve bedrock minerals, resulting in acidic, metal-laden, naturally degraded streams that are mostly devoid of aquatic life. Ferricrete is common. In contrast, WTF barely produces a surficial environmental footprint, mostly due to topography and relief. RM and SC are well exposed in the areas of relatively high relief, and both exhibit extensive areas of quartz-sericite-pyrite-alteration. While WTF shares many of the same deposit-and alteration characteristics, it is concealed by tundra in a large, nearly flat area. Surface water at WTF is absent and outcrops are sparse. Even though WTF is roughly the same size as Red Mountain （both around 3 million tonnes） and has similar base- and precious-metal grades, the surficial geochemical manifestation of WTF is minimal. However, exposure through mining of the altered, mineralized rock at WTF potentially could initiate the same processes of pyrite oxidation, acid generation, and mineral dissolution that are observed naturally at RM and SC.     

Changes to cadmium associations in canal sediments on drying and oxidation

The mainly 19th Century canal system in the UK, largely managed by British Waterways, has been increasingly brought back into operation over the last few decades, and is now widely used for both leisure, and, increasingly, transport. Both initial and routine dredging of the canal sediment is carried out and these sediments are generally disposed of to land. Because many of the canals were connected with primary industries, their sediments can locally be significantly contaminated with heavy metals, and the behaviour of these metals under differing redox conditions, when introduced into a new environment （i.e., on land） is of importance for environmental risk-assessment purposes. Canal sediments are often rich in sulfidic mineral phases, and we have attempted to quantify the influence of these sulfidic phases on the release and retention of metals in dredged canal sediments, using a combination of traditional chemical techniques （e.g. sequential extraction） and X-ray absorption spectroscopy （XAS）. Sediment samples have been collected from urban fresh-water canals, one in the British Midlands and one in Northern France. It appears from XAS that Cd is largely associated with oxygen in air-dried sediment, and with sulphur in vacuum-dried sediment.     

美国地质调查局激光雷达应用新进展

随着激光雷达(Light detection and ranging,Lidar)技术的成熟,美国地质调查局(U.S.Geo-logical Survey,USGS)在这个方向开展了许多应用研究。科学家们正在发展表达、使用高分辨率Lidar数据的新型技术;同时,为方便公众获取相应信息,数据及提取信息的发布手段也在研究之中。以下通过几个实例做一简要介绍。1典型研究1.1数据分发建立国家地图集(National Map)的一个目标是向公众发布基础数字地理信息。该地图集的高程部分是通过USGS地球观测系统(EROS)数据中心的国家高程数据集(National ElevationDataset,NED)维护的。NED提供3种…     

粘弹性应力转移延迟了1999年赫克托矿地震的触发

在某些情况下,由地震引起的地壳应力转移可以加快邻近断层的破裂,并引起地震序列的发生(Stein,et al,1992;King,et al,1994;Deng and Sykes,1996;Harris,et al,1995;Stein,1999)。1999年南加州赫克托矿地震(震级7.1)在1992年兰德斯地震(震级7.3)的7年后,在距其震中仅20km处发生。这表明赫克托矿地震是以某种方式被     

航空重力确定大地水准面的研究

随着近年来航空重力的发展,航空重力数据的精度和分辨率不断提高,其精度可达1 mGal,分辨率可达10km,这使得用航空重力数据计算精密大地水准面成为可能。本研究介绍利用满足一定条件的稳定、精确的航空重力数据计算大地水准面的一种新途径。它根据布隆公式,分离大地水准面与参考椭球,把航空重力观测值转换为大地水准面上的重力位,从而确定大地水准面。其具体步骤如下: 1.对重力扰动观测数据进行低通滤波,除去高频观测噪声; 2.利用全球重力场模型从低通滤波的重力     

西藏安多北断裂晚第四纪活动的基本特征

安多北断裂是青藏高原中部安多—错那盆地的北边界断裂(图1)。安多—错那盆地是青藏高原中部当雄—羊八井活动构造带北端的一个断陷盆地,盆地的北缘和南东缘分别为安多北断裂、安多南断裂和错那东断裂,这些断裂均为全新世活动断裂,安多北断裂和安多南断裂控制形成安多盆地,错那断裂控制形成错那盆地。安多盆地总体呈NNE走向,长约80km,南北宽约6～15km,盆地面的海拔高程为4580～4700m,呈东北部高、西南部低的趋势。以前的活动构造研究多集中在当雄—羊八井活动构造带的主体部分,如对念青