Evaluation of surface sediment contamination by polycyclic aromatic hydrocarbons in the "Saco do Laranjal" - (Patos Lagoon, Brazil)

This paper evaluates the concentration of Polyaromatic hydrocarbons - PAHs in the Estuarine area of the Patos Lagoon, more precisely in a local named "Saco do Laranjal" in Pelotas City (southern Brazil). The samples were collected in May 2008. The concentrations of 16 US-EPA priority polycyclic aromatic hydrocarbons (PAHs) were determined by gas chromatography with a mass spectrometry detector (GC/MS). The sum of PAHs concentration ranged from 7.3 to 92.8μgkg(-1) in dry weight. The positive correlation (Pearson test) between the total organic material (TOM) and the total PAH concentration (0.98) suggests that TOM plays an important role in controlling the PAHs levels in the sediments. According to the observed ratios of individual PAHs, the contamination in the studied area is originated, predominantly pyrolytic sources. The values found are considered under normal levels and indicates a not impacted area.     

Source of error and uncertainty in sheet erosion rates estimated from dendrogeomorphology

Dendrogeomorphology has been used since the 1960s to estimate sheet erosion rates. To date, most efforts have focused on accurately determining the first year of root exposure. However, an adequate methodological approach that takes into consideration the microtopography of the ground surface when estimating sheet erosion rates using dendrogeomorphology has not been proposed. In this study, terrestrial laser scanning (TLS) was used for the first time to examine how changes in microtopography determine the level of certainty in estimates. To this end, highly accurate TLS‐based digital elevation models representing exposed roots and their immediate vicinity were analysed using geographic information system tools. The results indicate that erosion rates calculated using the standard dendrogeomorphic method have been underestimated by up to 29% because the method does not take into account changes to the microtopography caused by the axial and radial pressure of the roots. Another source of uncertainty, which we estimate to be 50%, was also found and is the result of changes in the ground surface microtopography caused by variations in soil roughness. These findings do not invalidate the usefulness of dendrogeomorphology for assessing soil erosion, although they do show the need for correct characterization of the microtopography to guarantee reliability. Copyright © 2015 John Wiley & Sons, Ltd.     

Stable isotope characterisation of co-existing carbonates from the Holocene Gallocanta lake (NE Spain): palaeolimnological implications

The sedimentary succession of Gallocanta lake, a closed saline lake located in the Iberian Range (NE Spain), documents two successive lacustrine stages: (1) brackish lake stage and (2) shallow saline lake stage. The saline stage corresponds to the present-day situation in which the lake water properties are mainly controlled by a strongly negative annual water balance. The carbonates of the brackish lake stage have relatively constant δ¹⁸O values, however, they are rather high (δ¹⁸O_Do = 2.4‰ and δ¹⁸O_Cc = 4.5‰ mean values) suggesting a hydrologically closed lake with a long residence time of the waters. δ¹⁸O values of carbonates from the saline stage vary greatly, and are lighter than in the previous stage (δ¹⁸O_Do = 0.5‰, δ¹⁸O_Cc = −0.7‰, δ¹⁸O_Mgs = −2.3‰ mean values). These carbonates also precipitated in a hydrologically closed lake, but in equilibrium with a lake water of more variable isotopic composition. The δ¹³C values for carbonates of both stages reflect a mixing of different pools of carbon, but during saline stage δ¹³C values have been more controlled by the equilibrium of the lake waters with atmospheric CO₂. During the current stage, calcite and dolomite precipitate in Gallocanta lake mainly during spring and summer, although dolomite precipitation is more favoured towards the summer. Magnesite precipitates at the beginning of autumn, when the first rainfall re-dissolves the saline surface crust, producing saline waters with a high Mg²⁺ content. The isotopic composition of lake waters sampled in 2005 are far higher than those calculated from the carbonates. It is considered that this could be due to two factors: either because there have not been many extremely dry years (like the year 2005) during the development of the lake, or because the physical and chemical characteristics of the lake waters in such conditions are not appropriate for the development of these minerals.     

Implications of alternative metrics for global mitigation costs and greenhouse gas emissions from agriculture

100-year Global Warming Potentials (GWPs) are used almost universally to compare emissions of greenhouse gases in national inventories and reduction targets. GWPs have been criticised on several grounds, but little work has been done to determine global mitigation costs under alternative physics-based metrics . We used the integrated assessment model MESSAGE to compare emission pathways and abatement costs for fixed and time-dependent variants of the Global Temperature Change Potential (GTP) with those based on GWPs, for a policy goal of limiting the radiative forcing to a specified level in the year 2100. We find that fixed 100-year GTPs would increase global abatement costs (discounted and aggregated over the 21^st century) under this policy goal by 5–20 % relative to 100-year GWPs, whereas time-varying GTPs would reduce costs by about 5 %. These cost differences are smaller than differences arising from alternative assumptions regarding agricultural mitigation potential and much smaller than those arising from alternative radiative forcing targets. Using the land-use model GLOBIOM, we show that alternative metrics affect food production differently in different world regions depending on regional characteristics of future land-use change to meet growing food demand. We conclude that under scenarios of complete participation, the choice of metric has a limited impact on global abatement costs but could be important for the political economy of regional and sectoral participation in collective mitigation efforts, in particular changing costs and gains over time for agriculture and energy-intensive sectors.     

HAND contour: a new proxy predictor of inundation extent

Tools for accurately predicting environmental risks, such as the location and spatial extent of potential inundation, are not widely available. A dependence on calibration and a lack of available flood data have prevented the widespread application of existing hydrodynamic methods for predicting the extent of inundation. We use the height above the nearest drainage (HAND) terrain model to develop a simple static approach for mapping the potential extent of inundation that does not depend on flood observations and extends beyond methods for mapping low‐lying areas. While relying on the contour concept, the method utilizes drainage‐normalized topography and flowpaths to delineate the relative vertical distances (drop) to the nearest river. The HAND‐delineated relative drop is an effective distributed predictor of flood potential, which is directly related to the river stage height. We validated the new HAND contour approach using a flood event in Southern Brazil for which high‐resolution maps were available. The results indicated that the flood hazard‐mapping method accurately predicted the inundation extent of the channel carrying the flood wave and the channels influenced by flooding. For channels positioned outside of the flood‐wave area, the method overestimated the actual flood extent. As an original static assessment of floodwaters across the landscape, the HAND contour method could be used to map flood hazards in areas with poor information and could promote the development of new methods for predicting hydrological hazards. Copyright © 2015 John Wiley & Sons, Ltd.     

Simulation of the Seismic Response of Sedimentary Basins with Vertical Constant-Gradient Velocity for Incident <Emphasis Type="Italic">SH</Emphasis> Waves

The simulation of the seismic response of heterogeneous sedimentary basins under incident plane waves is computed using the Indirect Boundary Element Method (IBEM). To deal with these kinds of basins we used approximate analytical expressions for the two-dimensional Greens functions of a medium with constant-gradient wave propagation velocity. On the other hand, for the homogeneous half space underlying the sedimentary basin, the full space Greens functions were used. The response of semi-circular heterogeneous basins under incident SH waves is explored by means of the displacements in the frequency-space diagrams and synthetic seismograms. Moreover, we compared these results with those obtained for other homogeneous semi-circular models. The principal differences among them are pointed out. This simulation provided interesting results that displayed a complex amplification pattern in a rich spectrum of frequencies and locations. The maximum amplitudes levels were found around the edges of the heterogeneous sedimentary basins. In time domain some features characterize the seismic response of the basin which include enhanced generation and trapping of surface waves inside the sediments, and the reduced emission of seismic energy to the hard rock. In the heterogeneous models the lateral reflections of surface waves greatly influence the total displacements at the free surface in comparison with the homogeneous models where the displacements have a shared influence among both vertical and lateral reflections.     

Weathering processes in waste materials from a mining area in a semiarid zone

Chemical and mineralogical characterization of waste materials present in an abandoned Pb, Zn–Ag mining site (SE, Spain) was carried out. In unaltered rocks, the mineralogy is characterized by plagioclase, pyroxene, magnetite, ilmenite, amphibole, biotite and quartz. Trace-element contents of these samples represent unaltered values. In mine-waste materials, pH ranged from acidic to slightly acidic and trace-element content was generally high, especially for Pb and Zn, although there were also substantial As concentrations. X-ray diffraction results suggested that these samples have a complex mineralogy, including alteration products. Surficial materials in the study area were affected by weathering processes, generating supergene assemblages, including Fe and Mn oxides and hydroxides, carbonates, hydrated sulfates and jarosite. Knowledge of the geochemical processes that took place in the past and which are still taking place provide an important tool for assessing associated environmental problems in this area.     

Correlation of sedimentary units from grain-size and mineralogic analyses as a tool for constraining trench interpretations in palaeoseismology

In palaeoseismological trench studies, precise correlation of sedimentary units between fault blocks has an unquestionable value for accurately inferring the amounts of coseismic displacement and hence for assessing seismic hazard. A methodology based on laser analysis of particle size and mineralogic composition by X-ray diffraction is proposed in order to strengthen the correlation of sedimentary units in a trench excavated across the Concud Fault (central Iberian Chain, Spain). The surveyed sediments show sharp and multiple lateral facies changes, as well as inconsistent optically stimulated luminescence (OSL) ages. The results reinforce the correlation based on field inspection of lithologic and sedimentologic features. Moreover, they allow interpretation of rejuvenation of OSL ages of samples in the upthrown fault block, which has been attributed to partial erosion of sedimentary units, as evidenced by their smaller thickness and erosive boundaries. The correlated units are then used to estimate coseismic displacements for three palaeoseismic events.