A theoretical model for gas adsorption-induced coal swelling

Swelling and shrinkage (volumetric change) of coal during adsorption and desorption of gas is a well-known phenomenon. For coalbed methane recovery and carbon sequestration in deep, unminable coal beds, adsorption-induced coal volumetric change may cause significant reservoir permeability change. In this work, a theoretical model is derived to describe adsorption-induced coal swelling at adsorption and strain equilibrium. This model applies an energy balance approach, which assumes that the surface energy change caused by adsorption is equal to the elastic energy change of the coal solid. The elastic modulus of the coal, gas adsorption isotherm, and other measurable parameters, including coal density and porosity, are required in this model. Results from the model agree well with experimental observations of swelling. It is shown that the model is able to describe the differences in swelling behaviour with respect to gas species and at very high gas pressures, where the coal swelling ratio reaches a maximum then decreases. Furthermore, this model can be used to describe mixed-gas adsorption induced-coal swelling, and can thus be applied to CO₂-enhanced coalbed methane recovery.     

CM carbonaceous chondrite falls and their terrestrial alteration

The CM carbonaceous chondrites provide unique insights into the composition of the protoplanetary disk, and the accretion and geological history of their parent C‐complex asteroid(s). Of the hundreds of CMs that are available for study, the majority are finds and so may have been compromised by terrestrial weathering. Nineteen falls have been recovered between 1838 and 2020, and there is a hint of two temporal clusters: 1930–1942 and 2009–2020. Falls are considered preferable to finds to study because they should be near pristine, and here this assumption is tested by investigating their susceptibility to alteration before recovery and during curation. CMs falling on the land surface are prone to contamination by organic compounds from soil and vegetation. Where exposed to liquid water prior to collection, minerals including oldhamite can be dissolved and most fluid mobile elements leached. Within days of recovery, CMs adsorb water from the atmosphere and are commonly contaminated by airborne hydrocarbons. Interaction with atmospheric water and oxygen during curation over year to decadal timescales can produce Fe‐oxyhydroxides from Fe,Ni metal and gypsum from indigenous gypsum and oldhamite. Relationships between the petrologic (sub)types of pre‐1970 falls and their terrestrial age could be due to extensive but cryptic alteration during curation, but are more likely a sampling bias. The terrestrial history of a CM fall, including circumstances of its collection and conditions of its curation, must be taken into account before it is used to infer processes on C‐complex parent bodies such as Ryugu and Bennu.     

Effects of differential hillslope‐scale water retention characteristics on rainfall–runoff response at the Landscape Evolution Observatory

Hillslopes turn precipitation into runoff and thus exert important controls on various Earth system processes. It remains difficult to collect reliable data necessary for understanding and modeling these Earth system processes in real catchments. To overcome this problem, controlled experiments are being conducted at the Landscape Evolution Observatory at Biosphere 2, The University of Arizona. Previous experiments have revealed differences in hydrological response between 2 landscapes within Landscape Evolution Observatory, even though both landscapes were designed to be identical. In an attempt to discover where the observed differences stem from, we use a fully 3‐dimensional hydrological model (CATchment HYdrology) to show the effect of soil water retention characteristics and saturated hydraulic conductivity on the hydrological response of these 2 hillslopes. We also show that soil water retention characteristics can be derived at hillslope scale from experimental observations of soil moisture and matric potential. It is found that differences in soil packing between the 2 landscapes may be responsible for the observed differences in hydrological response. This modeling study also suggests that soil water retention characteristics and saturated hydraulic conductivity have a profound effect on rainfall–runoff processes at hillslope scale and that parametrization of a single hillslope may be a promising step in modeling rainfall–runoff response in real catchments.     

Landforms and landscape evolution in the Skardu,Shigar and Braldu Valleys,Central Karakoram

The Central Karakoram, which includes K2 in Pakistan, is one of the most rapidly rising areas on Earth and exhibits complex topography and extreme relief. Impressive valley fills and glacial landforms are present throughout the valleys. The dynamics of landscape evolution of the region are currently not well understood. Consequently, the landforms were mapped and assessed in the Skardu, Shigar, and Braldu valleys, to elucidate the spatio-temporal scale dependencies of surface processes active in the region. These valleys were examined using geomorphic field methods, remote sensing, geomorphometry, and terrestrial cosmogenic nuclides (TCNs) surface exposure dating. The glaciers in this region have oscillated considerably throughout the Late Quaternary, and four glacial stages have been recognized including at least six glacial advances. Surface processes readjusted after glacier retreat, and ubiquitous mass movements and catastrophic landsliding transported material from steep slopes to valley bottoms, while glaciofluvial meltwater and glacier outburst floods redistributed sediment down valley. Glacier geochronology and late Holocene ages of the outburst flood deposits indicate that landscape evolution has been dominated by glaciation and paraglaciation during the late Quaternary.     

SOLAR ENERGETIC ION AND ELECTRON LIMITS FROM HIREGS OBSERVATIONS

The HIgh-REsolution Gamma-ray and hard X-ray Spectrometer (HIREGS) consists of an actively shielded array of twelve liquid-nitrogen-cooled germanium detectors designed to provide unprecedented spectral resolution and narrow-line sensitivity for solar gamma-ray line observations. Two long-duration, circumpolar balloon flights of HIREGS in Antarctica (10–24 January, 1992 and 31 December, 1992–10 January, 1993) provided 90.9 and 20.4 hours of solar observations, respectively. During the observations, eleven soft X-ray bursts at C levels and above (largest M1.7) occurred, and three small solar hard X-ray bursts were detected by the Compton Gamma-Ray Observatory. HIREGS detected a significant increase above 30 keV in one. No solar gamma-ray line emission was detected. Limits on the 2.223-MeV line and the hard X-ray emission are used to estimate the relative contribution of protons and electrons to the energy in flares, and to coronal heating. For the 2.223-MeV line, the upper limit fluence is 0.8 ph cm^-2 in the flares, and the upper limit flux is 1.8 × 10^-4 ph s^-1 cm^-2 in the absence of flares. These limits imply that 6 × 10³⁰ (2) protons above 30 MeV were accelerated in the flares, assuming standard photospheric abundances and a thick target model. The total energy contained in the accelerated protons >30 MeV is 4 × 10²⁶ ergs, but this limit can be more than 10³⁰ ergs if the spectrum extends down to 1 MeV. The upper limit on the total energy in accelerated electrons during the observed flares can also exceed 10³⁰ ergs if the spectrum goes down to 7 keV. Quiet-Sun observations indicate that 10²⁶erg s^-1 are deposited by energetic protons >1 MeV, well below the10²⁷ –10²⁸ erg s^-1 required for coronal heating, while <3 × 10²⁷ erg s^-1 are deposited by energetic electrons, which does not exclude the possibility of coronal heating by quiet-time accelerated electrons. The quiet-Sun observations also suggest that if protons stored in the corona are to supply the energy for flares, as suggested by Elliot (1964), the proton spectrum must extend down to at least 2 MeV. However, collisional losses at typical coronal-loop densities prevent those low-energy protons from being stored for 10⁴ s. It therefore seems unlikely that the energy for flares could come from energetic protons stored over long periods.     

Constructing an idealized model of the North Atlantic Ocean using slippery sacks

This paper documents the continued development and testing of a new Lagrangian oceanic general circulation model. The slippery sacks ocean model (SSOM), which represents a body of water as a pile of conforming parcels, is improved and is used to simulate circulations in homogeneous oceans and in an idealized model of the North Atlantic Ocean.A method for including horizontal mixing in the SSOM is presented. A given sack’s nearest neighbors are identified in the positive and negative x- and y-directions, and the sack exchanges momentum and/or tracers with these neighbors. This formulation of mixing is straightforward to implement, computationally efficient, and it produces results similar to a standard Eulerian finite-difference representation of diffusion.The model’s ability to reproduce the Stommel and Munk solutions to the classical western boundary current problem is tested. When steps are taken to reduce the potential energy barrier to sacks crossing one another, the model generates circulations that are consistent with linear theory. In moderately non-linear regimes the model produces appropriate departures from linear solutions including a boundary current that continues along the northern boundary for a time.Taking advantage of the new mixing scheme and lessons learned from simulations of homogeneous oceans, the authors construct an idealized model of the North Atlantic Ocean. They compare simulations conducted with the SSOM to similar simulations conducted with the Massachusetts Institute of Technology general circulation model (MITgcm). The SSOM and the MITgcm produce similar wind-forced gyres, thermocline structure, and meridional overturning. The SSOM is also used to explore how circulations change in the limit when tracer diffusion goes to zero.     

Groundwater,Acid and Carbon Dioxide Dynamics Along a Coastal Wetland,Lake and Estuary Continuum

Coastal wetlands are hotspots for biodiversity and biological productivity, yet the hydrology and carbon cycling within these systems remains poorly understood due to their complex nature. By using a novel spatiotemporal approach, this study quantified groundwater discharge and the related inputs of acidity and CO₂ along a continuum of a modified coastal acid sulphate soil (CASS) wetland, a coastal lake and an estuary under highly contrasting hydrological conditions. To increase the resolution of spatiotemporal data and advance upon previous methodologies, we relied on automated observations from four simultaneous time-series stations to develop multiple radon mass balance models to estimate groundwater discharge and related groundwater inputs of acidity and dissolved inorganic carbon (DIC), along with surface water to atmosphere CO₂ fluxes. Spatial surveys indicated distinct acid hotspots with minimum surface water pH of 2.91 (dry conditions) and 2.67 (flood conditions) near a non-remediated (drained) CASS area. Under flood conditions, groundwater discharge accounted for ～14.5 % of surface water entering the lake. During the same period, acid discharge from the acid sulphate soil section of the continuum produced ～4.8 kg H₂SO₄?ha^?1 day^?1, a rate much higher than previous studies in similar systems. During baseflow conditions, the low pH water was rapidly buffered within the estuarine lake, with the pH increasing from 4.22 to 6.07 over a distance of ～250 m. The CO₂ evasion rates within the CASS were extremely high, averaging 2163?±?125 mmol m^?2 day^?1 in the dry period and 4061?±?259 mmol m^?2 day^?1 under flood conditions. Groundwater input of DIC could only account for 0.4 % of this evasion in the dry conditions and ～5 % during the flood conditions. We demonstrated that by utilising a spatiotemporal (multiple time-series stations) approach, the study was able to isolate distinct zones of differing hydrology and biogeochemistry, whilst providing more reasonable groundwater acid input estimates and air–water CO₂ flux estimates than some traditional sampling designs. This study highlights the notion that modified CASS wetlands can release large amounts of CO₂ to the atmosphere because of high groundwater acid inputs and extremely low surface water pH.