Salt Marsh and Fringing Oyster Reef Transgression in a Shallow Temperate Estuary: Implications for Restoration,Conservation and Blue Carbon

The importance of intertidal estuarine habitats, like salt marsh and oyster reef, has been well established, as has their ubiquitous loss along our coasts with resultant forfeiture of the ecosystem services they provide. Furthering our understanding of how these habitats are evolving in the face of anthropogenic and climate driven changes will help improve management strategies. Previous work has shown that the growth and productivity of both oyster reefs and salt marshes are strongly linked to elevation in the intertidal zone (duration of aerial exposure). We build on that research by examining the growth of marsh-fringing oyster reefs at yearly to decadal time scales and examine movement of the boundary between oyster reef and salt marsh at decadal to centennial time scales. We show that the growth of marsh-fringing reefs is strongly associated to the duration of aerial exposure, with little growth occurring below mean low water and above mean sea level. Marsh-shoreline movement, in the presence or absence of fringing oyster reefs, was reconstructed using transects of sediment cores. Carbonaceous marsh sediments sampled below the modern fringing oyster reefs indicate that marsh shorelines within Back Sound, North Carolina are predominantly in a state of transgression (landward retreat), and modern oyster-reef locations were previously occupied by salt marsh within the past two centuries. Cores fronting transgressive marsh shorelines absent fringing reefs sampled thinner and less extensive carbonaceous marsh sediment than at sites with fringing reefs. This indicates that fringing reefs are preserving carbonaceous marsh sediment from total erosion as they transgress and colonize the exposed marsh shoreline making marsh sediments more resistant to erosion. The amount of marsh sediment preservation underneath the reef scales with the reef’s relief, as reefs with the greatest relief were level with the marsh platform, preserving a maximum amount of carbonaceous sediments during transgression by buffering the marsh from erosional processes. Thus, fringing oyster reefs not only have the capacity to shelter shorelines but, if located at the ideal tidal elevation, they also keep up with accelerating sea-level rise and cap carbonaceous sediments, protecting them from erosion, as reefs develop along the marsh.     

Uptake of hazardous elements by spring onion (<Emphasis Type="Italic">Allium fistulosum</Emphasis> L.) from soil irrigated with different types of water and possible health risk

Bio-concentration of elements such as Mo, As, Se, Fe, Cu, Zn, Ni and Pb was analyzed in spring onion (Allium fistulosum L.) in three different locations of central Punjab, Pakistan. At location GW, relatively low level of hazardous elements was found in spring onion, suggesting that groundwater is a safe source of water for irrigating food crops. The pH of soil at wastewater irrigation was found less acidic (pH 7.4) than the other sites. The range of concentration in the different samples of spring onion was as follows: 6.15–8.16 mg kg^?1 for Mo, 2.77–4.28 mg kg^?1 for As, 0.395–0.705 mg kg^?1 for Se, 36.73–48.17 mg kg^?1 for Fe, 10.58–16.26 mg kg^?1 for Cu, 28.87–39.79 mg kg^?1 for Zn, 6.66–8.75 mg kg^?1 for Ni and 4.33–6.09 mg kg^?1 for Pb, respectively. High bio-concentration of Zn (15.37) from soil to spring onion was found at canal water irrigated location. The estimated daily intake of metal for spring onion was less, but the health risk index was higher than 1 for Mo, As, Cu, Pb and Ni, respectively. This was due to higher proportion of spring onion in diet, which consequently increased the health risk index for metals. Therefore, it is recommended to avoid growing vegetables in untreated urban and rural wastewater containing elevated amounts of metals.     

Local- and global-scale seismic analyses of historical masonry compounds in San Pio delle Camere (L’Aquila,Italy)

Masonry building aggregates are large parts of the Italian building heritage often designed without respecting seismic criteria. The current seismic Italian code does not foresee a clear calculation method to predict their static nonlinear behaviour. For this reason, in this paper firstly, a simple methodology to forecast the seismic response of masonry aggregates in San Pio delle Camere (L’Aquila, Italy) has been set up starting from the provisions of the Italian Guidelines on Cultural Heritage. The implemented procedure has been calibrated on the results of two FEM structural analysis programs used to investigate three masonry building compounds. As a result, a design chart used to correctly predict the base shear of aggregate masonry units starting from code provisions has been set up. Later on, the large-scale seismic vulnerability and damage appraisal of the inspected historical centre has been done on the basis of a quick methodology, already implemented and experienced by the author in some historical centres of the Campania region. The analysis result was a numerical correlation between vulnerability index and mean damage grade of examined building compounds. In particular, a damage forecast under numerical way has been firstly estimated and then compared with the real one. The post-earthquake scenario has represented an ideal term of comparison for effectively testing the reliability of the employed technique, which should be further extended to other Italian historical centres.     

A novel nuclear forensic tool involving deposit type normalized rare earth element signatures

Identifying the provenance of uranium‐rich materials is a critical objective of nuclear forensic analysis. Rare earth element (REE) distributions within uranium ores are well‐established forensic indicators, but quantifying and correlating trace element signatures for U ores to known deposits has thus far involved intricate statistical analyses. This study reports average chondrite normalized (CN)‐REE signatures for important U deposit types worldwide, which are then employed to evaluate U ore paragenesis using a simple linear regression analysis. This technique provides a straightforward method that can aid in determining the deposit type of U ores based on their REE abundances, and combined with other forensic indicators (e.g. radiogenic isotope signatures) can provide essential provenance information for nuclear materials.     

Application of the K?ppen classification for climatic zoning in the state of Minas Gerais, Brazil

The knowledge of the climatic conditions of a region is crucial for its agricultural development. It is also extremely important for understanding the fact that certain cultures have to develop under prevailing temperature and humidity conditions and assist in the adoption of a suitable irrigation technique, as well as its management and operationalization. The K?ppen system of climate classification is widely used for the identification of homogeneous climate zones as it considers only rainfall and temperature as the meteorological elements for classification. For this study, we used climatic databases of rainfall and temperature in a raster format, with a spatial resolution of 30″ of arc (an approximate area of 0.86?km²?pixel^?1), from 1961 to 1990. Through geoprocessing techniques, we obtained a map of climatic classification for the state of Minas Gerais. We found that the state has the following three major climatic groups: A, B and C, which correspond to tropical rainy, dry and warm temperate climates, respectively. The climate classes obtained were Aw, Am, BSh, Cwa and Cwb, with Aw, Cwa and Cwb classes occupying 99.89% of the territorial area of the state. The validation of the results showed a satisfactory agreement, with 93.75% reliability.     

Constraints on the genesis of gold mineralization at the Homestake Gold Deposit, Black Hills, South Dakota from rhenium–osmium sulfide geochronology

The Homestake gold deposit, located in the Black Hills, South Dakota, USA, is one of the largest known hydrothermal gold deposits globally, with total mining production exceeding 40 Moz Au. Rhenium–osmium geochronology of ore-associated arsenopyrite and pyrrhotite was performed in an effort to delineate the timing of gold mineralization in relation to known tectonothermal events in the northern Black Hills. Arsenopyrite yields a rhenium–osmium (Re–Os) age of 1,736 ± 8 Ma (mean squared weighted deviation = 1.6), consistent with existing age constraints for gold mineralization, whereas Re–Os pyrrhotite data are highly scattered and do not yield a meaningful mineralization age. This is taken to indicate that the Re–Os arsenopyrite chronometer is robust to at least 400°C, whereas the Re–Os pyrrhotite chronometer is likely disturbed by temperatures of 300–350°C. The Re–Os arsenopyrite age and initial Os ratio (0.28 ± 0.15) are interpreted to indicate that gold was introduced at ca. 1,730 Ma, coincident with the onset of exhumation of crustal blocks and, possibly, the earliest intrusive phases of Harney Peak granite magmatism. New in situ U–Pb monazite analyses from an aplite dike in the east-central Black Hills indicate that granite magmatism was a protracted event, persisting until at least ca. 1,690 Ma.     

The end of the Messinian Salinity Crisis in the western Mediterranean: Insights from the carbonate platforms of south-eastern Spain

How the Messinian Salinity Crisis (MSC) ended is still a matter of intense debate. The Terminal Carbonate Complex (TCC) is a late Messinian carbonate platform system that recorded western Mediterranean hydrological changes from the final stages of evaporite deposition till the advent of Lago-Mare fresh- to brackish water conditions at the very end of Messinian times. A multidisciplinary study has been carried out in three localities in south-eastern Spain to reconstruct the history of TCC platforms and elucidate their significance in the MSC. Overall, this study provides evidence that the TCC formed following a regional 4th order water level rise and fall concomitant with an opening-restriction trend. It can be subdivided into four 5th order depositional sequences (DS1 to DS4) recording two phases: (1) from DS1 to DS3, a tide-dominated ooidic to oobioclastic system with stenohaline faunas developed as a result of a 70 m water level rise. During this period, the TCC developed in a shallow sea with close to normal marine salinity; (2) in depositional sequence 4, a microbialite-dominated platform system developed. This is indicative of a significant environmental change and is attributed to a 30 to 40 m water level fall in the basins under study. These restricted conditions were coeval with intense evaporite deformation and brine recycling. The syn-sedimentary deformation of evaporites had a major impact on platform architecture and carbonate production, affecting the Messinian series throughout south-eastern Spain at the end of the TCC history. At that time, the TCC developed in a lake with fluctuating, brackish- to hypersaline water. These findings suggest a temporary restoration of marine conditions in the western Mediterranean marginal basins due to Atlantic water influxes prompted by a global sea level rise around 5.6 Ma. Whether marine conditions extended to the entire western Mediterranean still needs to be investigated.     

Source of parental melts to carbonatites–critical isotopic constraints

The restriction of most carbonatites to continental areas raises questions as to whether the parental liquids to carbonatites are generated within the continental lithosphere, or whether they are derived from deeper parts of the mantle with the lithosphere playing a subsidiary, but important, role in trapping volatile-rich melts/fluids. The constraints imposed by both radiogenic and stable isotopic data from carbonatites world-wide are consistent with a sub-lithospheric source for the parental melts, associated with either asthenospheric ‘upwellings’ or more deep-seated, plume-related activity. Crucial evidences that support the generation of carbonated melts from sub-lithospheric mantle are: the petrogenetic and temporal association of carbonatites with large igneous provinces (LIPs; e.g., Deccan, Parana), carbonatites with primitive noble gas isotopic signatures, radiogenic isotope ratios similar to OIBs (i.e. involving HIMU, EM1 and FOZO mantle components), and the uniform, time-integrated Rb/Sr and Sm/Nd development lines for Sr and Nd isotopic data for carbonatites from the Superior Province, Canada, and the Kola Peninsula, Russia. Such findings are difficult to reconcile with a lithospheric origin. Even if a metasomatized lithospheric mantle is considered to be the sole source of carbonated melts, an unknown mantle process is required, large enough to generate widespread, synchronous metasomatism spanning regions in excess of 1?×?10⁶?km².     

Portland Cement Stabilization of Soil–Bentonite for Vertical Cutoff Walls Against Diesel Oil Contaminant

The objective of this study was to evaluate the effect of water-cement ratio and cement content on the hydraulic behavior of soil–cement–bentonite (SCB) and soil–bentonite (SB) mixtures permeated with water and diesel oil, to assist with the design of vertical cutoff walls constructed with those mixtures. The experimental program included unconfined compression tests, hydraulic conductivity tests and X-ray diffraction analysis. The test results indicated changes in hydraulic conductivity take place due to the variation of the water-cement ratio and permeant fluid. The hydraulic conductivity of the SB mixtures permeated with diesel oil was higher than the hydraulic conductivity of the same samples permeated with water. X-ray diffraction analyses suggest that this might be due to the decrease in double layer thickness and increase of seepage pore space imparted by diesel oil permeation. Conversely, Portland cement addition increased the hydraulic conductivity of the SCB specimens permeated with water, whereas subsequent diesel oil permeation reduced the hydraulic conductivity of the SCB specimens; this might be due to the relatively lower impact imparted by diesel permeation on the double layer characteristics of the bentonite stabilized with Portland cement.     

Diesel transport monitoring in simulated unconfined aquifers using miniature resistivity arrays

The principal aim of this study is to assess the scope of monitoring diesel plume migration in a scaled aquifer model with a miniaturised electrical resistivity array. Respectively 1000 and 500 ml of diesel were injected in both the unsaturated and water-saturated zones of a sand body overlying a clay aquitard, and diesel migration was monitored with a miniature electrode array and an off-the-shelf resistivity meter. Inverted time-lapse electrical resistivity tomography (ERT) data reflect downward and lateral spreading of the diesel plume away from the injection point in the unsaturated zone. Diesel was also imaged to spread upwards and laterally away from the injection point in the saturated zone, as controlled by capillary rise. In both cases later-time ERT images reflected preferential pooling of diesel on the water table, as well as vertical smearing of pooled diesel in response to simulated water-table fluctuations. Repeat fluid electrical conductivity (EC) and dissolved oxygen (DO) measurements validate the observed changes in bulk resistivity caused by both diesel injections. Artefacts introduced by 2D inversion of 3D contaminant transport were abound. Time-lapse ERT imaging of diesel transport is therefore inferred to be feasible and well-suited to complementing conventional techniques of intrusive site investigation, although time-lapse 3D or 4D ERT imaging is strongly advocated.