Rainfall trends in the Brazilian Amazon Basin in the past eight decades

Rainfall series at 18 stations along the major rivers of the Brazilian Amazon Basin, having data since 1920s or 1930s, are analyzed to verify if there are appreciable long-term trends. Annual, rainy-season, and dry-season rainfalls are individually analyzed for each station and for the region as a whole. Some stations showed positive trends and some negative trends. The trends in the annual rainfall are significant at only six stations, five of which reporting increasing trends (Barcelos, Belem, Manaus, Rio Branco, and Soure stations) and just one (Itaituba station) reporting decreasing trend. The climatological values of rainfall before and after 1970 show significant differences at six stations (Barcelos, Belem, Benjamin Constant, Iaurete, Itaituba, and Soure). The region as a whole shows an insignificant and weak downward trend; therefore, we cannot affirm that the rainfall in the Brazilian Amazon basin is experiencing a significant change, except at a few individual stations. Subregions with upward and downward trends are interspersed in space from the far eastern Amazon to western Amazon. Most of the seasonal trends follow the annual trends, thus, indicating a certain consistency in the datasets and analysis.     

Late Pleistocene highstand and recession of a small, high-altitude pluvial lake, Jakes Valley, central Great Basin, USA

Models of factors controlling late Pleistocene pluvial lake-level fluctuations in the Great Basin are evaluated by dating lake levels in Jakes Valley. “Jakes Lake” rose to a highstand at 13,870 ± 50 ¹⁴C Yr B.P., receded to a stillstand at 12,440 ± 50 ¹⁴C yr B.P., and receded steadily to desiccation thereafter. The Jakes Lake highstand is roughly coincident with highstands of lakes Bonneville, Lahontan and Russell. The rise to highstand and recession of Jakes Lake were most likely controlled by a storm track steered by the polar jet stream. The final stillstand of Jakes Lake helps constrain timing of northward retreat of the polar jet stream during the Pleistocene-Holocene transition.     

GGR Biennial Critical Review: Analytical Developments Since 2014

This GGR biennial critical review covers developments and innovations in key analytical methods published since January 2014, relevant to the chemical, isotopic and crystallographic characterisation of geological and environmental materials. In nine selected analytical fields, publications considered to be of wide significance are summarised, background information is provided and their importance evaluated. In addition to instrumental technologies, this review also presents a summary of new developments in the preparation and characterisation of rock, microanalytical and isotopic reference materials, including a précis of recent changes and revisions to ISO guidelines for reference material characterisation and reporting. Selected reports are provided of isotope ratio determinations by both solution nebulisation MC‐ICP‐MS and laser ablation‐ICP‐MS, as well as of radioactive isotope geochronology by LA‐ICP‐MS. Most of the analytical techniques elaborated continue to provide new applications for geochemical analysis; however, it is noted that instrumental neutron activation analysis has become less popular in recent years, mostly due to the reduced availability of nuclear reactors to act as a neutron source. Many of the newer applications reported here provide analysis at increasingly finer resolution. Examples include atom probe tomography, a very sensitive method providing atomic scale information, nanoscale SIMS, for isotopic imaging of geological and biological samples, and micro‐XRF, which has a spatial resolution many orders of magnitude smaller than conventional XRF.     

Elucidation of different forms of organic carbon in marine sediments from the Atlantic coast of Spain using thermal analysis coupled to isotope ratio and quadrupole mass spectrometry

Analysis of river, estuary and marine sediments from the Atlantic coast of Spain using thermogravimetry–differential scanning calorimetry–quadrupole mass spectrometry–isotope ratio mass spectrometry (TG–DSC–QMS–IRMS) was used to (a) distinguish bulk chemical hosts for C within a sediment and humic acid fraction, (b) track C pools with differing natural C isotope ratios and (c) observe variation with distance from the coast. This is the first application of such a novel method to the characterisation of organic matter from marine sediments and their corresponding humic acid fractions. Using thermal analysis, a labile, a recalcitrant and a refractory carbon pool can be distinguished. Extracted humic fractions are mainly of recalcitrant nature. The proportion of refractory carbon is greatest in marine sediments and humic acid fractions. Quadrupole mass spectrometry confirmed that the greatest proportion of m/z 44 (CO₂) and m/z 18 (H₂O) were detected at temperatures associated with recalcitrant carbon (510–540 °C). Isotope analysis detected progressive enrichment in δ¹³C for the sediment samples with an increase in marine influence. Isotopic heterogeneity in the refractory organic matter in marine sediments could be due to products of anthropogenic origin or natural combustion products. Isotope homogeneity of humic acids confirms the presence of terrigenous C in marine sediments, allowing the terrestrial input to be characterised.     

Analysis of the weightiness of site effects on reinforced concrete (RC) building seismic behaviour: The Adra town example (SE Spain)

The damage distribution in Adra town (south‐eastern Spain) during the 1993 and 1994 Adra earthquakes (5.0 magnitude), that reached a maximum intensity degree of VII (European Macroseismic Scale (EMS scale)), was concentrated mainly in the south‐east zone of the town and the most relevant damage occurred in reinforced concrete (RC) buildings with four or five storeys. In order to evaluate the influence of ground condition on RC building behaviour, geological, geomorphological and geophysical surveys were carried out, and a detailed map of ground surface structure was obtained. Short‐period microtremor observations were performed in 160 sites on a 100m × 100m dimension grid and Nakamura's method was applied in order to determine a distribution map of soil predominant periods. Shorter predominant periods (0.1–0.3 s) were found in mountainous and neighbouring zones and larger periods (greater than 0.5 s) in thicker Holocene alluvial fans. A relationship T = (0.049 ± 0.001)N, where T is the natural period of swaying motion and N is the number of storeys, has been empirically obtained by using microtremor measurements at the top of 38 RC buildings (ranging from 2 to 9 storeys). 1‐D simulation of strong motion on different soil conditions and for several typical RC buildings were computed, using the acceleration record in Adra town of the 1993 earthquake. It is noteworthy that all the aforementioned results show the influence of site effects in the degree and distribution of observed building damage. Copyright © 2007 John Wiley & Sons, Ltd.     

Occurrence and Resistance of Pathogenic Bacteria Along the Tietê River Downstream of São Paulo in Brazil

The load of pathogenic bacteria, their fate and their dangerousness in the Tietê River were assessed along 100 km starting from the city of São Paulo, Brazil. The data were compared with those from two German rivers. High loads of pathogens were found in the Tietê River near the city of São Paulo (Escherichia coli O157:H7, Shigella flexneri, and Shigella boydii), which were absent 30 km downstream of São Paulo. The antibiotic resistances observed in the Tietê river were rather low and decreased after the major input in São Paulo to significantly lower levels about 30 km downstream. While the Brazilian isolates were more susceptible for ampicillin than the German ones, the reverse was observed for gentamycin. For optimal control of infections in humans critical areas where these bacteria survived longer and their elimination mechanisms should be identified as well as the extent and the origin of antibiotic resistance should be determined.     

The BEAM-project: prediction and assessment of mixture toxicities in the aquatic environment

Freshwater and marine ecosystems are exposed to various multi-component mixtures of pollutants. Nevertheless, most ecotoxicological research and chemicals regulation focus on hazard and exposure assessment of individual substances only, the problem of chemical mixtures in the environment is ignored to a large extent. In contrast, the assessment of combination effects has a long tradition in pharmacology, where mixtures of chemicals are specifically designed to develop new products, e.g. human and veterinary drugs or agricultural and non-agricultural pesticides. In this area, two concepts are frequently used and are thought to describe fundamental relationships between single substance and mixture effects: Independent Action (Response Addition) and Concentration Addition. The question, to what extent these concepts may also be applied in an ecotoxicological and regulatory context may be considered a research topic of major importance, as the concepts would allow to make use of already existing single substance toxicity data for the predictive assessment of mixture toxicities. Two critical knowledge gaps are identified: (a) There is a lack of environmental realism, as a huge part of our current knowledge about the applicability of the concepts is restricted to artificial situations with respect to mixture composition or biological effect assessment. (b) The knowledge on what exactly is needed for using the concepts as tools for the predictive mixture toxicity assessment is insufficient. Both gaps seriously hamper the necessary, scientifically sound consideration of mixture toxicities in a regulatory context.In this paper, the two concepts will be briefly introduced, the necessity of considering the toxicities of chemical mixtures in the environment will be demonstrated and the applicability of Independent Action and Concentration Addition as tools for the prediction and assessment of mixture toxicities will be discussed. An overview of the specific aims and approaches of the BEAM project to fill in the identified knowledge gaps is given and first results are outlined.     

Evaluating proxies for estimating subaerial beach volume change across increasing time scales and various morphologies

Proxies, such as changes in beach profiles and shoreline positions, are commonly used in management and research for estimating changes in subaerial beach volume; however, the accuracy of these proxies across increasing time scales and complex morphologies is unclear. Volume changes associated with along‐beach morphologic variability may not be captured well by changes in profiles, while volume changes associated with across‐beach morphologic variability may not be captured well by measuring shoreline change. This study assesses the impacts of morphologic variations, associated with beach cusps and nourishment material, on volume change estimates from profiles and shoreline change at 0.5 to 3.5 year time periods. Results indicate that profiles spaced ≥ 150 m apart and the shoreline‐change proxy will likely estimate volume change inaccurately over periods ≤ 1 year at beaches that are consistently eroding or accreting and contain cusps. However, over longer time periods (1–3.5 years), estimates of volume change from both proxies improved at those types of beaches. Volume changes at the edges of nourishment areas are not captured well by profiles. When the nourishment material is graded to a ramped morphology, which minimizes across‐beach morphologic variability, the shoreline‐change proxy does accurately estimate volume changes. Both proxies estimate volume changes inaccurately at beaches where volume changes oscillate between erosion and accretion on both short and long time scales because the magnitude of small‐scale changes in volume from the formation and erosion of morphologic features, such as cusps and berms, will always be similar to the longer‐term net volume change. This study suggests that decadal records of shoreline change, which are commonly developed using aerial photography, can be used to help identify the best proxy for estimating volume change; however, recent anthropogenic modifications that impact patterns of beach sedimentation, including nourishment, terminal groins, and inlet‐channel dredging, makes decadal records less useful. Copyright © 2013 John Wiley & Sons, Ltd.     

Fire severity and surface rock fragments cause patchy distribution of soil water repellency and infiltration rates after burning

Although fire‐induced soil water repellency (SWR) and its effects on soil hydrology and geomorphology have been studied in detail, very few studies have considered the effect of rock fragments resting on the soil surface or partly embedded in soil. In this research, we have studied the effect of rock fragments on the strength and spatial distribution of fire‐induced SWR at different fire severities. A fire‐affected area was selected for this experiment and classified into different zones according to fire severity (unburned, low, moderate and high) and rock fragment cover (low, <20% and high, >60%). During 7 days after fire, SWR and infiltration rates were assessed in the soil surface covered by individual rock fragments and in the midpoint between two adjacent rock fragments (with maximum spacing of 20 cm). SWR increased with fire severity. Rock fragments resting on the soil surface increased the heterogeneity of the spatial distribution of fire‐induced SWR. SWR increased significantly with rock fragment cover in bare areas under moderate and high fire severity, but quantitatively important changes were only observed under high fire severity. In areas with a low rock fragment cover, water repellency from soil surfaces covered by rock fragments increased relative to bare soil surfaces, with increasing SWR. In areas with a high rock fragment cover, SWR increased significantly from non‐covered to covered soil surfaces only after low‐severity burning. Rock fragment cover did not affect infiltration rates, although it decreased significantly in soil surfaces after high‐severity burning in areas under low and high rock fragment cover. Copyright © 2013 John Wiley & Sons, Ltd.     

Sewage treatment level and flow rates affect polychaete assemblages

The European Water Framework Directive (WFD) and the Urban Wastewater Treatment Directive (UWWTD) aim to improve water quality and reduce the environmental impact of wastewater, by requiring member states to introduce better treatment levels. This study was carried out in order to detect the most suitable treatment type or flow level for reducing benthic environmental impact. Therefore, soft-bottom polychaete assemblages affected by discharges of six treatment plants, with different treatment technologies and flow rates, were analysed over three consecutive years. Polychaete assemblages changed as a result of sewage discharge. These changes were related to treatment level and flow rates. Both disposal quality and quantity are important since changes in soft-bottom assemblages in stations affected by pre-treated sewage with medium and high flow rates are observed. However, the location with a low-flow pre-treated effluent has similar polychaete assemblages with regard to locations with biological treatment or controls.