Using stable isotope analyses to assess carbon dynamics in a shallow subtropical estuary

The sources of carbon, which fuel water column respiration, remain unresolved for most estuaries; our objective was to examine carbon dynamics in a shallow subtropical estuary. We sampled the Sabine-Neches estuary, Texas, during low (November 1999) and high (May 2000) freshwater inflow and measured stable carbon isotope ratios of the dissolved inorganic and orgnaic carbon (δ¹³C-DIC, δ¹³C-DOC), as well as quantifying accessory parameters (salinity, nutrients, total suspended solids, and photosynthetic pigments). Pigment analysis indicated that diatoms were the predominant phytoplankton. Data from the May 2000 sampling event exhibited conservative mixing, indicating that the system was acting as a conduit between the watershed and the Gulf of Mexico. During November, mixing was generally nonconservative indicating extensive recycling of allochthonous and autochthonous carbon sources. Our data imply that both carbon sources had similar isotope, ratios that made it impossible to unambiguously determine the dominant source supporting respiration. The nonconservative DIC concentration data indicating an autotrophic sink as well as the strong relationship between δ¹³C-DOC and chlorophylla, suggest that in situ production was an important component of the DOC pool. We hypothesize that uncharacteristically calm wind conditions during sampling may have promoted phytoplankton settling, removing autotrophs, from the water column, but leaving behind a dissolved biogeochemical signature. Interpretation of carbon dynamics may be confounded by spatial and temporal decoupling of producers and consumers from biogeochemical indicators.     

Influence of earthquake ground‐motion duration on damage estimation: application to steel moment resisting frames

This paper presents an analytical study evaluating the influence of ground motion duration on structural damage of 3‐story, 9‐story, and 20‐story SAC steel moment resisting frame buildings designed for downtown Seattle, WA, USA, using pre‐Northridge codes. Two‐dimensional nonlinear finite element models of the buildings are used to estimate the damage induced by the ground motions. A set of 44 ground motions is used to study the combined effect of spectral acceleration and ground motion significant duration on drift and damage measures. In addition, 10 spectrally equivalent short‐duration shallow crustal ground motions and long‐duration subduction zone records are selected to isolate duration effect and assess its effect on the response. For each ground motion pair, incremental dynamic analyses are performed at at least 20 intensity levels and response measures such as peak interstory drift ratio and energy dissipated are tracked. These response measures are combined into two damage metrics that account for the ductility and energy dissipation. Results indicate that the duration of the ground motion influences, above all, the combined damage measures, although some effect on drift‐based response measures is also observed for larger levels of drift. These results indicate that because the current assessment methodologies do not capture the effects of ground motion duration, both performance‐based and code‐based assessment methodologies should be revised to consider damage measures that are sensitive to duration. Copyright © 2016 John Wiley & Sons, Ltd     

Optimal instrumentation of uncertain structural systems subject to earthquake ground motions

A criterion is proposed for making decisions regarding the optimal location of a given number of sensors to record the seismic response of a structure for identification purposes. The optimal location of the sensors is selected so that the expected value of a Bayesian loss function, expressed in terms of the Fisher information in the recordings, is minimized. The criterion is applied to the case of multi-degree-of-freedom systems with uncertain structural properties subjected to earthquake ground motions modelled as stationary stochastic processes. The use and capabilities of the criterion are thoroughly illustrated by means of an example. Results are used to assess the influence of record duration, recording noise, and ground motion frequency content and amplitude, on the optimal location of accelerometers as well as on the reduction of prior uncertainty about the structural parameters. © 1998 John Wiley & Sons, Ltd.     

Crossover from Nonlinearity Controlled to Heterogeneity Controlled Mixing in Two-Phase Porous Media Flows

We use high resolution Monte Carlo simulations to study the dispersive mixing in two-phase, immiscible, porous media flow that results from the interaction of the nonlinearities in the flow equations with geologic heterogeneity. Our numerical experiments show that distinct dispersive regimes occur depending on the relative strength of nonlinearity and heterogeneity. In particular, for a given degree of multiscale heterogeneity, controlled by the Hurst exponent which characterizes the underlying stochastic model for the heterogeneity, linear and nonlinear flows are essentially identical in their degree of dispersion, if the heterogeneity is strong enough. As the heterogeneity weakens, the dispersion rates cross over from those of linear heterogeneous flows to those typical of nonlinear homogeneous flows.     

On the utility of identification schemes for digital earth science data: an assessment and recommendations

In recent years, a number of data identification technologies have been developed which purport to permanently identify digital objects. In this paper, nine technologies and systems for assigning persistent identifiers are assessed for their applicability to Earth science data (ARKs, DOIs, XRIs, Handles, LSIDs, OIDs, PURLs, URIs/URNs/URLs, and UUIDs). The evaluation used four use cases that focused on the suitability of each scheme to provide Unique Identifiers for Earth science data objects, to provide Unique Locators for the objects, to serve as Citable Locators, and to uniquely identify the scientific contents of data objects if the data were reformatted. Of all the identifier schemes assessed, the one that most closely meets all of the requirements for an Unique Identifier is the UUID scheme. Any of the URL/URI/IRI-based identifier schemes assessed could be used for Unique Locators. Since there are currently no strong market leaders to help make the choice among them, the decision must be based on secondary criteria. While most publications now allow the use of URLs in citations, so that all of the URL/URI/IRI based identification schemes discussed in this paper could potentially be used as a Citable Locator, DOIs are the identification scheme currently adopted by most commercial publishers. None of the identifier schemes assessed here even minimally address identification of scientifically identical numerical data sets under reformatting.     

The Sima de los Huesos (Burgos,northern Spain): palaeoenvironment and habitats of Homo heidelbergensis during the Middle Pleistocene

Interpreting how environmental dynamics respond to global climate change and how this has affected human evolution and dispersal is an on-going topic of debate. During the early Middle Pleistocene (～0.6–0.4 Ma), as compared to earlier, environmental conditions were relatively more stable, with longer climatic cycles alternating between open and forested landscapes. During this interval, humans spread successfully providing an important number of fossil sites where fossils or tools are reported. The Atapuerca-Sima de los Huesos (Burgos, northern Spain) site (Atapuerca-SH) is one of the earliest localities with hominin evidence in the European Middle Pleistocene, with the most important accumulation of Homo heidelbergensis so far. We have analyzed the abundant faunal record from Sima de los Huesos, which is mainly comprised of carnivores, in order to approach an interpretation of the palaeoenvironmental circumstances where these hominids inhabited within the Sierra. Other sites from Sierra de Atapuerca referred to the same Faunal Unit (FU 6), are roughly contemporaneous, and include important ungulates, which are here analyzed with Atapuerca-SH. Additional information provided by isotopic analysis helps elucidate the ancient ecology of taxa present in Sima de los Huesos allowing for an accurate portrayal of the setting in which humans lived. The timing of the spread of Homo heidelbergensis is dominated by a relative climatic and environmental stability and points to a landscape dominated by savannah-like open woodland.     

Flexural and gravity modelling of the Mérida Andes and Barinas–Apure Basin, Western Venezuela

The kinematic evolution of the Barinas–Apure Basin and the southern Mérida Andes from Lower Miocene to the Present is numerically modelled using flexural isostatic theory and geophysical and geological data. Two published regional transects are used to build up a reference section, which is then used to constrain important parameters (e.g. shortenings and sedimentary thicknesses) for the flexural modelling. To control the location of the main fault system in the flexural model earthquake information is also used. The estimated flexural elastic thickness of the South American lithosphere beneath the Barinas–Apure Basin and the Mérida Andes Range is 25 km. The value for the final total shortening is 60 km. The flexural isostatic model shows that the Andean uplift has caused the South American lithosphere subsidence and the development of the Barinas–Apure Basin.In addition, gravity modelling was used to understand deep crustal features that could not be predicted by flexural theory. Consequently, the best-fit flexural model is used to build a gravity model across the Mérida Andes and the Barinas–Apure Basin preserving the best-controlled structural features from the flexural modelling (e.g. basin wavelength and depth) and slightly changing the main bodies density values and deep crustal structures. The final gravity model is intended to be representative of the major features affecting the gravity field in the study area. The predicted morphology in the lower crustal level of the final gravity model favours the hypothesis of a present delamination or megathrust of the Maracaibo crust over the South American Shield. This process would use the Conrad discontinuity as a main detachment surface within an incipient NW dipping continental subduction.     

Groundwater contamination with arsenic and other trace elements in an area of the pampa,province of Córdoba,Argentina

A geochemical study of groundwater of the pampa in the province of Córdoba, Argentina, was performed; the area covered approximately 10,000 km².Physical-chemical parameters, dissolved solids, and seven trace elements were determined in 60 selected water samples. Systematic and accurate measurements of arsenic, flourine, and vanadium were performed for the first time. Three trace element contaminants not reported earlier were found: an important one, selenium, and two others of less known effects, uranium and molybdenum.Eighty-four percent of the water analyzed showed arsenic contents over 0.05 mg/L, maximum contaminant level established by the U.S. Environmental Protection Agency (1982). The frequency distribution of trace elements was analyzed, and its fit to the lognormal distribution was proved by means of the Pearson and Kolmogorov-Smirnov test; the geographic distribution of the seven trace elements was mapped and its correlation with the anion-cation composition of the water was studied.The maximum arsenic, fluorine, vanadium, and uranium contents were found in the western part of the area under study, in waters containing dominant alkali metals in the cation composition. Maximum selenium and antimony contents were found in the eastern part of the area, while molybdenum distribution does not show any relationship with the other two groups. In addition, the geographic distribution of the trace elements seems to be related to the subsurface structure, which has been inferred using interactive digital analysis of Landsat imagery. The movements of the subsoil have disturbed surface and subsurface drainage influencing the water salinity and trace element contents.In order to investigate the origin of the contamination, 54 loess samples were collected in wells at depths ranging from the surface down to the water table. This loess, which has a high proportion of volcanic components, mainly rhyolitic glass, exhibits a chemical composition corresponding to that of a dacite.The loess and the volcanic glass show anomalous contents of all contaminant trace elements, mainly arsenic and selenium. For this reason loess is considered the most important contamination source in the groundwater under study.     

Geological characteristics of 2011 Japan tsunami sediments deposited along the coast of southwestern Mexico

The tsunami of 11th March 2011 was originated at the east coast of Japan and deposited ca.1 cm thick sediment layer along the coast of southwestern Mexico up to a maximum distance of 320 m from the beach. The sedimentological, mineralogical and geochemical characteristics of the sediments deposited during the tsunami (JT) are compared with the pre-tsunami sediments (PRT). JT sediments consist of dominant coarser fractions (>54% of medium to coarse sand), whereas PRT deposits comprise abundant finer fractions (>58% of fine sand). Assemblage of mafic and heavy minerals suggests similar provenance for both. The higher abundance and variation of heavy minerals along with higher concentrations of bromine (Br) and sodium (Na) in the JT deposits reveal the influence of high energy sea waves in transportation of heavy mineral rich coarse sediments onto the coastal lowlands.