The influence of diurnal temperatures on the hydrochemistry of a tufa‐depositing stream

At‐a‐station diurnal variations in carbonate hydrochemistry were measured during four observation periods at Davys Creek, a tufa‐depositing stream in central NSW, Australia. Major ion concentrations and continuously logged measurements of specific conductivity, pH and temperature showed that changes in the amount of CaCO₃ deposited upstream of the study reach were directly related to changes in diurnal water temperatures, which control the rate of CO₂ efflux to the atmosphere. The greatest upstream losses occurred during the mid‐afternoon water temperature peak, whereas the lowest upstream losses occurred at sunrise, when water temperatures were at their lowest. Cloudy days at all times of the year produced small diurnal water temperatures ranges (c. 2–5°C) and, consequently, relatively small changes in upstream CaCO₃ loss (23–50 mg L^?1) through the day. Clear sunny days, especially during summer months, produced large diurnal water temperature changes (up to c. 11°C), which in turn triggered diurnal changes in upstream CaCO₃ loss of up to 100 mg L^?1. By implication, the active reach of tufa deposition must advance downstream and increase in length during the evening and vice versa during the day. Given that the temperature of Davys Creek waters are a function of insolation, changes in the reach of tufa deposition under baseflow conditions are a direct function of the prevailing weather. This has implications for the palaeoclimatic interpretation of fossil tufa deposits. Copyright © 2003 John Wiley & Sons, Ltd.     

Preliminary Quantitative Assessment of Earthquake Casualties and Damages

Prognostic estimations of the expected number of killed or injured people and about the approximate cost associated with the damages caused by earthquakes are made following a suitable methodology of wide-ranging application. For the preliminary assessment of human life losses due to the occurrence of a relatively strong earthquake we use a quantitative model consisting of a correlation between the number of casualties and the earthquake magnitude as a function of population density. The macroseismic intensity field is determined in accordance with an updated anelastic attenuation law, and the number of casualties within areas of different intensity is computed using an application developed in a geographic information system (GIS) environment, taking advantage of the possibilities of such a system for the treatment of space-distributed data. The casualty rate, defined as the number of killed people divided by the number of inhabitants of the affected region, is also computed and we show its variation for some urban concentrations with different population density. For a rough preliminary evaluation of the direct economic cost derived from the damages, equally through a GIS-based tool, we take into account the local social wealth as a function of the gross domestic product of the country. This last step is performed on the basis of the relationship of the macroseismic intensity to the earthquake economic loss in percentage of the wealth. Such an approach to the human casualty and damage levels is carried out for sites near important cities located in a seismically active zone of Spain, thus contributing to an easier taking of decisions in emergency preparedness planning, contemporary earthquake engineering and seismic risk prevention.     

Full Causal Bulk Viscous LRS Bianchi I With Time Varying Constants

In this paper we study the evolution of a LRS Bianchi I Universe, filled with a bulk viscous cosmological fluid in the presence of time varying constants “but” taking into account the effects of a c-variable into the curvature tensor. We find that the only physical models are those which “constants” G and c are growing functions on time t, while the cosmological constant Λ is a negative decreasing function. In such solutions the energy density obeys the ultrastiff matter equation of state i.e. ω = 1.     

Impact of quarrying gypsum in a semidesert karstic area (Sorbas,SE Spain)

The Messinian gypsum of Sorbas is intensively karstified, with hundreds of dolines and numerous, highly unusual exo- and endokarstic forms. Amongst these the tumuli are especially spectacular, as are the large caverns, adorned with numerous speleothems, some of which have not been described anywhere else in the World. The extraction of the gypsum has impacted practically all the elements of the environment (landscape, water, soil, subsoil, flora, fauna, etc.) and, in particular, all of the karstic forms. In addition to endangering the caves and the natural treasures that they contain, it affects the surface waters, markedly modifying the hydrographic network. Groundwaters, which now occur in the bottom of a quarry, are also affected.     

Investigation of natural and anthropogenic hydrocarbon inputs in sediments using geochemical markers. I. Santos, SP--Brazil

A study on the inputs of organic matter to marine sediments of Santos Bay and Estuary, located in southeastern S?o Paulo State, Brazil, is presented here. The following geochemical markers were identified and quantified: aliphatic hydrocarbons (normal and isoprenoid alkanes), petroleum biomarkers, linear alkylbenzenes (LABs) and polycyclic aromatic hydrocarbons (PAHs). Sediment samples, collected at 15 sites in the bay and surrounding channels, were extracted and analyzed by gas chromatography with flame ionization and mass spectrometer detectors. Total concentrations varied from 0.17 to 107.80 microg g(-1) for aliphatics, from 47.2 to 2560.1 ng g(-1) for petroleum biomarkers, from 16.9 to 430.6 ng g(-1) for LABs and from 79.6 to 15389.1 ng g(-1) for PAHs. Anthropogenic contributions were apparent, indicating the influences of the Cubatao industrial complex, sewage outfalls along the area, the waste deposit of Santos city and storage facilities for petroleum and derivatives, based on the higher concentrations of geochemical markers detected.     

Hydrothermal mixing,carbonate dissolution and sulfide precipitation in Mississippi Valley-type deposits

A large number of Mississippi Valley-Type (MVT) deposits are located within dissolution zones in carbonate host rocks. Some genetic models propose the existence of cavities generated by an earlier event such as a shallow karstification, that were subsequently filled with hydrothermal minerals. Alternative models propose carbonate dissolution caused by the simultaneous precipitation of sulfides. These models fail to explain either the deep geological setting of the cavities, or the observational features which suggest that the dissolution of carbonates and the precipitation of minerals filling the cavities are not strictly coeval. We present a genetic model inspired by the textural characteristics of MVT deposits that accounts for both the dissolution of carbonate and precipitation of sulfides and later carbonates in variable volumes. The model is based on the mixing of two hydrothermal fluids with a different chemistry. Depending on the proportion of the end members, the mixture dissolves and precipitates carbonates even though the two mixing solutions are both independently saturated in carbonates. We perform reactive transport simulations of mixing of a regional groundwater and brine ascending through a fracture, both saturated in calcite, but with different overall chemistries (Ca and carbonate concentrations, pH, etc). As a result of the intrinsic effects of chemical mixing, a carbonate dissolution zone, which is enhanced by acid brines, appears above the fracture, and another zone of calcite precipitation builds up between the cavity and the surrounding rock. Sulfide forms near the fracture and occupies a volume smaller than the cavity. A decline of the fluid flux in the fracture would cause the precipitation of calcite within the previously formed cavities. Therefore, dissolution of carbonate host rock, sulfide precipitation within the forming cavity, and later filling by carbonates may be part of the same overall process of mixing of fluids in the carbonate host rock.Editorial handling: C. Everett     

Neoproterozoic–Cambrian synsedimentary magmatism in the Central Iberian Zone (Spain): geology,petrology and geodynamic significance

Petrographic, geochemical and field studies in low grade metamorphic areas (Ciudad Rodrigo-Hurdes-Sierra de Gata domain, CRHSG, central-western Spain) show that Neoproterozoic-Lowermost Cambrian series in the Central Iberian Zone (CIZ) record two kinds of provenance sources including: (1) detrital material derived from recycled orogens and (2) a Cadomian coeval juvenile contribution that governs their isotopic signature. Evidence of magmatism contemporaneous with Neoproterozoic-Cambrian sedimentation is provided by the presence of coherent, massive volcanic rocks (metabasalts, metaandesites, and metarhyolites), volcaniclastic shales, sandstones, conglomerates and breccias. The appearance of volcanogenic lithic fragments and crystals mixed in different proportions with siliciclastic constituents and also present within calcareous components in the sedimentary succession, reinforces this evidence. Although most of the selected volcanic and volcaniclastic samples appear to show tholeiitic affinity, some of them display calc-alkaline affinity. Different trace element ratios, such as Sm/Nd, Nb/Yb and Ta/Yb, suggest a magmatic evolution in the same tectonic setting. The geochemical results reported here support the existence of an active geodynamic setting as a direct contributor to the synsedimentary and magmatic content of the Neoproterozoic–Lowermost Cambrian successions in the CIZ. In particular, the relatively high Nd _(T) values and the high range of f ^Sm/Nd ratios are consistent with an active margin during the Neoproterozoic–Early Cambrian. The existence of tectonic activity is also confirmed by the presence of synsedimentary deformation and volcanic rocks. All of these traits favour a geodynamic model in which the Iberian Cadomian segment represented in the CIZ would have been part of an active northern margin of Gondwana, with an associated magmatic arc and related basins during Neoproterozoic–Lower Cambrian times. A proposed link between the Ossa Morena and the Central Iberian Zones might account for late Cadomian pull-apart basins developed on both sides of the magmatic arc, sharing the same scenario and involving similar magmatic activity during the Neoproterozoic–Cambrian transition.

Geological,geophysical and geochemical structure of a fault zone developed in granitic rocks: Implications for fault zone modeling in 3-D

The structure of a fault zone developed in granitic rocks can be established on the basis of the spatial variability of geological, geophysical and geochemical parameters. In the North Fault of the Mina Ratones area (SW Iberian Massif, Spain), fault rocks along two studied traverses (SR-2 and SR-3 boreholes) exhibit systematic changes in mineralogy, geochemistry, fabrics and microstructures that are related to brittle deformation and alteration of granite to form cataclasite and subsequent gouge. The spatial distribution and intensity of these changes suggest a North Fault morphology that is consistent with the fault-core/damage-zone model proposed by Chester et al. (1993) to describe a fault zone architecture. North Fault damage zone thickness can be defined by the development of mechanically related mesoscopic faults and joints, that produce a Fracture Index (FI)>10. High FI values are spatially correlated with relative low seismic velocity zones (V_P<5 km/s and V_S<2.5 km/s in the well-logs), more probably related to a high concentration of fractures and geochemical alteration produced by meteoric water-granite interaction along fault surfaces. This correlation is the base of a geostatistical model proposed in the final part of this study to image the fault zone architecture of a granitic massif.     

The role of porosity in the development of authigenic dolomite and palygorskite. An example in siliceous sandstones of continental origin in Western Spain

During the Tertiary, the Hercynian basement of the Iberian Peninsula was uneven due to Alpine tectonism which led to the development of a set of horsts and grabens forming its main geological structure. One of these grabens is the Ciudad Rodrigo Basin, located close to the Portuguese border. The south-western margin of this graben is filled with arkosic sandstones of continental origin that, once deposited, underwent important low-grade diagenetic processes related to the surface processes. The main diagenetic processes were hydrolysis, replacement by carbonate, and argillization to palygorskite. These three processes led to the differentiation of three main levels within the outcrops studied: (1) the Lower Level, where the original clayey sandstone outcrops, displaying fairly hydromorphic traits; (2) the Middle Level, where part of the clayey matrix has been replaced by dolomitic carbonate; and (3) the Upper Level, where palygorskite is the new neoformed clay. The change in porosity seems to have been the controlling factor, since it governs the dynamics of the solutions inside the rocks. These conditions changed from being diffusion-driven, at the start of the diagenesis, to flow-driven as porosity increased.     

The use of the marine biotic index AMBI in the assessment of the ecological status of the Obidos lagoon (Portugal)

This study reports the longitudinal distribution of sediment properties, including inorganic and organic contaminants, and the structure of the benthic community in Obidos lagoon, a coastal system permanently connected to the sea and with negligible freshwater sources. Sediments from the upper to central lagoon consist of fine particles (91%) and from the lower lagoon of sands (94%). Chemical composition is strongly correlated to the percentage of fine particles. Contamination is relatively low in those sediments suggesting the effect of diffuse sources. The increase in organic matter content from down- to upstream areas was associated with the dominance of opportunistic species, while sensitive and indifferent species to organic enrichment were mainly associated to the clean sandy downstream area. The marine biotic index (AMBI) was suitable for the discrimination of the biological and environmental gradients in the Obidos lagoon and was highly related with the gradient of organic matter content in this system.