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171.
Alissa IoannoneAntonella Catucci Marco GrassoGian Luca Eusebi Borzelli 《Continental Shelf Research》2011,31(1):37-46
The variability and scales of the sea surface structure of the northern Ionian Sea from January 1993 to December 2007 were studied by means of altimeter remotely-sensed weekly Sea Level Anomaly (SLA) objective maps. Variability in the sea surface structure was addressed by means of empirical orthogonal function (EOF) analysis and, assuming an exponential correlation model, scales of the SLA field were quantified as e-folding distances of the SLA autocorrelation function. The variability in the sea surface structure, described by the first three EOFs, which cumulatively explain 60.3% of the data set variance, is characterized by a large-scale structure with variability on a time scale of ∼10-13 years and, on shorter scales, an eddy system with variability on an annual scale. The variability in the large-scale structure describes an overturning of the SLA field, which took place in 1997, and determines a reversal of the geostrophic upper-layer circulation. As the large-scale circulation transition takes place, time-dependent spectral analysis of EOF coefficients shows a redistribution of the spectral energy from inter-annual to semi-annual and monthly components. Spatial scales display variability on an annual and inter-annual time scale. On the annual time scale, variability in spatial scales is characterized by longer values in summer-fall and shorter in winter-spring. Inter-annual variability in spatial scales is demonstrated by a remarkable drop in the values during fall in the period 1998-2000. We propose an explanation of the variability in horizontal scales in terms of the redistribution of water masses and related modifications of the vertical structure of the water column associated with different regimes of the basin-scale circulation. 相似文献
172.
Chiara Elmi Maria Franca Brigatti Luca Pasquali Monica Montecchi Angela Laurora Daniele Malferrari Stefano Nannarone 《Physics and Chemistry of Minerals》2011,38(6):459-468
A multi-methodical approach has been applied for characterizing the bulk and surface crystal chemical features of a high-temperature
vesuvianite crystal from skarns of Mount Somma-Vesuvius Volcano (Naples, Italy). Vesuvianite belongs to the space group P4/nnc with unit cell parameters a = 15.633(1) Å, c = 11.834(1) Å and chemical formula (Ca18.858 Na0.028 Ba0.004 K0.006 Sr0.005 □0.098)19.000 (Al8.813 Ti0.037 Mg2.954 Mn0.008 Fe0.1142+ Fe1.3753+ Cr0.008 B0.202)13.511 Si18.000(O0.261 F0.940 OH7.799)9.000. Structure refinement, which converges at R = 0.0328, demonstrates a strong positional disorder down the fourfold axes, indicating that the Y1 site is split into two
positions (Y1A and Y1B) alternatively occupied. However, because of X4 proximity to Y1B and Y1A, X4 cannot be occupied if
Y1B or Y1A are. Overall Y1 occupancy (Y1A + Y1B) reaches approximately 0.5, as common in vesuvianite and occupancy of Y1B
site is extremely limited. Moreover, T1 position, limitedly occupied, accommodates the excess of cations generally related
to Y position. A small quantity (0.202 apfu) of boron is sited at the T2 site that, like T1, is poorly occupied. The determination
of the amount of each element on the (100) vesuvianite surface, obtained through X-ray photoelectron spectroscopy high-resolution
spectra in the region of the Si2p, Al2p, Mg1s, and Ca2p core levels, evidences that a greater amount of aluminum and a smaller amount of calcium characterize the surface with respect
to the bulk. Although both of these features require further investigation, we may consider the Al increase can be related
to preferential orientation of Al-rich sites on the (100) plane. Furthermore, the surface structure of vesuvianite suggests
that Al, Ca, and Mg cations maintain coordination features at the surface similar to the bulk. Silica, however, while presenting
fourfold coordination, shows also a [1]-fold small coordinated component at binding energy 99.85 eV, due to broken Si–O bonds
at the surface. The presence of eight- and nine-coordinated Ca cations is suggested by a large XPS feature resulting from
the merging of Ca2p3/2 and Ca2p1/2 peaks at 348.45 and 352.05 eV, respectively. 相似文献
173.
Identifying sources of chlorinated aliphatic hydrocarbons in a residential area in Italy using the integral pumping test method 总被引:1,自引:0,他引:1
The results of integral pumping tests (IPTs) performed in the city of Fabriano, Italy, are presented. The IPT methodology was developed by the European Union project INCORE, as a tool for groundwater investigation and source localization in contaminated areas. This methodology consists of a multiple-well pumping test in which the wells are positioned along a control plane downstream of suspected contaminant source zones and perpendicular to the mean groundwater flow direction. During the pumping, concentration time series of target contaminants are measured. In Fabriano, two control planes were realized to identify a chlorinated aliphatic hydrocarbon plume, to estimate the mass fluxes and draw up a ranked list of the main contamination sources. A numerical flow model was implemented to support the IPT design and to interpret the results. This study revealed low-level trichloroethylene contamination (concentration below 8 μg/l), tetrachloroethylene contamination (mean concentration up to 500 μg/l) and a mass flow rate of about 300 g/day. Through the application of the IPT method, the mean contaminant concentrations, the spatial distribution of concentration values along the control planes, and the total contaminant mass flow rates were evaluated, and the investigation area was reduced for further and deeper investigation activities. 相似文献
174.
Ivana La Licata Christian D. Langevin Alyssa M. Dausman Luca Alberti 《Hydrogeology Journal》2011,19(7):1313-1322
Variable-density groundwater models require extensive computational resources, particularly for simulations representing short-term hydrologic variability such as tidal fluctuations. Saltwater-intrusion models usually neglect tidal fluctuations and this may introduce errors in simulated concentrations. The effects of tides on simulated concentrations in a coastal aquifer were assessed. Three analyses are reported: in the first, simulations with and without tides were compared for three different dispersivity values. Tides do not significantly affect the transfer of a hypothetical contaminant into the ocean; however, the concentration difference between tidal and non-tidal simulations could be as much as 15%. In the second analysis, the dispersivity value for the model without tides was increased in a zone near the ocean boundary. By slightly increasing dispersivity in this zone, the maximum concentration difference between the simulations with and without tides was reduced to as low as 7%. In the last analysis, an apparent dispersivity value was calculated for each model cell using the simulated velocity variations from the model with tides. Use of apparent dispersivity values in models with a constant ocean boundary seems to provide a reasonable approach for approximating tidal effects in simulations where explicit representation of tidal fluctuations is not feasible. 相似文献
175.
The Multi-scale Soil Information System (MEUSIS) can be a suitable framework for building a nested system of soil data that could facilitate interoperability through a common coordinate reference system, a unique grid coding database, a set of detailed and standardized metadata, and an open exchangeable format. In the context of INSPIRE Directive, MEUSIS may be implemented as a system facilitating the update of existing soil information and accelerating the harmonization of various soil information systems. In environmental data like the soil one, it is common to generalize accurate data obtained at the field to coarser scales using either the pedotransfer rules or knowledge of experts or even some statistical solutions which combine single values of spatially distributed data. The most common statistical process for generalization is averaging the values within the study area. In this paper, we do not present a simple averaging of numerical values without any further processed information. The upscaling process is accompanied with significant statistical analysis in order to demonstrate the method suitability. The coarser resolution nested grids cells (10??? 10?km) represent broad regions where the calculated soil property (e.g., organic carbon) can be accurately upscaled. Multi-scaled approaches are urgently required to integrate different disciplines (such as Statistics) and provide a meta-model platform to improve current mechanistic modeling frameworks, request new collected data, and identify critical research questions. Past papers have described in detail the upscaling methodology while our present approach is to demonstrate an important application of this methodology accompanied with statistical evidence. 相似文献
176.
Di Virgilio Giovanni Evans Jason P. Di Luca Alejandro Grose Michael R. Round Vanessa Thatcher Marcus 《Climate Dynamics》2020,54(11):4675-4692
Climate Dynamics - Coarse resolution global climate models (GCMs) cannot resolve fine-scale drivers of regional climate, which is the scale where climate adaptation decisions are made. Regional... 相似文献
177.
Daniele Spiga Gianpiero Tagliaferri Paolo Soffitta Oberto Citterio Stefano Basso Ronaldo Bellazzini Alessandro Brez Wolfgang Burkert Vadim Burwitz Enrico Costa Luca de Ruvo Ettore Del Monte Sergio Fabiani Gisela Hartner Benedikt Menz Massimo Minuti Fabio Muleri Giovanni Pareschi Michele Pinchera Alda Rubini Carmelo Sgrò Gloria Spandre 《Experimental Astronomy》2014,37(1):37-53
The Joint European X-ray Telescope (JET-X) was the core instrument of the Russian Spectrum-X- γ space observatory. It consisted of two identical soft X-ray (0.3–10 keV) telescopes with focusing optical modules having a measured angular resolution of nearly 15 arcsec. Soon after the payload completion, the mission was cancelled and the two optical flight modules (FM) were brought to the Brera Astronomical Observatory where they had been manufactured. After 16 years of storage, we have utilized the JET-X FM2 to test at the PANTER X-ray facility a prototype of a novel X-ray polarimetric telescope, using a Gas Pixel Detector (GPD) with polarimetric capabilities in the focal plane of the FM2. The GPD was developed by a collaboration between INFN-Pisa and INAF-IAPS. In the first phase of the test campaign, we have re-tested the FM2 at PANTER to have an up-to-date characterization in terms of angular resolution and effective area, while in the second part of the test the GPD has been placed in the focal plane of the FM2. In this paper we report the results of the tests of the sole FM2, using an unpolarized X-ray source, comparing the results with the calibration done in 1996. 相似文献
178.
Tertiary folds of the central and eastern part of the Algerian Atlas were studied in order to assess their kinematics and regimes of deformation. Folds developed following two main phases of deformation during the Eocene and the Pliocene. The NE-SW trending Eocene folds show a clockwise rotation of fold axis with depth, noncylindrical geometry and a right-stepping en echelon configuration. Early secondary structures inside each fold are also rotated clockwise with respect to the younger folds. These data are in agreement with progressive ‘simple shear’ deformation. Pliocene folds strike E-W and display a cylindrical geometry. Associated Plio-Quaternary brittle structures show no rotational path. These observations are compatible with ‘pure shear’ style of deformation. These results, in combination with focal mechanism solutions, have important implications for the understanding of the kinematic evolution of the western segment of the African-European plate boundary. For Algeria they imply that transcurrent motion during the Paleogene was followed by coaxial shortening with a NNW direction during Neogene-Quaternary times. Comparison with published data for Morocco and Tunisia suggests that this transcurrent regime developed from west to east continuing from the Middle Jurassic through to the Miocene. 相似文献
179.
A series of experiments was performed using artificial seawater samples of increasing complexity, in order to identify, qualitatively and quantitatively, the contribution of main seawater components on the buffer capacity for CO2.The results show that magnesium plays the most important role in the uptake, enhancing the capacity of the carbonate system alone by more than 100%. 相似文献
180.
Edoardo Barbero Luca Pandolfi Morteza Delavari Asghar Dolati Emilio Saccani Rita Catanzariti Valeria Luciani Marco Chiari Michele Marroni 《地学前缘(英文版)》2021,12(3):101106
The Durkan Complex is a key tectonic element of the Makran accretionary prism (SE Iran) and it has been interpreted as representing a continental margin succession. We present here a multidisciplinary study of the western Durkan Complex, which is based on new geological, stratigraphic, biostratigraphic data, as well as geochemical data of the volcanic and meta-volcanic rocks forming this complex. Our data show that this complex consists of distinct tectonic slices showing both non-metamorphic and very low-grade metamorphic deformed successions. Stratigraphic and biostratigraphic data allow us to recognize three types of successions. Type-I is composed by a Coniacian – early Campanian pelagic succession with intercalation of pillow lavas and minor volcaniclastic rocks. Type-II succession includes a volcanic sequence passing to a volcano-sedimentary sequence with Cenomanian pelagic limestones, followed by a hemipelagic sequence. This succession is characterized by abundant mass-transport deposits. Type-III succession includes volcanic and volcano-sedimentary sequences, which are stratigraphically covered by a Cenomanian platform succession. The latter is locally followed by a hemipelagic sequence. The volcanic rocks in the different successions show alkaline geochemical affinity, suggesting an origin from an oceanic within-plate setting. Our new results indicate that the western Durkan Complex represents fragments of seamounts tectonically incorporated in the Makran accretionary wedge during the latest Late Cretaceous–Paleocene. We propose that incorporation of seamounts in the frontal prism caused a shortening of the whole convergent margin and possibly contributed to controlling the deformation style in the Makran Accretionary Wedge during Late Cretaceous–Paleocene times. 相似文献