Water–rock interaction during the process of steam stimulation exploitation of viscous crude oil in Liaohe Shuguang Oil Field, Liaoning, China

In the process of steam stimulation exploitation of viscous crude oil, the injected water, at high temperature and under high pressure, reacts intensively with the host rock. This kind of water–rock interaction in Liaohe Shuguang Oil Field was studied on the basis of analysis of water composition changes, laboratory experiments, mineral saturation indices analysis, and mass balance calculation. Compared with the injected water, the changes of the composition of discharged water are mainly the distinct decrease of pH, Na⁺, SiO₂ and Cl⁻, as well as the increase of K⁺, Ca²⁺, Mg²⁺, SO ₄ ²⁻ and HCO ₃ ⁻ . Laboratory experiments under field conditions showed: the dissolution sequence of minerals quantitatively is quartz>potassium feldspar>albite, and the main change of clay minerals is the conversion of kaolinite to analcime. Mass balance calculation indicated during the process of steam stimulation, large quantities of analcime are precipitated with the dissolution of large amounts of quartz, kaolinite, potassium feldspar, and CO₂. These results correlated very well with the experimental results. The calculated results of Liaohe Shuguang Oil Field showed that during the steam stimulation for viscous crude oil, the amounts of minerals dissolved (precipitated) are huge. To control the clogging of pore spaces of oil reservoirs, increased study of water–rock interaction is needed.     

A simple hypoplastic model for normally consolidated clay

The paper presents a simple constitutive model for normally consolidated clay. A mathematical formulation, using a single tensor-valued function to define the incrementally nonlinear stress–strain relation, is proposed based on the basic concept of hypoplasticity. The structure of the tensor-valued function is determined in the light of the response envelope. Particular attention is paid towards incorporating the critical state and to the capability for capturing undrained behaviour of clayey soils. With five material parameters that can be determined easily from isotropic consolidation and triaxial compression tests, the model is shown to provide good predictions for the response of normally consolidated clay along various stress paths, including drained true triaxial tests and undrained shear tests.     

Dissolved trace elements in river water: spatial distribution and the influencing factor, a study for the Pearl River Delta Economic Zone, China

Twenty-nine water samples were collected from different river channels of the Pearl River Delta Economic Zone, China. An inductively coupled plasma-mass spectromonitor (ICP-MS) was used to measure concentrations of the trace elements in these samples. The results suggest that the average concentrations of rare earth elements in river water show an increasing trend from the West River, the North River, the rivers of the Pearl River Delta, and the Shenzhen River to the East River. Relatively high concentrations of heavy metals appear in the East River, the rivers of the Pearl River Delta and the Shenzhen River, while the West River and the North River have relatively low heavy metal concentrations. Trace element concentrations in samples collected near urban or industrial areas are much higher than those of samples collected from distant areas, away from urban and industrial areas. After natural conditions, human activities have significant influence on the trace element concentrations in river water. This trace element concentration’s spatial distribution in the river water from the Pearl River Delta Economic Zone is actually an integrated effect of natural conditions and human activity.     

Diurnal Variations of Hydrochemistry in a Travertine-depositing Stream at Baishuitai, Yunnan, SW China

Diurnal variations of hydrochemistry were monitored at a spring and two pools in a travertine-depositing stream at Baishuitai, Yunnan, SW China. Water temperature, pH and specific conductivity were measured in intervals of 5 and 30 min for periods of 1 to 2 days. From these data the concentrations of Ca²⁺, HCO₃⁻, calcite saturation index, and CO₂ partial pressure were derived. The measurements in the spring of the stream did not show any diurnal variations in the chemical composition of the water. Diurnal variations, however, were observed in the water of the two travertine pools downstream. In one of them, a rise in temperature (thus more CO₂ degassing) during day time and consumption of CO₂ due to photosynthesis of submerged aquatic plants accelerated deposition of calcite, whereas in the other pool, where aquatic plants flourished and grew out of the water (so photosynthesis was taking place in the atmosphere), the authors suggest that temperature-dependent root respiration underwater took place, which dominated until noon. Consequently, due to the release of CO₂ by the root respiration into water, which dominated CO₂ production by degassing induced by temperature increase, the increased dissolution of calcite was observed. This is the first time anywhere at least in China that the effect of root respiration on diurnal hydrochemical variations has been observed. The finding has implications for sampling strategy within travertine-depositing streams and other similar environments with stagnant water bodies such as estuaries, lakes, reservoirs, pools and wetlands, where aquatic plants may flourish and grow out of water.     

桂北地区早石炭世杜内期的长身贝类的发现及其生物古地理意义

在广西北部兴安县高尚镇金子山剖面下石炭统鹿寨组底部，新发现了长身贝类腕足化石，包括1新种、1个相似种、6个未定种和2个属种未定类型。这些长身贝类以Productellidae和Productidae科的分子为主，另有少量Echinoconchidae和Monticuliferidae科的分子。这些长身贝类全部属于生活在静水环境中的薄壳类型，无一与华南同期地层中已知类型相同。它们之间的差异可能反映了不同沉积环境条件对腕足动物群属种的控制。在鹿寨组底部发现的长身贝类以及近年在桂林南边村和黔南睦化剖面腕足动物群的发现显示出华南台缘斜坡―盆地相区杜内阶中的腕足动物群具有极高的属种分异度，不但有大量见于世界其他地方同期动物群中的分子，也包含有不少原本认为只在维宪阶或更高层位出现的类型或全新的类型，说明华南台缘斜坡―盆地相区不但与世界其他地区的腕足动物群之间存在密切的生物地理区系联系，而且华南台缘斜坡―盆地相区是杜内期腕足动物起源和辐射演化的重要策源地之一。许多属种可能是在这里起源，并迁移扩散到其他地方。     

REE/trace element characteristics of sandstone-type uranium deposits in the Ordos Basin

1 Introduction The Ordos Basin is the second largest sedimentary basin in China. During the last 10 years, a great progress has been achieved in the aspects of tectonic evolution, dynamics process, inner and outer geological processes during Mesozoic-Cen…     

西南资源环境信息共享与服务平台原型设计

地理信息共享与GIS互操作是社会化GIS时代地理信息技术发展的必然趋势。本文在简述地理信息共享及GIS互操作理论的基础上，分析了基于Web服务的信息生命周期和OGC提出的OpenGIS服务架构，最后提出了西南资源环境信息共享与服务平台的初步架构。     

西部煤炭资源调查评价中遥感技术的应用

通过西部煤炭资源勘查对遥感技术的需求以及煤田地质体的可解译性、遥感技术的实际应用效果分析,论述了西部煤炭资源调查评价中遥感技术的重要作用,提出了今后遥感技术的应用建议.     

鲍店煤矿突水条件分析

对影响鲍店3煤安金井采的3煤顶、底部砂岩和红层的水文地质条件进行了分析,对其突水特征作了简明讨论,应用突水判别模式对本矿十采区作了安全开采评价,划分了可能突水的工作面,对今后的安全开采有一定的指导意义.     

淮河流域土壤湿度异常的时空分布特征及其与气候异常关系的初步研究

利用中国东部1990~2000年旬平均土壤湿度、降水和气温观测资料，通过对0~50 cm层次土壤湿度进行旋转主分量分析 (REOF)，重点分析了淮河流域土壤湿度的时空分布特征, 并初步研究了土壤湿度与前期、同期和后期不同时段降水与气温的关系。发现春季以30 cm为界，30 cm以上各层土壤湿度异常的第一旋转空间模态十分相似, 其大值中心主要位于淮河流域，而30 cm以下 (30~50 cm) 各层的第二旋转空间模态与之亦十分类似, 因此称该模态为“淮河型”，而夏季和秋季虽然该模态也很显著, 但特征不如春季突出。该模态在各层次土壤中具有明显的持续性特征，均存在40旬左右的显著周期；并与前期和同期降水（气温）呈显著正 (负) 相关关系，与约半年后的降水 (气温) 呈负 (正) 相关关系。