中国近海天然气水合物找矿前景

天然气水合物是一种新型能源，在海底沉积物和陆上永远冻土带中均有广泛分布。西太平洋是全球三大天然气水合物成矿带之一，在其中已发现许多水合物矿床或矿点。中国近海，包括南海、东海和台湾东部海域，具备良好的天然气水合物成矿条件和找矿前景，并已在这些海域中发现了一系列的找矿标志。南海的西沙海槽、台湾西南陆坡和台西南盆地、笔架南盆地及其东缘增生楔、东沙群岛东南坡、南部陆坡区，东海的冲绳海槽和台湾东北部海域是中国近海最有利的天然气水合物找矿远景区。     

阿尔泰造山带南缘昆格依特岩体LA-ICP-MS锆石U-Pb年代学、岩石成因及其地质意义

昆格依特岩体出露于阿尔泰造山带南缘青河县大青格里河昆格依特一带,主要为角闪黑云英云闪长岩。LA-ICP-MS锆石U-Pb定年结果显示,锆石的²⁰⁶Pb/²³⁸U年龄加权平均值为(403.4±7.4)Ma,表明该岩体形成于早泥盆世。岩体的SiO₂含量介于52.39%~71.89%之间,里特曼指数为0.68~1.53,A/CNK 值为0.76~1.06,属中钾、钙碱性、准铝质-弱过铝质岩石。具有富集Cs、Rb、Th、U等大离子亲石元素和轻稀土元素,相对亏损Nb、Ta、Hf、Ti等高场强元素和重稀土元素,弱的负Eu异常(δEu=0.56~0.86)的岛弧岩浆岩特征。结合区域地质资料,认为阿尔泰造山带南缘早泥盆世昆格依特岩体形成于活动大陆边缘的陆缘弧构造环境,是古亚洲洋俯冲过程中幔源的基性岩浆底侵下地壳使之熔融,并发生了岩浆混合和分异作用的产物。     

Fe3+纳米胶体颗粒的光吸收边蓝移与溶液中Al/Fe比的关系

合成了n（Al）／n（Fe）和碱化度不同的45个聚合氯化铝铁（PAFC）样品,进行了光谱分析,结果显示光吸收边蓝移或红移以及Fe（Ⅲ）羟基氧化物和Al-Fe共聚体纳米胶体颗粒大小分布与溶液的Al／Fe比和碱化度（B=[OH]／[Al＋Fe]）密切相关。电镜观察和电子衍射分析表明：Al（Ⅲ）的加入使Fe（Ⅲ）羟基氧化物和Al-Fe共聚体纳米胶体颗粒变小、有序度降低是造成PAFE光吸收边蓝移和保持胶体颗粒在亚稳定状态下存在的重要原因。当n（Al）／n（Fe）〉8：2后,PAFC溶液中Fe（Ⅲ）羟基氧化物和Al-Fe共聚体胶体主要以〈10m的纳米颗粒形态存在,对应的光谱能级提高到26000cm^-1以上,且各种曰值下Fe^3＋的光谱能级趋于一致。这表明,在大量Al（Ⅲ）存在条件下,PAFE中Fe3^＋的所处的化学环境相似。点能谱分析显示,n（Al）／n（Fe）=4：6的样品中颗粒物的化学计量比最接近AlOOH,FeOOH,溶液的稳定性最差。     

Downstream patterns of bed sediment-borne metals,minerals and organic matter in a stream system receiving acidic mine effluent: A preliminary study

Different downstream variation patterns were observed for a range of bed sediment-borne metals (aqua regia-extractable fraction) in a subtropical stream system receiving acid mine drainage. Mine-originated Fe tended to be deposited in the acidic (mean pH < 4.9) upstream reach in forms of goethite and/or hematite. In contrast, other metals tended to be transported farther downstream and settled in a low-gradient reach with high pH (mean pH > 5.6). The peak of sediment-borne Al, Be, Ca, Cd, Co, Cu, La, Mn, Ni and Zn corresponded very well with the peak of the sediment-borne organic matter, suggesting a close association between the water-borne organic colloids and the inorganic metal oxides/hydroxides during their transport. The marked increase in the sediment-borne Al and Pb started more upstream than the other metals, suggesting that the water-borne Al and Pb were more susceptible to pH rise-induced precipitation, as compared to the other metals. It appeared that the organic colloids played no important role in Pb transport and settlement. The iron precipitates had a limited role to play in affecting the transport and fates of other metals since they were predominantly formed and deposited in the acidic reach, which made them incapable of scavenging cationic metals by co-precipitation or adsorption.     

Ecological effects analysis of land use change in coal mining area based on ecosystem service valuing: a case study in Jiawang

Land use change is one of the uppermost driving forces of regional ecosystem change, and has a huge impact on the environmental balance. Mining areas with intensive resources exploitation and utilization have undergone different kinds of environmental influences, such as water pollution and land use cover change. The extensive coal mining in China has led to significant regional land use change resulting in major ecological damage. The objective of this study was to form a clearer picture of the regional ecological environmental situation for promoting ecological protection and improvement by ecosystem service valuing. The case study area was selected at Jiawang town, which has undergone extensive coal mine exploitation for many decades. The study investigated the relationship between land use change and ecological environment, and described the ecosystem service value variations in Jiawang, based on remote sensing and GIS technology. After modification of regional ecosystem service value coefficients, the method was used to evaluate the conditions in the study area from 1990 to 2005 based on the land use/cover information interpreted from TM/ETM+ images. The characters and changes of ecosystem service values were then analyzed both quantitatively and spatially.     

岩浆-流体过渡和阿尔泰三号伟晶岩脉之成因

本文对新疆阿尔泰可可托海的三号伟晶岩形成的物理化学条件、特别是流体-熔融包裹体进行了研究，证明岩浆的确可以分出热液，对于三号伟晶岩脉来说，这种热液组分主要是NaCl－CO2－H2O流体。     

Magma type and genesis of the basic-ultrabasic layered intrusions in Panzhihua-Xichang area,Southwest China

The layered intrusions in the Panzhihua-Xichang area may be grouped into two types: basic rock masses represented by the Panzhihua rockbody and basic-ultrabasic rock masses represented by the Hongge rockbody. Their major difference lies in that the former has poorly developed ultramafic facies, while the latter is characterized by well developed mafic facies and ultramafic facies. There exists apparent rhythmic stratification in the rock masses, which can be basically divided into four grades in terms of superimposition relationship and multicycle characters. Both direct and indirect evidence suggest that the magma responsible for the layered intrusions in this area should be a transition-type alkaline olivine basalt magma derived directly from partial melting of the upper mantle. In rhythmic cycles of various grades, the magmatic evolution is characterized obviously by periodicity and early enrichment of Fe and Ti, which is evidently different from the evolution of the Skaergaard magma in which Fe and Ti are enriched at the late stage. The FCA diagram can be used to describe the unique evolutionary trend of magma in this area. It is demonstrated in this diagram that the enrichment of Fe and Ti is consistent with the increase of basicity. In the upper magmatic chamber, the evolutionary trend of magma is conditioned by the difference in pressure, and this enables magma to form different types of rock assemblage. In the Fo-Di-An system, when the pressure exceeds 5 x 18⁸ Pa, forsterite is incompatible with anorthite, and the rock facies sequence of Hongge type might form; when the pressure is lower than 5 x 10⁸ Pa, forsterite can coexist with anorthite, and the rock facies sequence of Panzhihua type is likely to form if the magma is relatively rich in Mg and Fe components.     

Iron isotopic analyses of geological reference materials on MC-ICP-MS with instrumental mass bias corrected by three independent methods

Here we report iron (Fe) isotopic data of three pure Fe solution standards (IRMM-014, GSB Fe, and NIST 3126a) and five widely used geological reference materials (RMs) from the United States Geological Survey and Geological Survey of Japan obtained on a Neptune Plus multi-collector–inductively coupled plasma–mass spectrometer (MC-ICP-MS) in our laboratory over the past 3 years. The instrumental mass bias was corrected by three independent methods: sample-standard bracketing (SSB), Ni doping?+?SSB, and ⁵⁷Fe–⁵⁸Fe double spike?+?SSB. Measurements reveal that both the Ni doping and double spike methods helped calibrate short-term fluctuations in mass bias. Collectively, almost all measurements of RMs yielded δ⁵⁶Fe within?±?0.05 of recommended values, provided that each sample was measured four times on MC-ICP-MS. For the first time, new recommended values for NIST SRM3126a are reported (δ⁵⁶Fe?=?0.363?±?0.006, 2SE, 95% CI; and δ⁵⁷Fe?=?0.534?±?0.010, 2SE).     

Dehydration—Melting Experiments on the Khondalite Series,North Segment of Helan Mountain—I.Determination of Critical Melt Fraction

Dehydration-melting experiments were conducted on granulite and Al-gneiss,the two most representative rock-types of the khondalite series in the northern segment of the Helan Mountain.The critical melting fraction was determined to be 30% in volume,which is of great significance with respect to the P-T-t path of metamorphism and granite generation in the region.