Particulate aluminium in boreal streams: Towards a better understanding of its sources and influence on dissolved aluminium speciation

The adverse impacts of the inorganic labile monomeric Al (Al_i) fraction on aquatic organisms have meant that Al (Al_tot) determination and even speciation has become a routine part of environmental monitoring and assessment. However, if samples are not filtered prior to analysis then particulate Al (Al_tot(p)) could influence the determination of Al_tot, and therefore the determination of the more toxicologically important (Al_i), both when it is measured analytically or modelled from Al_tot. This paper shows that the Al/DOC ratio in unfiltered samples can identify the Al_tot(p) fraction, and thus improve the speciation of Al_i. These findings are based on data from a study in a 67 km² catchment in northern Sweden during the snowmelt-driven spring flood of two consecutive years. Filtered and unfiltered samples were studied to determine the spatial and temporal patterns in Al_tot(p). The concentrations of Al_tot(p) were greatest in larger downstream sites where significant silt deposits are located. The sites with no silt in their drainage area showed a mean difference between filtered (Al_tot(f)) and unfiltered (Al_tot(uf)) samples of 6%, while sites with silt deposits had a mean difference of 65%. The difference between filtered and unfiltered samples was greatest at peak flow. Spikes in Al_tot(p) did not behave consistently during fractionation with a cation exchange column, resulting in increases in either measured Al_i(f) or non-labile monomeric Al (Al_o(f)). Al_tot(p) spikes were associated with sharp increases in the Al:DOC ratio. The baseflow Al:DOC ratio could be used to model filtered Al_tot from DOC with a Spearman rho of 0.75.     

Ground-penetrating radar investigation of active faults along the Dead Sea Transform and implications for seismic hazards within the city of Aqaba, Jordan

Ground-penetrating radar (GPR) was used in an effort to locate a major active fault that traverses Aqaba City, Jordan. Measurements over an exposed (trenched) cross fault outside of the city identify a radar signature consisting of linear events and horizontal offset/flexured reflectors both showing a geometric correlation with two known faults at a control site. The asymmetric linear events are consistent with dipping planar reflectors matching the known direction of dip of the faults. However, other observations regarding this radar signature render the mechanism generating these events more complex and uncertain.GPR measurements in Aqaba City were limited to vacant lots. Seven GPR profiles were conducted approximately perpendicular to the assumed strike of the fault zone, based on regional geological evidence. A radar response very similar to that obtained over the cross fault was observed on five of the profiles in Aqaba City, although the response is weaker than that obtained at the control site. The positions of the identified responses form a near straight line with a strike of 45°. Although subsurface verification of the fault by trenching within the city is needed, the geophysical evidence for fault zone location is strong. The location of the interpreted fault zone relative to emergency services, military bases, commercial properties, and residential areas is defined to within a few meters. This study has significant implications for seismic hazard analysis in this tectonically active and heavily populated region.     

Thermal instability of the fluid column in a borehole: application to the Yaxcopoil hole (Mexico)

Observational evidence proved that even when a borehole is in “fully” stabilized conditions, temperature data may exhibit certain unrest resembling irregular oscillations in the order of hundredths or (in the extreme case) even tenths of degree. Temperature was monitored in complicated hydrogeological conditions in the Yaxcopoil-1 hole (Chicxulub impact structure, Mexico). Two experiments are reported: (a) 20-day monitoring when a logger was located in the center of the high temperature gradient anomaly produced by the cold wave slowly propagating downwards and (b) simultaneous three-loggers 18-day monitoring with loggers located above, in and below the anomaly. All observed temperature–time series displayed intermittent oscillations of temperature with sharp gradients and large fluctuations over all observed time scales. While the “upper” and “lower” records revealed quasi-periodic temperature variations, the “central” record shows fast temperature oscillations with strong up-and-down reversals, all with amplitudes up to a few tenths of degree. The observed temperature–time series were processed by recurrence and recurrence interval quantification as well as by spectral analyses. It is shown that fluid in a borehole, subject to thermal gradient, is stable, as far as the gradient remains below a certain critical value. At higher Rayleigh numbers, the periodic character of oscillations typical for “quiescent” regime is superseded by stochastic features. This “oscillatory” convection occurs due to instability of the horizontal boundary layers. In the specific case of the Yaxcopoil hole, the time series above and below the cold wave (characterized by relatively lower temperature gradients between 20 and 50 mK/m) contain a clear low frequency component produced by tidal forcing. This component dominates over the high frequency domain (periods from 10–15 to 1 min), which exhibit a scaling behavior. This pattern conspicuously changes in the center part of the cold wave, where the local temperature gradient exceeds 200 mK/m and where tidal forcing composes only ~3% of the signal.     

Impurities and nonstoichiometry in the bulk and on the (101?4) surface of dolomite

Atomistic computer simulation methods have been used to model the nature of nonstoichiometry and impurity defects in the bulk and at the (101?4) surface of dolomite (MgCa(CO₃)₂). Calcium and Mg in the bulk and at the surface have been replaced with divalent Ni, Co, Zn, Fe, Mn, and Cd. The results of these calculations indicate that in the bulk, these impurities will prefer to substitute at the Ca site rather than the Mg site. Ca excess in dolomite is most likely incorporated as basal stacking faults; this nonstoichiometry can influence the site distribution of impurities. The calculated surface segregation energies suggest that of all the impurities studied, only Cd will show a strong preference for the (101?4) surface of dolomite.     

Precise temperature monitoring in boreholes: evidence for oscillatory convection? Part II: theory and interpretation

In the previous part of this work (Cermak, Safanda and Bodri, this volume p.MMM) we have described experimental data and quantified the heterogeneity features of the microtemperature time series. The spectral analysis and the local growth of the second moment technique revealed scaling structure of all observed time series generally similar and suggested the presence of two temperature forming processes. The longer-scale part can be attributed to the heat conduction in compositional and structural heterogeneous solid rocks, further affected by various local conditions. Short-scale temperature oscillations are produced by the intra-hole fluid convection due to inherent instability of water column filling the hole. Here we present how the observational evidence is supported by the results of the computer simulations. The exact modes of intra-hole convection may be different, ranging from quasi-periodic (“quiescent”) state to close of turbulence. As demonstrated by numerical modeling and referred on laboratory experiments, at higher Rayleigh numbers the periodic character of oscillation characteristic for “quiescent” regime is superseded by stochastic features. This so called “oscillatory” convection occurs due to instability within the horizontal boundary layers between the individual convectional cells. In spite of the fact that the basic convective cell motion is maintained and convection is characterized by slow motion, the oscillatory intra-hole flow and corresponding temperature patterns exhibit typical features of turbulence. The idea of boundary layer instability as a source of stochastic temperature fluctuations could explain many distinct features of borehole temperatures that previously cannot be interpreted.     

Timing and pace of ice-sheet withdrawal across the marine–terrestrial transition west of Ireland during the last glaciation

Understanding the pace and drivers of marine-based ice-sheet retreat relies upon the integration of numerical ice-sheet models with observations from contemporary polar ice sheets and well-constrained palaeo-glaciological reconstructions. This paper provides a reconstruction of the retreat of the last British–Irish Ice Sheet (BIIS) from the Atlantic shelf west of Ireland during and following the Last Glacial Maximum (LGM). It uses marine-geophysical data and sediment cores dated by radiocarbon, combined with terrestrial cosmogenic nuclide and optically stimulated luminescence dating of onshore ice-marginal landforms, to reconstruct the timing and rate of ice-sheet retreat from the continental shelf and across the adjoining coastline of Ireland, thus including the switch from a marine- to a terrestrially-based ice-sheet margin. Seafloor bathymetric data in the form of moraines and grounding-zone wedges on the continental shelf record an extensive ice sheet west of Ireland during the LGM which advanced to the outer shelf. This interpretation is supported by the presence of dated subglacial tills and overridden glacimarine sediments from across the Porcupine Bank, a westwards extension of the Irish continental shelf. The ice sheet was grounded on the outer shelf at ~26.8 ka cal bp with initial retreat underway by 25.9 ka cal bp. Retreat was not a continuous process but was punctuated by marginal oscillations until ~24.3 ka cal bp. The ice sheet thereafter retreated to the mid-shelf where it formed a large grounding-zone complex at ~23.7 ka cal bp. This retreat occurred in a glacimarine environment. The Aran Islands on the inner continental shelf were ice-free by ~19.5 ka bp and the ice sheet had become largely terrestrially based by 17.3 ka bp. This suggests that the Aran Islands acted to stabilize and slow overall ice-sheet retreat once the BIIS margin had reached the inner shelf. Our results constrain the timing of initial retreat of the BIIS from the outer shelf west of Ireland to the period of minimum global eustatic sea level. Initial retreat was driven, at least in part, by glacio-isostatically induced, high relative sea level. Net rates of ice-sheet retreat across the shelf were slow (62–19 m a⁻¹) and reduced (8 m a⁻¹) as the ice sheet vacated the inner shelf and moved onshore. A picture therefore emerges of an extensive BIIS on the Atlantic shelf west of Ireland, in which early, oscillatory retreat was followed by slow episodic retreat which decelerated further as the ice margin became terrestrially based. More broadly, this demonstrates the importance of localized controls, in particular bed topography, on modulating the retreat of marine-based sectors of ice sheets.     

A framework to assess the vulnerability of California commercial sea urchin fishermen to the impact of MPAs under climate change

This paper describes the development of a Livelihood Vulnerability Index (LVI) that estimates the relative ability of California commercial sea urchin fishermen to cope with the change associated with proposed marine protected areas. A key goal in establishing marine protected areas is to maximize conservation benefits while minimizing the potential negative impacts to local fishing communities. However, current impact analyses largely assume a linear relationship between percent of fishing area or revenue lost with the magnitude of impact to fishermen. The LVI described in this paper aims to provide an additional dimension to impact analyses in which the adaptive capacity of individual fishermen is examined to estimate the differential abilities of fishermen to cope with the loss of fishing areas or revenue. This paper advances vulnerability assessments as it develops a novel framework for identifying and measuring drivers of vulnerability for understudied fishing populations whose livelihoods depend upon marine resources. This vulnerability assessment is intended to inform the design of marine protected areas by enabling researchers to incorporate the adaptive capacity of fishermen into socioeconomic impact analyses. The LVI was developed for the California commercial sea urchin fishery in the context of proposed marine protected area networks develop through the California Marine Life Protected Act planning process. As climate change advances there is an increasing need to identify vulnerable and resilient populations and ways to bolster adaptive capacity given the environmental and economic changes ahead.     

Socio-cultural dimensions of climate change: charting the terrain

We have reached a crucial turning point in debates around climate change. A well established scientific consensus regarding the physical causes, dynamics, and at least many likely implications of anthropogenic climate change has thus far failed to result in any substantial movement towards mitigation. For many, then, the most urgent questions regarding climate change are now socio-cultural ones, such as: how do people come to hold and act on certain beliefs regarding environmental conditions and processes; how do institutional forms and histories shape and constrain the views and options of various sorts of actors; and what are relationships among fossil fuels, climate change, and the historical geographies and future trajectories of capitalism? Far from being simpler than physical and life science questions, these social science questions introduce entirely new sorts of actors, dynamics, and methodological challenges into this already complex and dynamic domain. This special issue takes up these topics. In this essay, we chart some of the major contours of contemporary social science thinking regarding climate change and introduce the articles in the special issue. We begin by examining work, from political science and scholarship on the commons, that foregrounds questions of sovereignty, territoriality, and cooperation with respect to environmental governance. Then we examine work from neoclassical economics and radical political economy, which frame climate change in terms of externalities, or contradiction and crisis, respectively. Finally, we examine the rapidly proliferating work exploring how individuals think and feel about these issues, emphasizing concepts of risk, communication, and governmentality.     

Surface complexation model for strontium sorption to amorphous silica and goethite

Strontium sorption to amorphous silica and goethite was measured as a function of pH and dissolved strontium and carbonate concentrations at 25°C. Strontium sorption gradually increases from 0 to 100% from pH 6 to 10 for both phases and requires multiple outer-sphere surface complexes to fit the data. All data are modeled using the triple layer model and the site-occupancy standard state; unless stated otherwise all strontium complexes are mononuclear. Strontium sorption to amorphous silica in the presence and absence of dissolved carbonate can be fit with tetradentate Sr²⁺ and SrOH⁺ complexes on the β-plane and a monodentate Sr²⁺complex on the diffuse plane to account for strontium sorption at low ionic strength. Strontium sorption to goethite in the absence of dissolved carbonate can be fit with monodentate and tetradentate SrOH⁺ complexes and a tetradentate binuclear Sr²⁺ species on the β-plane. The binuclear complex is needed to account for enhanced sorption at hgh strontium surface loadings. In the presence of dissolved carbonate additional monodentate Sr²⁺ and SrOH⁺ carbonate surface complexes on the β-plane are needed to fit strontium sorption to goethite. Modeling strontium sorption as outer-sphere complexes is consistent with quantitative analysis of extended X-ray absorption fine structure (EXAFS) on selected sorption samples that show a single first shell of oxygen atoms around strontium indicating hydrated surface complexes at the amorphous silica and goethite surfaces.