Niveo-aeolian sand deposition in subarctic dunes,eastern coast of Hudson Bay,Québec,Canada

Aeolian sand transport during winter and the snow-free season was assessed quantitatively by direct year-round field measurements along transects on the lee side of parabolic dunes in subarctic Québec. In 1987–1988, niveo-aeolian deposition was more important than aeolian sedimentation in three of the four study sites, and contributed > 75% of the total annual accumulation in exposed sites and < 25% in protected forest sites. The maximum depth of interstratified snow and sand deposits (3.5 m) was recorded in March. Semi-permanent snow lenses may persist longer than 2 years in the aeolian sediments. After dissipation of snow, 22 cm of sand (as a maximum) accumulated on the slipface of the most active dunes, whereas only minor sand accumulation occurred in distant areas from active sand erosion. Wind-driven sand was dispersed over 7.4 km² in the Whapmagoostui-Kuujjuarapik area. The acumulation of snow and sand during the snow season, together with spring thaw and collapse of the niveo-aeolian deposit, caused different types of injuries to trees, especially in 1985 and 1987 when a maximum of torn branches was recorded over the last 10 year period.     

Serving God and science

Agustín Udías reflects on the Jesuit scientific tradition in astronomy and geophysics, by considering those who were also Fellows of the RAS.
The Society of Jesus has a venerable tradition of scientific observation and enquiry, as has the Royal Astronomical Society. Their paths have frequently crossed over the years and this tradition of shared enquiry continues to this day.     

Timing and thermochemical constraints on multi-element mineralisation at the Nori/RA Cu–Mo–U prospect, Great Bear magmatic zone, Northwest Territories, Canada

The timing of Cu–Mo–U mineralisation at the Nori/RA prospect in the Paleoproterozoic Great Bear magmatic zone has been investigated using Re–Os molybdenite and ⁴⁰Ar–³⁹Ar biotite geochronology. The Re–Os molybdenite ages presented are the first robust sulphide mineralisation ages derived from the Great Bear magmatic zone. Cu–Mo–U mineralisation is hosted in early to syn-deformational hydrothermal veins consisting of quartz and K-feldspar or more commonly tourmaline-biotite-quartz-K-feldspar, with associated wall-rock alteration assemblages being predominantly biotite. Sulphide and oxide minerals consist of chalcopyrite, molybdenite and uraninite with lesser pyrite and magnetite. Elevated light rare earth elements and tungsten concentrations associated with the Cu–Mo–U mineralisation have also been reported at the prospect by previous workers. Molybdenite and uraninite occur intimately in dravitic tourmaline growth zones and at grain margins, attesting to their syngenetic nature (with respect to hydrothermal veining). Two molybdenite separates yield Re–Os model ages of 1,874.4 ± 8.7 (2σ) and 1,872.4 ± 8.8 Ma (2σ) with a weighted average model age of 1,873.4 ± 6.1 Ma (2σ). Laser step heating of biotite from the marginal alteration of the wall-rock adjacent to the veins yields a ⁴⁰Ar–³⁹Ar maximum cooling age of 1,875 ± 8 Ma (MSWD = 3.8; 2σ), indistinguishable from the Re–Os molybdenite model age and a previously dated ‘syn-tectonic’ aplitic dyke in the region. Dravitic tourmaline hosts abundant primary liquid–vapour–solid-bearing fluid inclusions. Analytical results indicate liquid–vapour homogenisation at >260°C constraining the minimum temperature of mineralisation. The solids, which are possibly trapped, did not homogenise with the liquid–vapour by 400°C. Salinities in the inclusions are variable. Raman spectra identify that at least some of the solids are calcite and anhydrite. Raman spectra also confirm the vapour phases contain some CO₂; whereas clathrates or CH₄ was not observed or detected. Quartz grains only host secondary fluid inclusions, which fluoresce under ultraviolet light, indicating trapped hydrocarbons. We speculate that these resulted from Phanerozoic fluid circulation through the Proterozoic basement. The collective interpretation of the age, hydrothermal character and associated metals, high temperature and variable salinity suggests that the Nori/RA Cu–Mo–U mineralisation can be linked with the earliest stages of plutonism in the Great Bear magmatic zone. From a regional perspective, the mineralisation may pre-date the extensive multi-element mineralisation now recognised as part of the iron oxide copper–gold (IOCG) spectrum of deposits. As IOCG provinces generally contain a variety of mineralisation styles, we interpret this as the earliest phase of the extensive mineralising system.     

Assessing impacts of agricultural water interventions in the Kothapally watershed,Southern India

The paper describes a hydrological model for agricultural water intervention in a community watershed at Kothapally in India, developed through integrated management and a consortium approach. The impacts of various soil and water management interventions in the watershed are compared to no‐intervention during a 30‐year simulation period by application of the calibrated and validated ARCSWAT 2005 (Version 2.1.4a) modelling tool. Kothapally receives, on average, 800 mm rainfall in the monsoon period. 72% of total rainfall is converted as evaporation and transpiration (ET), 20% is stored by groundwater aquifer, and 8% exported as outflow from the watershed boundary in current water interventions. ET, groundwater recharge and outflow under no‐intervention conditions are found to be 64, 9, and 19%, respectively. Check dams helped in storing water for groundwater recharge, which can be used for irrigation, as well minimising soil loss. In situ water management practices improved the infiltration capacity and water holding capacity of the soil, which resulted in increased water availability by 10–30% and better crop yields compared to no‐intervention. Water outflows from the developed watershed were more than halved compared to no‐intervention, indicating potentially large negative downstream impacts if these systems were to be implemented on a larger scale. On the other hand, in the watershed development program, sediment loads to the streams were less than one‐tenth. It can be concluded that the hydrological impacts of large‐scale implementation of agricultural water interventions are significant. They result in improved rain‐fed agriculture and improved productivity and livelihood of farmers in upland areas while also addressing the issues of poverty, equity, and gender in watersheds. There is a need for case‐specific studies of such hydrological impacts along with other impacts in terms of equity, gender, sustainability, and development at the mesoscale. Copyright © 2011 John Wiley & Sons, Ltd.     

Catalyzing mitigation ambition under the Paris Agreement: elements for an effective Global Stocktake

The Global Stocktake (GST) takes a central role within the architecture of the Paris Agreement, with many hoping that it will become a catalyst for increased mitigation ambition. This paper outlines four governance functions for an ideal GST: pacemaker, ensurer of accountability, driver of ambition and provider of guidance and signal. The GST can set the pace of progress by stimulating and synchronizing policy processes across governance levels. It can ensure accountability of Parties through transparency and public information sharing. Ambition can be enhanced through benchmarks for action and transformative learning. By reiterating and refining the long term visions, it can echo and amplify the guidance and signal provided by the Paris Agreement. The paper further outlines preconditions for the effective performance of these functions. Process-related conditions include: a public appraisal of inputs; a facilitative format that can develop specific recommendations; high-level endorsement to amplify the message and effectively inform national climate policy agendas; and an appropriate schedule, especially with respect to the transparency framework. Underlying information provided by Parties complemented with other (scientific) sources needs to enable benchmark setting for collective climate action, to allow for transparent assessments of the state of emissions and progress of a low-carbon transformation. The information also needs to be politically relevant and concrete enough to trigger enhancement of ambition. We conclude that meeting these conditions would enable an ideal GST and maximize its catalytic effect.

Key policy insights

• The functional argument developed in this article may inspire a purposeful design of the GST as its modalities and procedures are currently being negotiated.

• The analytical framework provided serves as a benchmark against which to assess the GST's modalities and procedures.

• Gaps and blind spots in the official GST can and should be addressed by processes external to the climate regime in academia and civil society.

     

Large,prehistoric clay slides revealed in road excavations in Buvika,mid-Norway

Several excavated sections along new roads in Buvika, mid-Norway, display records of large, prehistoric clay slides. Slightly undulating but otherwise intact laminated clay, with minor amounts of unsorted or sorted coarser-grained debris, appears in the sections. Folding, shearing and internal slide surfaces have also been recorded, and the deposits are interpreted as slide debris. Slide-scar morphologies are diffuse or absent for most of these deposits, and the inferred slide mechanism is translation and rotation of blocks on a thin layer of remoulded quick clay. One section cuts through a slide block inside a classic, morphologically well-defined quick-clay slide scar. Varying results from ¹⁴C-datings of organic material in the deposits give only maximum ages of the slide events. The style of sliding reflected in several sections differs from slide events in the area known from historical records. These younger slide events seem to be characterised by collapse and remoulding of thicker quick-clay layers. The present study of slide deposits gives information on processes and deformation history of the slides. It is suggested that the gradual formation of quick clay has an important impact on long-term landscape degradation and on the character of the present day landscape. There may be far more signs of slide activity in Norwegian valleys than solely indicated by slide scars and also in the relatively high-lying parts of the valley fill, such as interfluve areas.     

The Effect of Bottle Fill Rate and Pour Technique on the Recovery of Volatile Organics

This field study was conducted to examine whether the method or the flow rate (fill rate) used to fill a sample vial affects recovery of volatile organics (VOCs). To our knowledge, there have not been any systematic studies that have examined this issue. For this field study, three fill rates (50 mL/min, 250 mL/min, and ~1 L/min) and three filling methods (top‐pour, side‐pour, and bottom‐fill) were used to fill sample vials. We found that the bottom‐fill method, with the tubing submerged in the sample as it fills, yielded the greatest recovery (i.e., highest concentrations) of VOCs. Little improvement was observed by pouring down the side of a vial vs. simply pouring straight down from the top. We also found that filling the vials at the fastest fill rate (~1 L/min) yielded higher recovery than the slowest fill rate (50 mL/min) using all three filling methods. These results are counter to prevailing guidance and conventional wisdom that slower filling is preferable to faster filling and that pouring down the side of a sample vial is the best practice for VOC sampling. However, because we were unable to randomize the order the samples were collected with respect to fill rate, we recommend a follow‐on study be conducted that will allow us to confirm our findings and better determine which fill rates minimize losses of VOCs     

Extensive methane-derived authigenic carbonates in the Irish Sea

Extensive areas of methane-derived authigenic carbonate (MDAC) have been mapped in the Irish Sea. In the Irish Sector, 23 seabed mounds associated with the Codling Fault Zone were identified by multi-beam echo sounder mapping. Inspection by ROV-mounted video showed that these mounds are rocky features rising 5–10 m above the normal seabed; sampling showed that they are comprised of quartz grains bound together by carbonate cement, probably MDAC. Two separate locations have been mapped in the UK Sector. At Texel 11, seabed mounds and a 6–8 m high cliff were mapped geophysically (MBES, SSS and seismic profiler surveys). Video surveys showed that both the mounds and the cliff are rocky reefs colonised by a prolific fauna. Samples proved to be carbonate-cemented sediments, and carbon isotope analysis (δ¹³C −41 to −46% PDB) showed that the cement was MDAC. Similar surveys of the Holden’s Reefs area proved the presence of similar rocky reefs which are also cemented by MDAC. The total area covered by these two MDAC occurrences is estimated to be >500,000 m². These MDAC occurrences are comparable in nature and formation to the ‘bubbling reefs’ of the Kattegat. As the bubbling reefs are “seabed features formed by leaking gas”, one of the marine habitats identified by the European Commission’s Habitats Directive as being sensitive and worthy of protection, it is suggested that the Irish Sea carbonate reefs should also be considered as special habitats.     

Identification and characterization of secondary minerals formed in tungsten mine tailings using transmission electron microscopy

Secondary minerals formed in tailings derived from a W-rich deposit were investigated in detail using transmission electron microscopy (TEM). The study focused on secondary minerals that formed in the vicinity of oxidized sphalerite [ZnS] and tennantite [Cu₁₀(Fe,Zn)₂As₄S₁₃] grains. Samples for TEM analysis were prepared directly from petrographic thin sections using a focused ion beam instrument. This method insured that spatial relationships among primary grains, secondary minerals and the pore spaces were maintained. The results from this study indicate that the secondary coatings associated with sphalerite and tennantite are composed of several discrete phases. The phases identified in this study include an Fe–Zn–As–O phase, secondary sulfides, native Cu, an Fe–Si–O phase, an In–O phase, and wulfenite [PbMoO₄]. The Fe–Zn–As–O phase precipitates directly from the pore water and the nearby primary mineral grains act as a source for some of the elements (e.g., Zn from sphalerite, As from tennantite). Secondary Cu sulfides were found at the outer margins of sphalerite and roquesite [CuInS₂] grains. It is likely that these Cu sulfides form as a result of interactions between the primary grain and aqueous Cu(II) present in the pore water, similar to what occurs in supergene environments. A secondary sulfide that was composed of variable amounts of Cu, Zn, As, Fe and S was also identified along the outer margins of tennantite. Native Cu was found in association with chalcopyrite [CuFeS₂] inclusions that were present in one of the sphalerite grains and probably represents a low-temperature secondary phase. The oxidation of chalcopyrite in the presence of aqueous Si leads to the formation of a nanocrystalline or amorphous Fe–Si–O phase. Roquesite oxidation leads to the formation of a crystalline In–O phase, which is likely dzhalindite [In(OH)₃]. Wulfenite was found in the interstitial voids present in the Fe–Zn–As–O phase suggesting that it forms by direct precipitation from the local pore water. The results from this study indicate that secondary coatings consist of complex secondary phases that may only be distinguished at the nanoscale. The TEM investigations reveal details regarding mineralogical sinks and sources for aqueous components that may otherwise be overlooked.