Effect of Concentration on Sorption of Dissolved Organics by PVC, PTFE, and Stainless Steel Well Casings

This report examines sorption of low ppb levels of organic solutions by polytetra- fluoroethylene (PTFE), rigid polyvinyl chloride (PVC), and stainless steel 304 and 316 well casings. Nineteen organics were selected, including several munitions and chlorinated solvents. Compounds were selected to offer a range of physical properties, such as solubility in water, octanol/water partition coefficient, and molecular structure. When these results were compared with the results from a similar study conducted at ppm levels, the rate and extent of sorption by PTFE and PVC were the same as seen previously for almost all analytes. There were no losses of any compounds associated with stainless steel. At these low levels (ppm and ppb), the rate of diffusion within the polymer (PVC and PTFE) is independent of concentration. Only with PTFE are the rates rapid enough to be of concern when monitoring for some contaminants in ground water. Tetrachloroethylene was the compound PTFE sorbed the most rapidly. The study showed that PVC well casings are suitable for monitoring low levels (ppm and ppb) of organics.     

Fossil mammoths from Santa Cruz Island, California

Mammoth remains on Santa Cruz Island, one of the four Northern Channel Islands of California, are very sparse, in marked contrast to those reported from Santa Rosa and San Miguel Islands of the same island group. A probable major reason for this scarcity is that Quaternary deposits are greatly restricted on Santa Cruz Island. It is proposed, contrary to popular opinion, that fossils found on Santa Cruz Island were derived from animals which died on the island, and were not transported there by humans. Reasons for this conclusion are that the size and geological context of the fossils are similar to those of the largest mammoth fossils of Santa Rosa Island, and that, in spite of extensive investigations by many persons, mammoth remains have not been found in middens, either on the islands or on the adjacent mainland.     

Coarsening of three-dimensional structured and unstructured grids for subsurface flow

We present a generic, semi-automated algorithm for generating non-uniform coarse grids for modeling subsurface flow. The method is applicable to arbitrary grids and does not impose smoothness constraints on the coarse grid. One therefore avoids conventional smoothing procedures that are commonly used to ensure that the grids obtained with standard coarsening procedures are not too rough. The coarsening algorithm is very simple and essentially involves only two parameters that specify the level of coarsening. Consequently the algorithm allows the user to specify the simulation grid dynamically to fit available computer resources, and, e.g., use the original geomodel as input for flow simulations. This is of great importance since coarse grid-generation is normally the most time-consuming part of an upscaling phase, and therefore the main obstacle that has prevented simulation workflows with user-defined resolution. We apply the coarsening algorithm to a series of two-phase flow problems on both structured (Cartesian) and unstructured grids. The numerical results demonstrate that one consistently obtains significantly more accurate results using the proposed non-uniform coarsening strategy than with corresponding uniform coarse grids with roughly the same number of cells.     

Climate change of the last millennium inferred from borehole temperatures: regional patterns of climatic changes in the Czech Republic — Part III

Accurate temperature–depth profiles may help to assess the temperature variations associated with the climate changes in the past. Ninety-eight ground surface temperature histories inverted from the temperature–depth borehole logs drilled on the territory of the Czech Republic [Bodri, L., ermák, V., 1995. Climate changes of the last millennium inferred from borehole temperatures: results from the Czech Republic — Part I. Global Planet. Change 11, pp. 111–125; Bodri, L., ermák, V., 1997. Climate changes of the last two millennia inferred from borehole temperatures: results from the Czech Republic — Part II. Global Planet. Change 14, pp. 163–173.] are used to reconstruct the regional patterns of the respective climate change. The climate was mapped for the following periods: 1100–1300 A.D. (Little Climatic Optimum), 1400–1500 A.D., 1600–1700 A.D. (main phase of the Little Ice Age), and for the most recent climate trend after year 1960. Comparison of the obtained maps with the meteorological observations and proxy climatic reconstructions confirmed good applicability of the “geothermal” paleoclimatic reconstructions for the regional studies.     

Fractal analysis of climatic data: Mean annual temperature records in Hungary

Summary Rescaled range analysis of the annual mean surface air temperatures at 7 meteorological stations in Hungary for the period of 1901–1991 indicates that the considered temperatures are fractals with a mean fractal dimension of 1.23 ± 0.01. This value compares favourably with the fractal dimensions of other climatic records, both on small time scale of 10–100 years and for time spans 10³–10⁶ years. Possibly such fractal dimensions are characteristic of climate change over the whole spectral range of 10 to 10⁶ years. If this assumption becomes confirmed through analysis of a wider set of climatic records, long-range climatic prediction (in statistical sense) on different time scales will appear feasible.With 4 Figures     

4-tert-octylphenol and 17beta-estradiol applied by feeding to flounder Platichthys flesus: induction of vitellogenin and accumulation in tissues

In order to simulate a possible natural administration route of xenoestrogens male flounder Platichthys flesus were exposed via the diet to the alkylphenol 4-tert-octylphenol. Treatment with 4-tert-octylphenol (10, 50 and 100 mg OP kg(-1) BW) or 17beta-estradiol (0.05 mg kg(-1) BW) every second day during a period of 11 days resulted in a significant increase in plasma vitellogenin (Vtg) concentrations. The induction of Vtg was greatest in the fish receiving 50 mg OP kg-' BW. A significant accumulation of 4-tert-octylphenol was found in liver and muscle tissue of the OP treated groups. The tissue concentrations of 4-tert-octylphenol and the plasma vitellogenin concentration were positively correlated. The results show that 4-tert-octylphenol accumulates in liver and muscles of flounder P. flesus, and exerts estrogenic effects such as vitellogenin induction.