Screening of polymers on selected Hawaii soils for erosion reduction and particle settling

In recent years, high‐molecular‐weight anionic polyacrylamides (PAMs) have been tested on a variety of soils, primarily in temperate climates. However, little information is available regarding the effectiveness of PAM for preventing soil loss through runoff in tropical settings. Screening tests were performed using three negatively charged PAMs and one positively charged PAM on five Hawaii soils (two Oxisols, one Vertisol, and two Aridisols) to determine erosion loss, sediment settling, and aggregate stability. A laboratory‐scale rainfall simulator was used to apply erosive rainfall at intensities from 5 to 8·5 cm h^?1 at various PAM doses applied in both dry and solution forms. Soil detachment due to splash and runoff, as well as the runoff and percolate water volumes, were measured for initial and successive storms. The impact of PAM on particle settling and aggregate stability was also evaluated for selected soil‐treatment combinations. Among the PAMs, Superfloc A‐836 was most effective, and significantly reduced runoff and splash sediment loss for the Wahiawa Oxisol and Pakini Andisol at rates varying between 10 and 50 kg ha^?1. Reduced runoff and splash sediment loss were also noted for PAM Aerotil‐D when applied in solution form to the Wahiawa Oxisol. Significant reductions in soil loss were not noted for either the Lualualei Vertisol or the Holomua Oxisol. It is believed that the high montmorillonite content of the Lualualei Vertisol and the low cation‐exchange capacity of the Holomua Oxisol diminished the effectiveness of the various PAMs tested. The polymers were also found to enhance sediment settling of all soils and helped improve their aggregate stability. This screening study shows the potential use of PAM for tropical soils for applications such as infiltration enhancement, runoff reduction, and enhanced sedimentation of detention ponds. Copyright © 2005 John Wiley & Sons, Ltd.     

Chemical abundances determined from meteor spectra: I. Ratios of the main chemical elements

Abstract— Relative chemical abundances of 13 meteoroids were determined by averaging the composition of the radiating gas along the fireball path that originated during their penetration into the Earth's atmosphere. Mg, Fe, Ni, Cr, Mn, and Co abundances, relative to Si, are similar to those reported for CI and CM carbonaceous chondrites and interplanetary dust particles. In contrast, relative abundances of Ca and Ti in meteor spectra indicate that these elements suffer incomplete evaporation processes. The chemical composition of all meteoroids studied in this work differs from that of 1P/Halley dust.     

Analytical solutions of one‐dimensional infiltration before and after ponding

This paper is a continuation of previous research, which obtained a convenient solution for arbitrary surface fluxes before ponding. By means of Fourier Transformation this has been extended to derive analytical solutions of a linearized Richards' equation for arbitrary input fluxes after surface saturation. Copyright © 2003 John Wiley & Sons, Ltd.     

Measurements of the north polar cap of Mars and the Earth's northern hemisphere ice and snow cover

The boundaries of the polar caps of Mars have been measured on more than 3000 photographs since 1905 from the plate collection at the Lowell Observatory. For the Earth, the polar caps have been accurately mapped only since the mid 1960's when satellites were first available to synoptically view the polar regions. The polar caps of both planets wax and wane in response to changes in the seasons, and interannual differences in polar cap behavior on Mars as well as Earth are intimately linked to global energy balance. Data on the year to year variations in the extent of the north polar caps of Mars and Earth have been assembled and compared, although only 6 years of concurrent data were available for comparison.     

Peak metamorphic temperatures in type 6 ordinary chondrites: An evaluation of pyroxene and plagioclase geothermometry

Abstract— Quantifying the peak temperatures achieved during metamorphism is critical for understanding the thermal histories of ordinary chondrite parent bodies. Various geothermometers have been used to estimate equilibration temperatures for chondrites of the highest metamorphic grade (type 6), but results are inconsistent and span hundreds of degrees. Because different geothermometers and calibration models were used with different meteorites, it is unclear whether variations in peak temperatures represent actual ranges of metamorphic conditions within type 6 chondrites or differences in model calibrations. We addressed this problem by performing twopyroxene geothermometry, using QUILF95, on the same type 6 chondrites for which peak temperatures were estimated using the plagioclase geothermometer (Nakamuta and Motomura 1999). We also calculated temperatures for published pyroxene analyses from other type 6 H, L, and LL chondrites to determine the most representative peak metamorphic temperatures for ordinary chondrites. Pyroxenes record a narrow, overlapping range of temperatures in H6 (865–926 °C), L6 (812–934 °C), and LL6 (874–945 °C) chondrites. Plagioclase temperature estimates are 96–179 °C lower than pyroxenes in the same type 6 meteorites. Plagioclase estimates may not reflect peak metamorphic temperatures because chondrule glass probably recrystallized to plagioclase prior to reaching the metamorphic peak. The average temperature for H, L, and LL chondrites (～900 °C), which agrees with previously published oxygen isotope geothermometry, is at least 50 °C lower than the peak temperatures used in current asteroid thermal evolution models. This difference may require minor adjustments to thermal model calculations.     

Monitoring selective availability dither frequencies and their effect on GPS data

Summary The signals transmitted by Block II satellites of the Global Positioning System (GPS) can be degraded to limit the highest accuracy of the system (10 m or better point positioning) to authorized users. This mode of degraded operation is called Selective Availability (S/A). S/A involves the degradation in the quality of broadcast orbits and satellite clock dithering. We monitored the dithered satellite oscillator and investigated the effect of this clock dithering on high accuracy relative positioning. The effect was studied over short 3-meter and zero-baselines with two GPS receivers. The equivalent S/A effects for baselines ranging from 0 to >10,000 km can be examined with short test baselines if the receiver clocks are deliberately mis-synchronized by a known and varying amount. Our results show that the maximum effect of satellite clock dithering on GPS double difference phase residuals grows as a function of the clock synchronization error according to: S/A _effect =0.04 cm/msec, and it increases as a function of baseline length like: S/A _effect =0.014 cm/100 km. These are equations for maximum observed values of post-fit residuals due to S/A. The effect on GPS baselines is likely to be smaller than the 0.14 mm for a baseline separation of 100 km. We therefore conclude, for our limited data set, and for the level of S/A during our tests, that S/A clock dithering has negligible effect on all terrestrial GPS baselines if double difference processing techniques are employed and if the GPS receivers remain synchronized to better than 10 msec. S/A may constitute a problem, however, if accurate point processing is required, or if GPS receivers are not synchronized. We suggest and test two different methods to monitor satellite frequency offsets due to S/A. S/A modulates GPS carrier frequencies in the range of-2 Hz to +2 Hz over time periods of several minutes. The methods used in this paper to measure the satellite clock dither could be applied by the civilian GPS community to continuously monitor S/A clock dithering. The monitored frequencies may aid high accuracy point positioning applications in a postprocessing mode (Malys and Ortiz 1989), and differential GPS with poorly synchronized receivers (Feigl et al. 1991).     

V792 Her=HD 155638: A totally eclipsing RS CVn binary

Photometry of HD 155638=V792 Her has been analyzed to determine the elements of this totally eclipsing RS CVn binary. The light variation outside eclipse was found to have a period of 27^d.07±0^d.07, which is slightly different from the 27^d.5384±0^d.0045 orbital period. Analysis of the eclipses was achieved by a modification of the Russell-Merrill technique. With the aid of radial velocity measures, absolute elements were obtained for the hot and cool stars, respectively;R _h=2.58R ,R _c=12.28R ,M _h=1.40M ,M _c=1.46M ,i=80^o.61 and velocity semi-amplitudesK _c=48.36 km s^–1±0.79 km s^–1, andK _h=50.50 km s^–1±0.33 km s^–1. The apparent magnitudes areV _h=9 ^m .73 andV _c=8 ^m .48. The distance to HD 155638 was estimated to be 310 parsecs.     

Properties of r-modes in the Sun

Global oscillations of the Sun (r-modes) with very long periods 1 month are reviewed and studied. Such modes would be trapped in an acoustic cavity formed either by most of the convective envelope or by most of the radiative interior. A turning point frequency giving cavity boundaries is defined and the run of eigenvalues for angular harmonics l 3 are plotted for a conventional solar convection zone. The r-modes show equipartition of oscillatory energy among shells which each contain one antinode in the radial dimension. Toroidal motion is dominant to at least the 14^th radial harmonic mode. Viscosity from convective turbulence is strong and would damp any mode in just a few solar rotations if it were the only significant nonadiabatic effect. Radial fine splitting which lifts the degeneracy in n is very small (20 nHz or less) for all n 14 trapped in the envelope. But, if splitting could be detected, we would have a valuable new constraint on solar convection theories.     

Palaeoenvironmental significance of Late Permian palaeosols in the South‐Eastern Iberian Ranges,Spain

The Late Permian (Wuchiapingian) Alcotas Formation in the SE Iberian Ranges consists of one red alluvial succession where abundant soil profiles developed. Detailed petrographical and sedimentological studies in seven sections of the Alcotas Formation allow six different types of palaeosols, with distinctive characteristics and different palaeogeographical distribution, to be distinguished throughout the South‐eastern Iberian Basin. These characteristics are, in turn, related to topographic, climatic and tectonic controls. The vertical distribution of the palaeosols is used to differentiate the formation in three parts from bottom to top showing both drastic and gradual vertical upwards palaeoenvironmental changes in the sections. Reconstruction of palaeoenvironmental conditions based on palaeosols provides evidence for understanding the events that occurred during the Late Permian, some few millions of years before the well‐known Permian‐Triassic global crisis.     

Methane‐related microbial gypsum calcitization in stromatolites of a marine evaporative setting (Münder Formation,Upper Jurassic,Hils Syncline,north Germany)

Fossil stromatolites may reveal information about their hydrochemical palaeoenvironment, provided that assignment to a specific microbial community and a corresponding biogeochemical mechanism of formation can be made. Tithonian stromatolites of the Münder Formation at Thüste, north Germany, have traditionally been considered as formed by intertidal cyanobacterial communities. However, thin sections of the stromatolites show elongated angular traces of former gypsum crystals in a dense arrangement, but no algal or cyanobacterial filament traces. Moreover, high Fe²⁺ and Mn²⁺ contents, oxygen‐isotope and sulphur‐isotope ratios of carbonate‐bound sulphates, and sulphurized hydrocarbon biomarkers of the stromatolitic carbonate indicate that CaCO₃ precipitation occurred near the oxic–anoxic interface as a result of intensive bacterial sulphur cycling rather than photosynthetic activity. Furthermore, anaerobic oxidation of methane by Archaea may have driven CaCO₃ precipitation in deeper parts of the biofilm community, as reflected by high concentrations of squalane with a strongly negative δ¹³C in conjunction with evaporite pseudomorphs showing extremely low δ¹³C_Carb ratios. Consequently, the Thüste stromatolites are now interpreted as having initially formed by gypsum impregnation of biofilms. Subsequently, early Mg‐calcitic calcitization within the biofilms occurred because of combined bacterial iron, manganese and sulphate reduction, with an increasing contribution of anaerobic oxidation of methane with depth. This model plausibly explains the prominent preservation of signals derived from oxygen‐independent metabolic pathways, whereas virtually no geochemical record exists for an aerobic community that may, nevertheless, have prevailed at the stromatolite surface. Photic‐zone stromatolites with a prominent signal of anaerobic oxidation of methane may be common in, and indicative of, oxygen‐depleted sulphate‐bearing environments with high rates of methane production, conditions that possibly were fulfilled at the Archaean to Proterozoic transition.