Effect of a dolerite intrusion on triterpane stereochemistry and kerogen in Rundle oil shale,Australia

Stereochemical changes of triterpanes present in extracts from an immature oil shale sequence intruded by a 3-m dolerite sill have been studied by gas chromatography-mass spectrometry (GC-MS). The steric configuration of the hopanes was observed to change from one dominated by the thermally less stable 17β(H), 21β(H) configuration at some distance from the intrusion, to one dominated by the thermally more stable 17α(H), 21β(H) and 17β(H), 21α(H) configurating in the immediate vicinity of the intrusion. In addition, severe alteration of the kerogen appeared to have taken place as a result of the contact metamorphism, and high concentrations of extractable organic matter were observed below the intrusion. Characterization of the kerogens by Curie-point pyrolysis has enabled the effects of the intrusion on the shales to be monitored.     

Two pedogenic models for paleoclimatic records of magnetic susceptibility from Chinese and Siberian loess

The magnetic susceptibility (MS) of Chinese loess showing a general proportional relationship to pedogenic grade has been widely recognized and used for reconstruction of paleoclimate by Quaternary scientists. The in-situ pedogenic enhancement of ferrimagnetic content is normally believed to be the main reason for the increase of susceptibility in soil units. However, this pattern of high magnetic susceptibility in palaeosols, and low values in loess, are not replicated in some loess deposits. Siberian loess deposits display a completely opposite susceptibility behavior: high values in loess and low values in palaeosols. This inverse relationship has been explained by the idea that magnetic susceptibility is reflecting the magnitude of an aeolian ferrimagnetic component of consistent mineralogy, the grain size of which is related to average wind velocity. Our magnetic study of Siberian samples in this paper suggests that there are notable differences in magnetic properties between Siberian loess and developed palaeosols, not only in magnetic grain-size and concentration but also in magnetic mineralogy. This evidence is difficult to explain fully through variation in wind strength alone, but implies that the low magnetic susceptibility values in the Siberian paleosol units are a reflection, at least in part, of the alteration of the ferrimagnetic content by post-depositional processes. The Loess Plateau is a very arid area where potential evaporation is always higher than precipitation; pedogenesis occurs under dry oxidising conditions. The Siberian Kurtak region is located on the edge of the tundra where it is always wet and saturation during interglacials will lead to a reducing pedogenic environment. Ferrimagnetic minerals under this condition will be destroyed, resulting in lower magnetic susceptibility. Therefore, great care should be taken when using susceptibility values for paleoclimatic reconstruction.     

Review Paper: A semi‐empirical model of strain sensitivity for 4D seismic interpretation

We reformulate the original model of Hatchell and Bourne and Røste, Stovas and Landrø that couples fractional velocity change to subsurface strain via a fundamental constant R. The new model combines elastic compressibility of a dual‐porosity system for a sand–shale mixture with horizontal planes of inter‐granular weakness. The majority of observed R‐factor magnitudes from post‐stack 4D seismic data in both the reservoir and overburden can thus be explained. R is predicted to depend strongly on lithology and also initial strain state. The model is also extended to predict the observed angle‐dependence of time‐lapse time‐shifts from pre‐stack data. An expression for the gradient of time‐shift with incidence angle is obtained in terms of the background V_P/V_S, and also the ratio of tangential to normal compliances B_T/B_N representing loss or creation of inter‐granular coupling. If accurately estimated from data, this compliance ratio can be used as an additional parameter to assess the post‐production state of the overburden. It is concluded that whilst R remains the over‐arching parameter controlling the magnitude of time‐shifts measured from 4D seismic data, B_T/B_N is a subtler parameter that may also prove of future value.     

Composition of widespread volcanic glass in deep-sea sediments of the Southern Pacific Ocean: an Antarctic source inferred

Widespread Plio-Pleistocene (2.43-0.06 Ma) tephra zones recognised in deep-sea cores from high latitudes (>60°) in the Southern Pacific Ocean were thought to have originated from calc-alkaline rhyolitic eruptions in New Zealand, some 5000 km distant. Electron microprobe analyses of the glasses reveal a wide diversity of alkalic felsic compositions, as well as minor components of basic and intermediate glasses, incompatible with a New Zealand Neogene source but similar to contemporaneous eruptives from the Antarctic region. Most tephra zones are trachytic; seven zones are peralkaline rhyolite. The rhyolitic zones represent a deep-sea record of widespread silicic eruptions from continental Antarctica, possibly Marie Byrd Land. The extent of these rhyolitic zones suggest a greater frequency of large explosive eruptions in Antarctica than previously documented. The coarse grain size of some of the shards (up to 3 mm), their great distance from the closest sources (>1600 km for some cores), and the presence of nonvolcanic ice-rafted debris indicate some of the glasses, especially the more basic compositions, may have been ice-rafted, contrary to previous suggestions of a fallout origin.     

Integrating agriculture and energy to assess GHG emissions reduction: a methodological approach

Agriculture is responsible for approximately 25% of anthropogenic global GHG emissions. This significant share highlights the fundamental importance of the agricultural sector in the global GHG emissions reduction challenge. This article develops and tests a methodology for the integration of agricultural and energy systems modelling. The goal of the research is to extend an energy systems modelling approach to agriculture in order to provide richer insights into the dynamics and interactions between the two (e.g. in competition for land-use). We build Agri-TIMES, an agricultural systems module using the TIMES energy systems modelling framework, to model the effect of livestock emissions and explore emissions reduction options. The research focuses on Ireland, which is an interesting test case for two reasons: first, agriculture currently accounts for about 30% of Ireland's GHG emissions, significantly higher than other industrialized countries yet comparable with global levels (here including emissions associated with other land-use change and forestation); second, Ireland is both a complete and reasonably sized agricultural system to act as a test case for this new approach. This article describes the methodology used, the data requirements, and technical assumptions made to facilitate the modelling. It also presents results to illustrate the approach and provide associated initial insights.

Policy relevance

Most of the policy focus with regard to climate mitigation targets has been on reducing energy-related CO₂ emissions, which is understandable as they represent by far the largest source of emissions. Non-energy-related GHG emissions – largely from agriculture, industrial processes, and waste – have received significantly less attention in policy discourse. Going forward, however, if significant cuts are made in energy-related CO₂ emissions, the role of non-energy-related GHG emissions will grow in importance. It is therefore crucial that climate mitigation analyses and strategies are not limited to the energy system. This article shows the value of using integrated energy and agriculture techno-economic modelling techniques to draw evidence for new comprehensive climate policy strategies able to discern between the full range of technical solutions available. It enables the production of economy-wide least-cost climate mitigation pathways.     

UV irradiation of natural organic matter (NOM): impact on organic carbon and bacteria

UV-induced transformation of dissolved organic matter (DOC) is often accompanied by reduction of molecular weight and aromaticity and an increase of low-molecular weight (LMW) matter that can be utilized as a substrate by heterotrophic bacteria. Moreover, the generation of reactive transients and mineralization of DOC occurs. For a better understanding of the modification that starts after irradiation and to distinguish between possible chemical and biological modifications, we selected different natural organic matter (NOM) from Norway and Germany. The aqueous solutions were treated by UV irradiation and divided into two aliquot samples. NaN₃ anti-bacterial treatment was applied to one sample, and high-pressure size-exclusion chromatography (HPSEC) analysis was used for both. In all samples, we found typical modifications of NOM after UV irradiation. Incubation (>7?days) of UV-irradiated NOM samples resulted in lower levels of LMW matter and increased aromaticity. Parallel to these changes of carbon fractions, an increase in bacterial cell numbers was observed. Addition of NaN₃ to NOM, however, inhibited the reduction of LMW matter, indicating that microbial activity accounted for the observed changes in NOM. Analysis of the bacterial community composition by denaturing gradient gel electrophoresis (DGGE) of the amplified 16S rRNA genes revealed that bacterial communities of non-irradiated and UV-irradiated NOM were different and that UV selected for specific members of ??-proteobacteria, ??-proteobacteria, and Bacteriodetes. Our results imply that after UV-irradiation of NOM, specific bacterial members are well adapted to low pH, high LMW DOC concentrations, and oxidative stress, and therefore thrive well on UV-irradiated humic matter.     

Comparisons of the hydraulics of water flows in Martian outflow channels with flows of similar scale on earth

Comparisons are undertaken between the hydraulics of channelized water flows on Mars, large terrestrial rivers, deep-sea turbidity currents, and the catastrophic flow of Lake Missoula floods. Expected bottom shear stresses, velocities and discharges, flow powers, and other parameters are computed for each. Sand transport rates and the times required for channel erosion are estimated for Mangala Channel. These calculations indicate that the turbidity currents and Lake Missoula floods were similar to channelized water flow on Mars in their flow characteristics and in their abilities to erode and transport sediments. Like the Lake Missoula floods, deep-sea turbidity currents are catastrophic in character, being formed by the slumping of large masses of sediment trapped in submarine canyons or deposited on the continental slope. The repeated flows originating from submarine canyons have formed deep-sea channels similar in scale and overall morphology to the Martian outflow channels. The submarine canyon can be viewed as the counterpart of the chaotic terrain or crater which serves as sources for many Martian channels. Like most Martian outflow channels, the deep-sea channels generally lack tributaries or have only minor tributaries, instead consisting of a single pronounced channel extending for several hundred kilometers from its origin at the submarine canyon to deep abyssal depths. The channels vary considerably in dimensions, but most commonly have widths in the range 2 to 15 km with reliefs of 50 to 450 meters, again similar in scale to the Martian channels. Other similarities include sections of anastomosing channels, a general lack of pronounced meandering, and a lack of an apparent “delta” where the transported sediments are deposited. The similarities of channel morphology and flow hydraulics indicate the deep-sea channels and turbidity currents can be useful in furthering our understanding of the Martian outflow channels. Physical processes in the deep-sea occur under a reduced effective gravity because of the overlying water with its buoyancy. The deep-sea channels provide another set of Earth-based channels which can be studied to determine the effects of gravity on such factors as channel meandering and anastomosing characteristics.     

An example of post-collisional appinitic magmatism with an arc-like signature: the Wadi Nasb mafic intrusion,north Arabian–Nubian Shield,south Sinai,Egypt

We present new data for the Neoproterozoic mafic intrusion exposed in Wadi Nasb, south Sinai, Egypt (northernmost Arabian–Nubian Shield; ANS). The Nasb mafic intrusion (NMI) intrudes metasediments, Rutig volcanics, and diorite/granodiorite, and is intruded in turn by younger monzogranite and quartz-monzonite. Available geochronological data for the country rocks of the NMI provide a tight constraint on its age, between 619 and 610 Ma, during the hiatus between the lower and upper Rutig volcanics. The NMI is neither deformed nor metamorphosed, indicating post-collisional emplacement, and uralitization by late-magmatic and sub-solidus alteration is restricted to the margins of the intrusion. A quantitative fractionation model indicates a fractionating assemblage of 61% primary amphibole, 10% clinopyroxene, 28% plagioclase, 1% biotite, 0.4% apatite, and 0.15% Fe-Ti oxide. Contrary to the recent studies, we find that the nearby diorite of Gebel Sheikh El-Arab is not co-genetic with the appinitic gabbro of the NMI. Although there are volcanic xenoliths in the NMI, we find no chemical evidence requiring contamination by continental crust. A subduction-related signature in a post-orogenic intrusion requires the inheritance of geochemical tendencies from a previous subduction phase. Given that the fine-grained gabbro of the NMI is consistent with a near-primary mantle melt, we attribute this inheritance to persistence and later melting of the slab-modified mantle domains, as opposed to partial melting and assimilation of the juvenile continental crust. The fine-grained gabbro composition indicates derivation at temperature and pressure conditions similar to the sources of mid-ocean ridge basalts: mantle potential temperature near 1350°C and extent of melting about 7%. Such temperatures, neither so high as to require a plume nor so low as to be consistent with small degrees of melting of a volatile-rich source, are most consistent with a lithospheric delamination scenario, allowing the upwelling of fertile, subduction-modified asthenosphere to depths ≤50 km.     

Bowers Swell: Evidence for a zone of compressive deformation concentric with Bowers Ridge, Bering Sea

Bowers Swell is a newly discovered bathymetric feature which is up to 90 m high, between 12 and 20 km wide, and which extends arcuately about 400 km along the northern and eastern sides of Bowers Ridge. The swell was first revealed on GLORIA sonographs and subsequently mapped on seismic reflection and 3.5 kHz bathymetric profiles. These geophysical data show that the swell caps an arcuate anticlinal ridge, which is composed of deformed strata in an ancient trench on the northern and eastern sides of Bowers Ridge. The trench fill beneath the swell is actively deforming, as shown by faulting of the sea floor and by thinning of the strata across the crest of the swell. Thinning and faulting of the trench strata preclude an origin for the swell by simple sediment draping over an older basement high. We considered several models for the origin of Bowers Swell, including folding and uplift of the underlying trench sediment during the interaction between the Pacific plate beneath the Aleutian Ridge and a remnant oceanic slab beneath Bowers Ridge. However, such plate motions should generate extensive seismicity beneath Bowers Ridge, which is aseismic, and refraction data do not show any remnant slab beneath Bowers Ridge. Another origin considered for Bowers Swell invokes sediment deformation resulting from differential loading and diapirism in the trench fill. However, diapirism is not evident on seismic reflection profiles across the swell. We favour a model in which sediment deformation and swell formation resulted from a few tens of kilometers of low seismicity motion by intraplate crustal blocks beneath the Aleutian Basin. This motion may result from the translation of blocks in western Alaska to the south-west, forcing the movement of the Bering Sea margin west of Alaska into the abyssal Aleutian Basin.     

Toxicity of Santa Barbara seep oil to starfish embryos: Part 3—influence of parental exposure and the effects of other crude oils

We exposed the bat starfish, Patiria miniata, to the water-soluble fraction (WSF) of oil from a natural seep near Santa Barbara, California, during the first 48 hours of embryological growth. There were no consistent differences among populations whose parents were from areas with differing levels of hydrocarbon exposure. In a second experiment, the order of decreasing toxicity of crude oils to the embryos was: Monterey Zone > Rincon Zone > Prudhoe Bay > Isla Vista Seep. The results are discussed in relation to the effects of natural seeps and oil characteristics.