Geochemistry and origin of Dehoo manganese deposit,south Zahedan,southeastern Iran

Dehoo manganese deposit is located 52 km to the south of Zahedan in Sistan and Baluchestan Province, southeastern Iran. This deposit that lies in the central part of the Iranian Flysch Zone is lenticular in shape and lies above the micritic limestone-radiolarite cherts of the upper Cretaceous ophiolite unit. It is hosted within the reddish to brown radiolarite cherts and in places interlinks with them, so that the radiolarite chert packages play a key role for Mn mineralization in the region. Investigated ore-paragenetic successions and the geochemical characteristics of the Dehoo deposit were studied by means of major oxide, trace, and rare earth element (REE) contents that provide information as to the mineral origin. Strong positive correlations were found between major oxides and trace elements (Al₂O₃-TiO₂, r = 0.95; TiO₂-MgO, r = 0.94; Fe₂O₃-Al₂O₃, r = 0.90; MgO-Al₂O₃, r = 0.84; MgO-Fe₂O₃, r = 0.88; Fe₂O₃-TiO₂, r = 0.91; Fe₂O₃-K₂O, r = 0.74; Al₂O₃-K₂O, r = 0.69; Al₂O₃-V, r = 0.72; TiO₂-V, r = 0.73, and MgO-V, r = 0.69) that testify to the contribution of mafic terrigenous detrital material to the deposit. Chondrite-normalized REE patterns of all ore samples are characterized by negative Ce (0.06–0.15, average 0.10) and slightly positive Eu (0.29–0.45, average 0.36) anomalies. Based on ratios of Mn/Fe (average 56.23), Co/Ni (average 0.33), Co/Zn (average 0.38), U/Th (average 3.40), La/Ce (average 1.45), La_n/Nd_n (average 2.16), Dy_n/Yb_n (average 0.33), and light REE/heavy REE (average 8.40; LREE > HREE), as well as Ba (average 920 ppm) and total REE contents (average 6.96 ppm) negative Ce and positive Eu anomalies, Dehoo could be considered a predominantly submarine hydrothermal Mn deposit complemented by terrigenous detrital mafic material.     

Neoproterozoic calc‐alkaline peraluminous granitoids of the Deleihimmi pluton,Central Eastern Desert,Egypt: implications for transition from late‐ to post‐collisional tectonomagmatic evolution in the northern Arabian–Nubian Shield

The widely distributed late‐collisional calc‐alkaline granitoids in the northern Arabian–Nubian Shield (ANS) have a geodynamic interest as they represent significant addition of material into the ANS juvenile crust in a short time interval (∼630–590 Ma). The Deleihimmi granitoids in the Egyptian Central Eastern Desert are, therefore, particularly interesting since they form a multiphase pluton composed largely of late‐collisional biotite granitoids enclosing granodiorite microgranular enclaves and intruded by leuco‐ and muscovite granites. Geochemically, different granitoid phases share some features and distinctly vary in others. They display slightly peraluminous (ASI = 1–1.16), non‐alkaline (calc‐alkaline and highly fractionated calc‐alkaline), I‐type affinities. Both biotite granitoids and leucogranites show similar rare earth element (REE) patterns [(La/Lu)_N = 3.04–2.92 and 1.9–1.14; Eu/Eu* = 0.26–0.19 and 0.11–0.08, respectively) and related most likely by closed system crystal fractionation of a common parent. On the other hand, the late phase muscovite granites have distinctive geochemical features typical of rare‐metal granites. They are remarkably depleted in Sr and Ba (4–35 and 13–18 ppm, respectively), and enriched in Rb (381–473 ppm) and many rare metals. Moreover, their REE patterns show a tetrad effect (TE_1,3 = 1.13 and 1.29) and pronounced negative Eu anomalies (Eu/Eu* = 0.07 and 0.08), implying extensive open system fractionation via fluid–rock interaction during the magmatic stage. Origin of the calc‐alkaline granitoids by high degree of partial melting of mafic lower crust with subsequent crystal fractionation is advocated. The broad distribution of late‐collisional calc‐alkaline granitoids in the northern ANS is related most likely to large areal and intensive lithospheric delamination subsequent to slab break‐off and crustal/mantle thickening. Such delamination caused both crustal uplift and partial melting of the remaining mantle lithosphere in response to asthenospheric uprise. The melts produced underplate the lower crust to promote its melting. The presence of microgranular enclaves, resulting from mingling of mantle‐derived mafic magma with felsic crustal‐derived liquid, favours this process. The derivation of the late‐phase rare‐metal granites by open system fractionation via fluid interaction is almost related to the onset of extension above the rising asthenosphere that results in mantle degassing during the switch to post‐collisional stage. Consequently, the switch from late‐ to post‐collisional stage of crustal evolution in the northern ANS could be potentially significant not only geodynamically but also economically. Copyright © 2011 John Wiley & Sons, Ltd.     

Earthquake response of concrete arch dams: a plastic–damage approach

There are several alternatives to evaluate seismic damage‐cracking behavior of concrete arch dams, among which damage theory is the most popular. A more recent option introduced for this purpose is plastic–damage (PD) approach. In this study, a special finite element program coded in 3‐D space is developed on the basis of a well‐established PD model successfully applied to gravity dams in 2‐D plane stress state. The model originally proposed by Lee and Fenves in 1998 relies on isotropic damaged elasticity in combination with isotropic tensile and compressive plasticity to capture inelastic behaviors of concrete in cyclic or dynamic loadings. The present implementation is based on the rate‐dependent version of the model, including large crack opening/closing possibilities. Moreover, with utilizing the Hilber–Hughes–Taylor time integration scheme, an incremental–iterative solution strategy is detailed for the coupled dam–reservoir equations while the damage–dependent damping stress is included. The program is initially validated, and then, it is employed for the main analyses of the Koyna gravity dam in a 3‐D modeling as well as a typical concrete arch dam. The former is a major verification for the further examination on the arch dam. The application of the PD model to an arch dam is more challenging because the governing stress condition is multiaxial, causing shear damage to become more important than uniaxial states dominated in gravity dams. In fact, the softening and strength loss in compression for the damaged regions under multiaxial cyclic loadings affect its seismic safety. Copyright © 2013 John Wiley & Sons, Ltd.     

PM10 Source Apportionment in Ahvaz,Iran, Using Positive Matrix Factorization

Source apportionment of particulate matter <10 µm in diameter (PM₁₀), having considerable impacts on human health and the environment, is of high priority in air quality management. The present study, therefore, aimed at identifying the potential sources of PM₁₀ in an arid area of Ahvaz located in southwest of Iran. For this purpose, we collected 24‐h PM₁₀ samples by a high volume air sampler. The samples were then analyzed for their elemental (Al, As, B, Ba, Be, Ca, Cd, Co, Cr, Cu, Fe, Hg, K, Mg, Mn, Na, Ni, Pb, Se, Si, Sn, Sr, Li, Ti, V, Zn, Mo, and Sb) and ionic (NH, Cl^?, NO, and SO) components using inductively coupled plasma optical emission spectrometry and ion chromatography instruments, respectively. Eight factors were identified by positive matrix factorization: crustal dust (41.5%), road dust (5.5%), motor vehicles (11.5%), marine aerosol (8.0%), secondary aerosol (9.5%), metallurgical plants (6.0%), petrochemical industries and fossil fuel combustion (13.0%), and vegetative burning (5.0%). Result of this study suggested that the natural sources contribute most to PM₁₀ particles in the area, followed closely by the anthropogenic sources.     

Pore pressure assessment from well data and overpressure mechanism: Case study in Eastern Tunisia basins

Abstract

Independent and complementary methods were used for pore pressure assessment in the eastern Tunisian basins. Drilling data and surveys allow settling the pore pressure profile in these basins. The main used parameters are mud weights, formation pressure surveys, drilling parameters, well logs, fluids exchange with formation and borehole issues. In the eastern Tunisia platform, the pore pressure profiles show changes in overpressure magnitude in all the three dimensions of the basin (location and depth/stratigraphy). We highlighted two overpressure intervals form bottom to top: The late Cretaceous in the North-eastern part, and the Tertiary overpressure interval hosted in the Palaeocene to Miocene series. The structural analysis of overpressure location shows that the Tertiary interval is likely to have originated in a disequilibrium compaction in Cenozoic grabens. Pore pressure cross sections and maps confirm the link between active normal faults that segmented the basin to grabens and highs and pore pressure anomalous area. In the Senonian interval, we noted mature source-rocks that can explain the overpressure in the late Cretaceous interval. In addition, the recent to active compressive tectonics may have contributed to both pore pressure anomaly generations. The fluid overpressures characterization in the eastern Tunisian sedimentary basins helps in hydrocarbons exploration. Indeed, the overpressure interval in the reservoir levels stimulates and improves the production in the oilfields and contributes to hydrocarbon trapping. Moreover, the adequate prediction of pore pressure profile contributes to reduce drilling cost and enhance the drilling operations safety.     

On the Impact of the Assimilation of SARAL/AltiKa Wave Data in the Operational Wave Model MFWAM

As a part of our calibration/validation activities five months of SARAL/AltiKa wave data have been analyzed in this study. A robust quality control procedure using threshold values on signal and retrieved wave heights was implemented before the assimilation. Assimilation runs in the wave model Météo-France (MFWAM) were performed for a long period. The validation of the model outputs was performed with independent wave observations from altimeter and buoy data. The results indicate good performance in terms of bias and scatter index for the significant wave height and the peak wave period. Statistical analyses were performed for different ocean basins (high and intermediate latitudes and tropics). The use of SARAL/AltiKa and Jason-2 wave data combined was also investigated. This leads to further improvements for the analysis and forecast periods. In other respects, the impact of the assimilation of SARAL/AltiKa wave data is discussed for waves under strong wind conditions such as typhoons Fitow and Danas which occurred in early October 2013.     

Application of water pinch technology for water and wastewater minimization in aluminum anodizing industries

This study aims to describe the application of water pinch technology in industrial water consumption management in aluminum anodizing industry. Water pinch analysis is a systematic technique for designing, optimization and retrofitting of energy, mass and water recovery networks. The selection of different operations existing in an industry has an important role in correctness of application of pinch technology. Water usages in anodizing industry are various, but researches have been shown that, it has the best efficiency on the selection of rinsing chambers to pinch technology. There are different methods in pinch technology mostly based on mass transfer of single or multiple contaminants. In this research, a new method is used to select effective contaminant to be applied to pinch analysis. This research is based on Mann and Liu’s method in single contaminant. But “the guide for classification of raw water, wastewater and recycled water for industrial and recreation” is chosen to use a complex of index contaminants as a single contaminant. This method is very simple and applicable for various industrial processes. By an index contaminant like total dissolved solids, the water usage reduced about 6.7 %. Using pinch technology and this new approach in three rinsing chambers, water usage reduced about 14.4 %.     

Formulation of hydrodynamic pressures in cracks due to earthquakes in concrete dams

A new analytical development of the seismic hydrodynamic pressure inside pre-existing cracks on the upstream face of concrete dams is presented. The finite control volume approach is utilized to derive an expression for the seismic hydrodynamic pressure using the continuity principle and the linear momentum theorem for the fluid inside the crack. The derived pressure expression is a function of the relative crack-opening acceleration and velocity. The acceleration and velocity terms are then recast in the form of added mass and damping matrices which can then be included at the nodes inside the discrete crack of a finite element model. This procedure linearizes the solution of the problem. A dam, 55 m high and having an initial crack opening of 2 mm at the base or near the crest and subjected to two different accelerograms, is analysed. For high-frequency ground motion, the seismic hydrodynamic pressure inside the crack, at the base of the dam, appears to be 50 per cent higher than the corresponding hydrostatic pressure.     

First direct age determination from the Jurassic radiolarian-bearing siliceous series (Jédidi Formation) of northwestern Tunisia

Our study presents preliminary biostratigraphic results from the Jurassic siliceous series of northwestern Tunisia. For the first time, radiolarians are extracted from the Jédidi formation and provide a direct age determination. They are the first radiolarian fauna documented from Tunisia. Two age assignments are comprised within the following intervals: (1) Late Bathonian–Early Callovian, (2) Late Bathonian–Early Oxfordian. These ages are compatible with recent stratigraphic synthesis proposed for the Jurassic series of Tunisia. The data suggest the correlation of the Jédidi formation with siliceous series of Middle–Late Jurassic age from the external zone of the Maghrebides belt rather than with true oceanic units from the Maghrebian flyschs or the internal zones of western Tethys. To cite this article: F. Cordey et al., C. R. Geoscience 337 (2005).