Buried palaeosols of the Nevado de Toluca: an alternative record of Late Quaternary environmental change in central Mexico

Buried palaeosols of central Mexico, not previously analysed from a palaeopedological standpoint, have helped to develop a reliable regional model of Late Quaternary climatic change. This paper focuses upon morphological and micromorphological properties, particle‐size distribution, and extractable Fe, Al and Si of seven palaeosols (named PT1–PT7) in the vicinity of the Nevado de Toluca volcano. The characteristics of Andic Cambisol PT1, similar to those of modern soils in semi‐arid environments, indicate a drier climate in the first half of the Holocene. Humic Andosols PT2–PT4 are analogous to modern volcanic soils of humid forest environments. They show evidence that a moist palaeoclimate prevailed during marine oxygen isotope stages (OIS) 2 and 3. Luvisols PT5 and PT6, which are assumed to have formed at the end of marine OIS 5 to marine OIS 4, also indicate humid conditions. We attribute the differences between Andosols PT2–PT4 and Luvisols PT5–PT7 to variations in the duration in the pedogenesis rather than to changes in palaeoclimate. Micromorphological features of Andosol to Luvisol transition confirm that these soils form an evolutionary sequence. Being for the most part consistent with lacustrine records, the palaeosol properties do not reflect the episodes of ‘drier climate’ during the Last Glacial Maximum, however, as shown by diatom and palynological data from lake sediments. Mesoclimate variations and/or incompleteness of ‘soil memory’, reflecting mostly periods of humid pedogenesis, probably provide the reason for this disagreement. Copyright © 2001 John Wiley & Sons, Ltd.     

Application of a new computer program for tectonic discrimination of Cambrian to Holocene clastic sediments

TecSand is a new Java software that is used for deciphering the tectonic setting of clastic sediments and sedimentary rocks through two new multidimensional discrimination diagrams. For each sample, TecSand calculates four complex discriminant functions: DF1_m1 and DF2_m1 for the high-silica diagram and DF1_m2 and DF2_m2 for the low-silica diagram, each representing linear combinations of log-ratios of all major elements. These functions determine the position of each sample within island or continental arc, continental rift, and collision/convergent settings. The program also calculates the probability values for the three tectonic fields. TecSand provides a “ready for publication” report for each locality, including the adjusted major elements, log-transformed variables, DF1 and DF2 results, and probability values for individual samples. Validations from samples of known tectonic settings, evaluation of chemical changes, and applications to Precambrian clastic sediments have previously been demonstrated in the literature. Therefore, we illustrate the use of TecSand in 10 case studies covering ages from the Early Cambrian to the Holocene. The results obtained from these two diagrams were not only mutually consistent but also with other geological constraints. As an innovation, TecSand provides an overall synthesis of the two diagrams as total percent probability values. Comparison of the results of this study with the previously published tectonic discrimination diagrams reveals that two recent multidimensional discrimination diagrams are more efficient in discriminating tectonic settings. Although TecSand does provide graphics, which can be imported and modified in commercial software, plotting of the sample diagram is no longer required.     

Quality control in geochemistry from a comparison of four central tendency and five dispersion estimators and example of a geochemical reference material

Data quality control in geochemistry constitutes a fundamental problem that is still to be solved from the application of statistics and computation. We used refined Monte Carlo simulations of 10,000 replications and 190 independent experiments for sample sizes of 5 to 100. Statistical contaminations of 1 to 4 observations were used to compare 9 statistical parameters (4 central tendency—mean, median, trimean, and Gastwirth mean, and 5 dispersion estimates—standard deviation, median absolute deviation, S _n , Q _n , and \( {\widehat{\sigma}}_n \)). The presence of discordant observations in the data arrays rendered the outlier-based and robust parameters to disagree with each other. However, when the mean and standard deviation (outlier-based parameters) were estimated from censored data arrays obtained after the identification and separation of outlying observations, they generally provided a better estimate of the population than the robust estimates obtained from the original data arrays. This inference is contrary to the general belief, and therefore, reasons for the better performance of the outlier-based methods as compared to the robust methods are suggested. However, when all parameters were estimated from censored arrays and appropriate precise and accurate correction factors put forth in this work were applied, all of them became fully consistent, i.e., the mean agreed with the median, trimean and Gastwirth mean, and the standard deviation with the median absolute deviation, S _n , Q _n , and \( {\widehat{\sigma}}_n \). An example of inter-laboratory chemical data for a Hawaiian reference material BHVO-1 included sample sizes from 5 to 100, which showed that small samples of up to 20 provide inconsistent estimates, whereas larger samples of 20–100, especially >40, were more appropriate for estimating statistical parameters through robust or outlier-based methods. Although all statistical estimators provided consistent results, our simulation study shows that it is better to use the censored sample mean and population standard deviation as the best estimates.     

Spatial and temporal variation of natural recharge in the semi-arid valley of Aguascalientes,Mexico

The investigation involves a temporal and spatial analysis to characterize recharge in the Aguascalientes valley in central Mexico. The results are based on a two-part methodological strategy using a geospatial and numerical analysis. Results from the geospatial analysis are based on the analytical hierarchical process (AHP) method, which involves developing a zoning map that qualifies the conditions for groundwater recharge in the valley. In addition, one-dimensional numerical modeling based on the van Genuchten equation was applied for various soil column configurations to estimate the transit time of recharge through the vadose zone. The analysis was performed over a 20-year period from 1995 to 2015. The results of the geospatial analysis indicate that the optimal area for groundwater recharge is the lower zone of the valley, particularly the portion influenced by surface discontinuities. The shortest estimated period of recharge for water to pass through the vadose zone is approximately 4.25 years.     

Paleohydrological Changes in Highland Desert Rivers and Human Occupation, 7000‐3000 Cal. Yr B.P., South‐Central Andes,Argentina

This article focuses on local paleohydrological changes experienced by the Las Pitas and Miriguaca Rivers in the south‐central Andes of Argentina and their impacts on hunter‐gatherers as they transitioned to food‐producing communities 7000–3000 cal. yr B.P. Paleoenvironmental reconstruction based on geomorphology, alluvial sedimentology, and diatom evidence indicates a dry phase of reduced streamflow between ca. 6700 and 4800 cal. yr B.P. for the Las Pitas River, and 6600 and 3000 cal. yr B.P. for the Miriguaca River. A phase of more humid environmental conditions commenced after ca. 4900 cal. yr B.P. along the Las Pitas River, and after 3000 cal. yr B.P. along the Miriguaca River. Differences in the chronology and magnitude of hydrological changes along both rivers are related to topographic and hydrological characteristics of their respective watersheds. Higher catchment elevation and enhanced orographic precipitation favored greater sensitivity for the Las Pitas River to short humid events during the middle‐to‐late Holocene. The archaeological evidence suggests that the paleohydrological changes within these catchments played a significant role in human occupational dynamics such that the Las Pitas River offered better environmental conditions for human occupation relative to the Miriguaca River as foragers increasingly relied on plant and animal domestication.     

New classification system for mass transport complexes in offshore Trinidad

This paper delineates our use of 10 708 km² of three‐dimensional (3D) seismic data from the continental margin of Trinidad and Tobago West Indies to describe a series of mass transport complexes (MTCs) that were deposited during the Plio‐Pleistocene. This area, situated along the obliquely converging boundary of the Caribbean/South American plates and proximal to the Orinoco Delta, is characterized by catastrophic shelf‐margin processes, intrusive/extrusive mobile shales and active tectonism. Extensive mapping of different stratigraphic intervals of the 3D seismic survey reveals several MTCs that range in area from 11.3 to 2017 km². Three types of MTCs are identified: (1) shelf‐attached systems that were fed by shelf‐edge deltas whose sediment input is controlled by sea‐level fluctuations and sedimentation rates; (2) slope‐attached systems, which occur when upper‐slope sediments catastrophically fail owing to gas‐hydrate disruptions and/or earthquakes and (3) locally detached systems, formed when local instabilities in the seafloor trigger relatively small collapses. Such classification of the relationship between slope mass failures and sourcing regions enables a better understanding of the nature of initiation, length of development history and petrography of such MTCs. 3D seismic enables more accurate calculation of deposit volumes, improves deposit imaging, and, thus, increases the accuracy of physical and computer simulations of mass failure processes.     

Connectivity in a Karst System Using Electrical Resistivity Tomography and Network Theory

The Ring of Cenotes (RC) is an alignment of numerous cenotes (sinkholes) in a semicircular form (with a radius of 100 km) located in northwestern Yucatán, México. The formation roughly coincides with a concentric ring that corresponds to a buried structure, which has been identified as the product of a meteor impact, known as the Chicxulub crater. Secondary permeability generated by the fracturing and faulting of the sedimentary sequence in the Chicxulub crater has favored the karstification process and therefore the development of underground rivers that transport water from the mainland to the sea. This study implements the network theory to study the hydrological connectivity between a group of 11 cenotes within the RC. Eight electrical resistivity tomography transects were used as an empirical basis. Each transect was acquired directly in the field using the SuperSting R1/IP equipment with a dipole‐dipole configuration. An adapted version of the reliability algorithm for communication networks was used as a theoretical model. We found evidence of the existence of water cavities in the study area. We made a network from the data and assigned connection probabilities among cenotes as a function of the separation length and the number of water cavities, as well as their size.     

Advantages and Limitations of Using Mobile Apps for Protected Area Monitoring and Management

Digital technologies, including participatory Internet mapping, social media and smartphones, provide new avenues for research in outdoor recreation and tourism. The potential to reach a greater audience and collect visitation data on a broader scale, with less costs than traditional paper surveys, are key advantages that have increased the use of these novel technologies. Using of mobile apps for data collection is still at the experimental stage. We evaluate previous attempts to use apps for monitoring recreation and tourism in protected areas, as an alternative to other in situ or online methods. We present a pilot study implemented in Jotunheimen National Park (Norway), where we developed a mobile app for visitor monitoring and real-time mapping of values and experiences. We present the lessons learned, give suggestions on how and for what apps can be used, and discuss the advantages and limitations of using smartphones for visitor monitoring in protected areas.     

Magnetostratigraphy of the impact breccias and post‐impact carbonates from borehole Yaxcopoil‐1, Chicxulub impact crater,Yucatán,Mexico

Abstract— We report the magnetostratigraphy of the sedimentary sequence between the impact breccias and the post‐impact carbonate sequence conducted on samples recovered by Yaxcopoil‐1 (Yax‐1). Samples of impact breccias show reverse polarities that span up to ～56 cm into the post‐impact carbonate lithologies. We correlate these breccias to those of PEMEX boreholes Yucatán‐6 and Chicxulub‐1, from which we tied our magnetostratigraphy to the radiometric age from a melt sample from the Yucatán‐6 borehole. Thin section analyses of the carbonate samples showed a significant amount of dark minerals and glass shards that we identified as the magnetic carriers; therefore, we propose that the mechanism of magnetic acquisition within the carbonate rocks for the interval studied is detrital remanent magnetism (DRM). With these samples, we constructed the scale of geomagnetic polarities where we find two polarities within the sequence, a reverse polarity event within the impact breccias and the base of the post‐impact carbonate sequence (up to 794.07 m), and a normal polarity event in the last ～20 cm of the interval studied. The polarities recorded in the sequence analyzed are interpreted to span from chron 29r to 29n, and we propose that the reverse polarity event lies within the 29r chron. The magnetostratigraphy of the sequence studied shows that the horizon at 794.11 m deep, interpreted as the K/T boundary, lies within the geomagnetic chron 29r, which contains the K/T boundary.     

Relative Efficiency of Single-Outlier Discordancy Tests for Processing Geochemical Data on Reference Materials and Application to Instrumental Calibrations by a Weighted Least-Squares Linear Regression Model

Numerous studies report geochemical data on reference materials (RMs) processed by outlier-based methods that use univariate discordancy tests. However, the relative efficiency of the discordancy tests is not precisely known. We used an extensive geochemical database for thirty-five RMs from four countries (Canada, Japan, South Africa and USA) to empirically evaluate the performance of nine single-outlier tests with thirteen test variants. It appears that the kurtosis test (N15) is the most powerful test for detecting discordant outliers in such geochemical RM databases and is closely followed by the Grubbs type tests (N1 and N4) and the skewness test (N14). The Dixon-type tests (N7, N8, N9 and N10) as well as the Grubbs type test (N2) depicted smaller global relative efficiency criterion values for the detection of outlying observations in this extensive database. Upper discordant outliers were more common than the lower discordant outliers, implying that positively skewed inter-laboratory geochemical datasets are more frequent than negatively skewed ones and that the median, a robust central tendency indicator, is likely to be biased especially for small-sized samples. Our outlier-based procedure should be useful for objectively identifying discordant outliers in many fields of science and engineering and for interpreting them accordingly. After processing these databases by single-outlier discordancy tests and obtaining reliable estimates of central tendency and dispersion parameters of the geochemical data for the RMs in our database, we used these statistical data to apply a weighted least-squares linear regression (WLR) model for the major element determinations by X-ray fluorescence spectrometry and compared the WLR results with an ordinary least-squares linear regression model. An advantage in using our outlier procedure and the new concentration values and uncertainty estimates for these RMs was clearly established.