Sedimentary processes and trace metal contaminants in the buccaneer oil/gas field,northwestern gulf of Mexico

Sediments are the ultimate sink for contaminants in the marine environment, and physical processes of sedimentation influence the distribution and accumulation of these contaminants. Evaluation of contaminant levels in sediments is one approach to assessing environmental impact; data interpretation depends on consideration of sediment texture and mineralogy, however, which profoundly influence chemical composition. In this study, comparison of potentially contaminated sediments from the production field with control populations was done only within the context of similar (as to texture and organic carbon and carbonate content) sample groups as determined by cluster analysis. Ba, Cd, and Sr are identified as contaminants. Supported by the identification of a well-crystallized expandable clay—possibly bentonite—drilling fluids are a potential source of Ba. Ba and Sr may be unnaturally high because of their abundance in discharged produced formation waters, but may also be naturally controlled by the unique faunal assemblage associated with the structures. Cd is probably derived from corrosion of the structures and assorted debris on the seafloor. In general, contamination is limited to an area within 100 m of the platforms. Furthermore, substantial erosion around platforms has probably effectively removed and dispersed the bulk of the contaminants introduced into the marine environment by the offshore exploration/production operations.     

Simulation of the diurnal evolution of the atmospheric boundary layer

Results of simulating the diurnal evolution of the atmospheric boundary layer (ABL) with a second-order closure model are presented. The model includes new algebraic expressions for triple correlations to describe their behavior over the entire height of the mixed layer adequately to measurements. The model also takes into account the influence of long-wave radiation on the heat balance, which becomes important in the nocturnal ABL. The modeling results are compared with 24-h ABL evolution simulations by the third-order closure model and available in situ and laboratory measurements.     

Way forward to achieve sustainable and cost-effective biofuel production from microalgae: a review

Driven by policies aimed at enhancing energy security and mitigating greenhouse gas emissions, the production and use of biofuels have significantly increased in recent years. Microalgae owing to its multiple advantages which include high lipid content, sustainable biomass production, effective land and water utilization are the most potential biofuel feedstock that can provide drop-in fossil fuel replacements without stimulating competition for agricultural resources and are considered to be more environmentally benign than the first- and second-generation biofuel feedstocks. However, there are many existing technical and scientific impediments that are yet to be resolved. Keeping this in view, the present review provides a concise account of the microalgal species known to accumulate high levels of lipid and describes the main factors that should be taken into consideration while selecting suitable algal strains for mass cultivation. The underlining advantages and limitations of raceway pond and photobioreactor cultivation systems are also examined. The recent advances in genetic engineering of microalgae to improve biomass and lipid productivity are then highlighted, which include the ongoing debate over the biosafety issues pertinent to the use of genetically modified algae. Furthermore, a wide range of high-value products that can be co-produced from microalgae have been discussed. The review concludes with a comprehensive summary of the major techno-economic constraints to commercialization of algal-derived biofuels along with promising methods for overcoming these challenges in order to produce cost-competitive and environmentally sustainable biofuel.     

Mineralogy and geochemistry of lateritic soil profiles in Kerala, India

Lateritic soils near Calicut, Kerala, contain halloysite of intermediate hydration, kaolinite, goethite, gibbsite and quartz. The presence of halloysite is responsible for relatively high plasticity and cation-exchange capacity. Fe-hydroxide colloids along with halloysite contribute to significant phosphate uptake by this soil. Composition of local groundwater is consistent with weathering of sodic plagioclase to gibbsite, kaolinite and metastable halloysite.     

Investigation on strength and stability of jointed rock mass using three‐dimensional numerical manifold method

This paper proposes a numerical model for jointed rock masses within the 3‐D numerical manifold method (NMM) framework equipped with a customized contact algorithm. The strength of rock sample containing a few sets of discontinuities is first investigated. The results of models with simple geometries are compared with the available analytical solutions to verify the developed computer code, whereas models with complex geometries are simulated to better understand the fundamental behavior and failure mechanism of jointed rock mass. Furthermore, the stability of jointed rock mass in an underground excavation is studied, where rock failure process is determined by the 3‐D NMM simulation. The simulation results provide valuable guidance on excavation process design and stabilization design in rock engineering practice. Copyright © 2012 John Wiley & Sons, Ltd.     

Effects of a Fence on Pollutant Dispersion in a Boundary Layer Exposed to a Rural-to-Urban Transition

Simultaneous particle-image velocimetry and laser-induced fluorescence combined with large-eddy simulations are used to investigate the flow and pollutant dispersion behaviour in a rural-to-urban roughness transition. The urban roughness is characterized by an array of cubical obstacles in an aligned arrangement. A plane fence is added one obstacle height h upstream of the urban roughness elements, with three different fence heights considered. A smooth-wall turbulent boundary layer with a depth of 10h is used as the approaching flow, and a passive tracer is released from a uniform line source 1h upstream of the fence. A shear layer is formed at the top of the fence, which increases in strength for the higher fence cases, resulting in a deeper internal boundary layer (IBL). It is found that the mean flow for the rural-to-urban transition can be described by means of a mixing-length model provided that the transitional effects are accounted for. The mixing-length formulation for sparse urban canopies, as found in the literature, is extended to take into account the blockage effect in dense canopies. Additionally, the average mean concentration field is found to scale with the IBL depth and the bulk velocity in the IBL.     

Improved in situ gamma-ray transmission densitometer for marine sediments

The first-generation University of Illinois gamma-ray transmission densitometer, designed for the in situ measurement of sediment bulk density, was modified by incorporating in the detector probe (1) an Americium-241 alpha particle pulser and an anti-walk gain stabilization control to maintain better temperature stability and (2) a small power supply and a IC preamplifier to eliminate the need for a high-voltage coaxial cable between the detector and external signal conditioning electronics package. This second-generation Lehigh University system has been successfully deployed since 1971 in routine use from ships and submersibles in the Atlantic and Pacific Oceans and the Gulf of Mexico. Results are presented of system operations to (1) measure bulk density over the range of 1.2–1.8 Mg/m³ in the Hudson Canyon, (2) penetrate 1.9 m into the seafloor in the San Diego trough and, (3) be lowered to a water depth of 3.6 km in the Gulf of Mexico.     

Topography and a magnetic analysis of an area south-east of the Azores (36°N, 23°W)

A detailed survey of a 1°×1°-square of seafloor 100 miles south-east of the Azores shows a strong correlation between directions of regional topographic and magnetic lineations. The area is dissected by the East Azores Fracture Zone at 36°55N, identified as the active Eurasian-African plate boundary, and by another large, non-active fracture zone at 36°10N. Both fracture zones strike 265° and are accompanied by large amplitude magnetic anomalies. The general strike in the area in between is 000°–015°. The skewing effect at this magnetic latitude is very sensitive to variations in strike of the magnetic contrasts. This effect was eliminated by a non-linear transformation which also gives the positions of magnetic contrasts. Some N-S contrasts were identified as sea floor spreading polarity contrasts (anomalies 31 and 32). Weak contrasts could be identified as topographic effects and gave a magnetization intensity of 5 A m^-1. The identified sea floor spreading anomalies to both sides of the fracture zone at 36°10N agree very well, also quantatively, with a three-dimensional model for the fracture zone anomalies. This model describes the non-linear anomalies as end effects of the magnetic layer which is divided in blocks of alternating polarity.     

Comparison of three oxidation methods used for the analysis of the dissolved organic carbon in seawater

Three methods for the determination of dissolved organic carbon in seawater were compared. Samples were analysed using persulphate oxidation, high-temperature combustion, and ultraviolet photo-oxidation. The dissolved organic carbon content of the seawater samples ranged from 0.6 to 1.6 mg C/I. This study shows that results of high-temperature oxidation and photo-oxidation procedures differ by less than 5%, whereas results with persulphate oxidation are about 15% less than those obtained with the high-temperature oxidation. The relative merits of each of the oxidation techniques for the determination of organic matter in seawater are discussed.