塔里木盆地陆相烃源岩有机组分的分类及其岩石学特征

通过对塔里木盆地陆相烃源岩所作的详细有机岩石学研究，提出了适合该盆地的陆相烃源岩有机组分分类方案，并系统地阐述各有机组分的光性、成因及岩石学特性。     

浙江省东部土壤元素地球化学特征及意义

为了研究土壤和稻米元素地球化学分布特征及影响稻米中重金属质量分数的主要因素,对浙江省东部农田根系土-稻谷样品进行了采集和分析。结果表明：各研究区均有重金属元素质量分数高于区域地球化学背景值,尤其是温州南郊地区的Hg、台州泽国地区Cd、绍兴北郊地区的Hg,其质量分数分别是背景值的6倍、5倍及9倍;7个研究区中,只有嘉兴新胜地区的As质量分数超过背景值。其原因是这些地区工业化进程迅速,人为活动频繁,污染较严重。绍兴北郊、嘉兴新丰、嘉兴新胜和桐乡崇福地区稻米中As、Cd、Cr、Hg、Se和Pb质量分数均未超过标准限值。稻米对重金属元素的吸收富集主要受土壤有机质、pH、土壤阳离子交换量和黏粒组成等土壤理化性质的影响：土壤有机碳越丰富越有利于稻米对As、Cd、Cr和Ni的吸收;稻米对As、Cd、Mn和Ni的富集系数随着pH上升而下降;土壤阳离子交换量和黏粒组成与水稻As、Cu、Hg、Mn、Pb、Se和Zn的富集系数呈显著负相关。     

测井曲线在杭东勘查区煤炭普查煤岩层对比中的应用

杭东普查区煤层产状平缓,构造简单,但由于含煤地层为陆相沉积,煤层层数多、厚度、间距变化大,沉积岩相变化快、大范围内缺乏稳定的对比标志层,因此煤岩层对比是本区勘查需要重点解决的难题。通过对比杭东普查区与邻区200余孔的测井资料,分析煤岩层在各种测井曲线的异常特征与异常组合规律,确定了对煤岩层对比有重大意义的标志层,如延长组与上覆延安组的典型视电阻率异常分界;延安组在高视电阻率曲线上的“树杆”状凸起特征;安定组视电阻率曲线近直线的低值形态;4-1煤在视电阻率曲线上呈现出的“斜坡”状或“刀”状高异常,以及在自然伽玛曲线上的“凹坑”特征;侏罗系中统直罗组的高伽马异常,等等。这些典型特征保证了该区煤岩层对比可靠性,为提交优质地质勘查报告发挥了重要作用。     

Genetic model and exploration target area of geothermal resources in Hongtang Area,Xiamen, China

The geothermal resources in Fujian Province are mainly hydrothermal resources of medium-low temperature. To better understand the whole process and conditions of heat control in the middle and deep crust, this study focuses on the analysis of heat accumulation model in Hongtang Area of Xiamen, and the main conditions of the model such as faults and sags are explored and interpreted in detail by using gravity and wide-field electromagnetic methods. 4 main faults (F33, F2, F12 and HT-F1) and 10 secondary faults (HT-F2, HT-F3, HT-F4, HT-F5, HT-F6, HT-F7, HT-F8, HT-F9, HT-F10 and HT-F11) were inferred, and the distribution range of sags was delineated. The convective geothermal system is composed of four components: Heat source, geothermal reservoir, heat-conductive fault and heat retaining cover, which form a quaternary heat accumulation model. According to the model, the intersection of the main faults F12, HT-F1 and F33 can be delineated as the primary target area of geothermal exploration, while the intersection of the secondary faults (F12 and HT-F6; F12 and HT-F2; HT-F9, HT-F10 and F12; F12 and HT-F11; F33 and HT-F3; HT-F8 and HT-F3; HT-F2, HT-F10 and HT-F1) can be delineated as the secondary target area. Borehole DR01, which is located in the primary target area, shows that the water temperature increases from fast to slow in the depth range of 0–500 m, and stays at 36℃ below 500 m. The reliability of the heat accumulation model and the target area was tested via geothermal boreholes, which is of great significance to the exploitation and utilization of geothermal resources in Hongtang Area of Xiamen.     

不同氧化还原条件下铅锌矿尾砂中重金属元素活化迁移规律

以广西大厂镇鲁塘铅锌矿尾砂为研究对象,通过淋滤实验研究了不同氧化还原条件下尾砂中Cu、Cd、Zn、Pb和As等元素的活化和迁移规律。结果表明：经高浓度氧化、高浓度还原条件处理的尾矿表现为pH<7的酸性环境,经低浓度氧化环境条件处理的尾砂呈现pH>7的弱酸性至弱碱性环境;尾砂中Cu、Cd元素活化迁移受pH值的影响明显,即高浓度还原和高浓度氧化条件可以促进Cu和Cd元素的迁移,酸性条件对Cu和Cd元素的迁移起到促进作用;Zn与Cd元素存在竞争吸附关系,但二者仍有明显差别;Pb和As元素受到还原条件的影响,能有效促进Pb和As元素的释放迁移。在淋滤实验前期,铅锌矿的表面阻力较小,由于环境酸碱性的改变,初始尾砂对重金属元素的吸附位能发生变化,重金属元素初期迁移能力得到加强;淋滤后期,矿物颗粒表面由于发生氧化还原反应,促使颗粒表面的阻力增加,重金属元素的溶出量减少,迁移能力受到抑制。     

沧县隆起北部地区地热资源特征及开发潜力

【研究目的】地热资源特征研究及开发潜力分析是开发区域地热资源的重要依据。【研究方法】本文将前人研究成果与最新钻井资料相结合,通过对沧县隆起北部地区地热地质背景、热储分布、地温场特征、水化学资源类型等主要因素进行剖析,建立了该区的地热成藏模式。【研究结果】沧县隆起北部地区是在渤海湾伸展型沉积盆地高大地热流值背景下,由北部燕山裸露区基岩接受的大气降水作为近源补给水源,进入基岩的冷水在深层循环过程中受到深部热源加热增温,沿断裂破碎带和不整合面向上运移富集,形成的以传导型传热机制为主的地热系统。【结论】本区地热资源特点为热储类型多、盖层地温梯度高、补给速度快、资源量巨大。主要表现为：区内分布馆陶组砂岩热储,奥陶系、蓟县系雾迷山组岩溶热储三套主力热水储集层;地温场分布主要受基底构造形态控制,基岩凸起区的平均地温梯度为45℃/km;地下水类型随着埋深的增加由HCO₃-Na、HCO₃·SO₄-Na型水向成熟的Cl-Na型水过渡;本区内三套热储的可采地热资源量为1.67×10¹⁰GJ,折合标煤5.72×10⁸t,年可开采地热资源量可满足供暖面积2亿m²,若在采灌平衡的条件下,沧县隆起北部地区年可采地热资源量为7.06×10⁷GJ,折合标煤2.41×10⁶t,可满足供暖面积0.85亿m²,具有良好的地热市场开发前景。     

Study on Rationality of Large Diameter Pressure Relief Drilling Parameters Under Different Coal Seam Conditions

Geotechnical and Geological Engineering - To study the influence of changes in the coal seam mechanical characteristics at depth on the stress relief effect of a borehole, this paper established...     

我国城市规划中气候信息应用回顾与展望

城市规划中气候信息的应用经历了从早期的风玫瑰图利用到考虑风、温、湿、压等要素的气候适宜性分析以及目前关注城市通风环境、热环境以及污染敏感区的城市环境气候图技术的历程。气候信息获得的途径也从数量极为有限的基本气象观测站资料到空间加密的自动气象站资料、更精细的气象数值模式以及精细化地理信息技术的应用。同时,细化的技术导则和规范的建立以及不同行业间的联合发文有力推动了气候信息的实际应用。此外,研究展示了近年开展的伊犁、深圳、北京实际案例主要内容。最后,针对未来我国将根据大气环流特征和生态环境承载能力、走优化城镇空间布局和城镇规模结构的新型城镇化道路,从工作层面和技术层面给出了需要不断完善并深入研究的几个重点。     

The dissolution of synthetic Na-boltwoodite in sodium carbonate solutions

Uranyl silicates such as uranophane and Na-boltwoodite appear to control the solubility of uranium in certain contaminated sediments at the US Department of Energy Hanford site [Liu, C., Zachara, J.M., Qafoku, O., McKinley, J.P., Heald, S.M., Wang, Z. 2004. Dissolution of uranyl microprecipitates in subsurface sediments at Hanford Site, USA. Geochim. Cosmochim. Acta68, 4519-4537.]. Consequently, the solubility of synthetic Na-boltwoodite, Na(UO₂)(SiO₃OH) · 1.5H₂O, was determined over a wide range of bicarbonate concentrations, from circumneutral to alkaline pH, that are representative of porewater and groundwater compositions at the Hanford site and calcareous environments generally. Experiments were open to air. Results show that Na-boltwoodite dissolution was nearly congruent and its solubility and dissolution kinetics increased with increasing bicarbonate concentration and pH. A consistent set of solubility constants were determined from circumneutral pH (0 added bicarbonate) to alkaline pH (50 mM added bicarbonate). Average or 5.85 ± 0.0.26; using the Pitzer ion-interaction model or Davies equation, respectively. These values are close to the one determined by [Nguyen, S.N., Silva, R.J., Weed, H.C., Andrews, Jr., J.E., 1992. Standard Gibbs free energies of formation at the temperature 303.15 K of four uranyl silicates: soddyite, uranophane, sodium boltwoodite, and sodium weeksite. J. Chem. Thermodynamics24, 359-376.] under very different conditions (pH 4.5, Ar atmosphere).     

VTI介质中弹性波方程正演的一阶混合吸收边界

波动方程正演是研究地震波在地下介质中的传播机理以及提高地震资料采集、处理、解释精度和效果的重要工具,截断边界的处理是波动方程正演的重要研究内容。针对在地震数值模拟中常用的三种(吸收)边界处理方法存在的不足与问题,提出了适用于VTI介质中弹性波动方程正演的一阶混合吸收边界条件,并给出了该方法在过渡区域的线性叠加系数公式。数值模拟实验表明:相同条件下,VTI介质一阶混合吸收边界方法不仅在吸收效果方面优于常规的PML边界条件,而且在存储量和计算效率方面也具有较大优势。