Preparation and Measurement of Cassiterite for Sn Isotope Analysis

Increased interest in the fractionation of Sn isotopes has led to the development of several techniques for preparing cassiterite (SnO₂, the primary ore of Sn) for isotopic analysis. Two distinct methods have been applied in recent isotopic studies of cassiterite: (a) reduction to tin metal with potassium cyanide (KCN) at high temperature (800 °C), with subsequent dissolution in HCl, and (b) reduction to a Sn solution with hydriodic acid (HI) at low temperature (100 °C). This study compares the effectiveness and accuracy of these two methods and contributes additional methodological details. The KCN method consistently yielded more Sn (> 70% in comparison with < 5%), does not appear to fractionate Sn isotopes at high temperatures over a 2‐hour period and produced consistent Sn isotope values at flux mass ratios of ≥ 4:1 (flux to mineral) with a minimum reduction time of 40 min. By means of a distillation experiment, it was demonstrated that HI could volatilise Sn, explaining the consistently low yields by this method. Furthermore, the distillation generated Sn vapour, which is up to 0.38‰ per mass unit different from the starting material, the largest induced Sn fractionation reported to date. Accordingly, the HI method is not recommended for cassiterite preparation for Sn isotopic analysis.     

遥感影像变分Mask自适应匀光算法

针对Mask匀光法对低通滤波器及其尺寸参数依赖的问题,提出一种变分Mask自适应匀光算法。根据影像自身的先验信息,结合Mask数学模型构造变分能量函数,分别利用各向异性和各向同性全变分正则项约束理想影像和背景影像,采用分裂Bregman方法交替迭代求解,可同时获取最优化背景影像和理想影像。利用3幅光照不均匀的遥感影像进行实验并与3种不同滤波尺寸的Mask匀光法进行了比较,本文方法在目视效果和定量评价指标上均呈现明显的优势,在消除亮度不均的同时能够保持影像的纹理和细节信息。     

CNS+GNSS+INS船载高精度实时定位定姿算法改进研究

天文导航(CNS)、卫星导航(GNSS)和惯性导航(INS) 3种系统组合可提供高精度的定位定姿结果。实际工程中因INS长时间误差累积,以及系统硬件传输存在不可忽略的时间延迟,导致INS提供给CNS的预报粗姿态误差较大,恶劣海况下难以保障快速搜星,造成天文导航可靠性下降、姿态测量精度较低的问题。为此,本文提出了一种CNS+GNSS+INS高精度信息融合实时定位定姿框架,引入了等角速度外推措施,有效地解决了惯导信息延迟问题。通过高精度转台模拟恶劣海况下载体大角速度摇摆,验证了本文提出的改进算法的有效性。试验结果表明,该算法架构简单,性能可靠,显著提高了恶劣环境下星敏感器的快速、准确搜星能力,保障了三组合姿态测量的精度和可用性。     

豫北“21·7”极端暴雨过程特征及成因分析

利用探空、地面自动站、多普勒雷达等观测资料及ERA5再分析产品,对2021年7月17—22日豫北地区的极端暴雨过程进行分析。结果表明,极端暴雨过程具有强降水持续时间长、降水强度极端及地形影响明显等特征。极端暴雨过程发生于稳定的大尺度天气形势下,在日本海高压西伸及台风烟花(2106号)、查帕卡(2107号)西北行背景下,黄淮低涡外围加强北上的东南急流/偏南急流为强降水的发生提供了异常充足的水汽、能量条件,对流层中低层暖湿平流强迫、叠加地形影响的强动力辐合抬升作用及低空弱冷空气扩散南下是形成强降水的重要条件,而大气“强-弱-强-弱”的对流不稳定层结特征转化说明强降水过程中存在着两种互补的物理机制。不同阶段极端短时强降水(小时降水量≥50 mm)对流系统的形态结构和发展演变特征不同,但从雷达回波的垂直分布来看,系统均具有“低质心”特征,质心强度≥55 dBz且≥50 dBz强回波垂直伸展至5～8 km、持续时间1 h以上。强降水对流系统在太行山前30 km左右范围内的后向发展特征明显,一方面与地面西行偏东风/东北风在太行山绕流作用下形成的地形辐合线不断南伸有关,另一方面也与强降水冷池效应促使...     

Mean flow-transient perturbation interaction in the Southern Hemisphere: a simulation using a variable-resolution GCM

The ability of an atmospheric general circulation model to reproduce fundamental features of the wintertime extratropical Southern Hemisphere (SH) circulation is evaluated with emphasis on the daily variability of the SH mean flow and the mean flow-transient perturbations interaction. Two 10-year simulations using a new version of the LMDZ GCM with a stretched grid scheme centered at 45 °S and forced by climatological SST are performed: a high (144Ꮡ) and low (64Ꭹ) horizontal resolution runs. The performance of both simulations was determined by comparing several simulated fields (zonal wind, temperature, kinetic energy, transient eddy momentum and heat fluxes, Eliassen-Palm fluxes, Eady growth rate and baroclinic conversion term) against the European Centre for Medium Range Weather Forecast reanalyses (ERA). High and low-resolution simulations are similar in many respects; in particular, both experiments reproduce the main patterns of the southern extratropical large-scale circulation satisfactorily. Increasing resolution does not improve universally some spurious aspects of the low resolution simulation (e.g. the cold bias in the high polar troposphere, the debilitated subtropical jet, the low baroclinic conversion rate). Those aspects present little sensitivity to the model resolution. The interaction between transient eddies and zonal mean flow are examined. The low-resolution experiment is able to qualitatively represent the acceleration/deceleration of the mean flow by transient perturbations, south/north of 30 °S with an accuracy similar to that of the high-resolution experiment. Although both experiments represent the baroclinic structure of the mean flow satisfactorily, the model underestimates some transient properties due to the underestimation of the baroclinic conversion term in middle latitudes. Such misrepresentation does not improve with increasing resolution and is related to the relatively weak meridional temperature gradient and the inadequate geographical distribution of the eddy heat fluxes. In particular, the eddy kinetic energy is always underestimated. Eddy kinetic energy does not improve convincingly with increasing resolution, suggesting that the adequate representation of the storm tracks is highly influenced by the physical parametrizations.     

Performance of a multi-RCM ensemble for South Eastern South America

The ability of four regional climate models to reproduce the present-day South American climate is examined with emphasis on La Plata Basin. Models were integrated for the period 1991–2000 with initial and lateral boundary conditions from ERA-40 Reanalysis. The ensemble sea level pressure, maximum and minimum temperatures and precipitation are evaluated in terms of seasonal means and extreme indices based on a percentile approach. Dispersion among the individual models and uncertainties when comparing the ensemble mean with different climatologies are also discussed. The ensemble mean is warmer than the observations in South Eastern South America (SESA), especially for minimum winter temperatures with errors increasing in magnitude towards the tails of the distributions. The ensemble mean reproduces the broad spatial pattern of precipitation, but overestimates the convective precipitation in the tropics and the orographic precipitation along the Andes and over the Brazilian Highlands, and underestimates the precipitation near the monsoon core region. The models overestimate the number of wet days and underestimate the daily intensity of rainfall for both seasons suggesting a premature triggering of convection. The skill of models to simulate the intensity of convective precipitation in summer in SESA and the variability associated with heavy precipitation events (the upper quartile daily precipitation) is far from satisfactory. Owing to the sparseness of the observing network, ensemble and observations uncertainties in seasonal means are comparable for some regions and seasons.     

动载作用下混凝土细观损伤的CT图像分割和灰度共生矩阵特征值研究

动载作用下混凝土随应力变化的系列CT图像完整地记录了混凝土内部破损过程,在CT图像中能直接观察到细观裂纹时混凝土往往已发生宏观破坏,挖掘混凝土材料损伤的细观信息是混凝土细观力学分析的核心.本文基于混凝土单轴动态压缩CT试验,获得不同应力阶段的横断面CT图像,分别应用图像分割技术和灰度共生矩阵法提取孔隙率和4个特征值,研...     

地震行业地面骨干网与应急卫星通信网互联路由设计方案的探讨

本文介绍了地震行业地面骨干网与应急卫星通信网的运行现状及互联存在的路由问题,讨论了实现两网互联的路由设计目标和策略,根据OSPF协议与BGP协议的特点和适用范围,提出了统一互联的接入方法,以及联合使用OSPF和BGP协议解决两网互联路由问题的具体方案,经网络仿真平台测试证明,该方案切实可行,效果良好。     

On the inclusion of ground-based gravity measurements to the calibration process of a global rainfall-discharge reservoir model: case of the Durzon karst system (Larzac, southern France)

This work examines the relevance of the inclusion of ground-based gravity data in the calibration process of a global rainfall-discharge reservoir model. The analysis is performed for the Durzon karst system (Larzac, France). The first part of the study focuses on the hydrological interpretation of the ground-based gravity measurements. The second part of the study investigates further the information content of the gravity data with respect to water storage dynamics modelling. The gravity-derived information is found unable to either reduce equifinality of the single-objective, discharge-based model calibration process or enhance model performance through assimilation.     

湖南仁里稀有金属矿田206号锂辉石伟晶岩脉地球化学特征及成矿时代

湖南仁里稀有金属矿田是中国近年来新发现的一处重要的花岗伟晶岩型铌、钽、锂等稀有金属矿产地,文章针对矿田含锂伟晶岩地球化学特征、成矿时代及其与花岗岩的关系,选取传梓源锂铌钽矿床内规模最大的206号锂辉石伟晶岩脉开展地球化学和白云母Ar-Ar定年工作,并与区内其他伟晶岩、花岗岩的地球化学特征、成岩时代对比分析.传梓源206号锂辉石伟晶岩属高分异稀有金属伟晶岩,形成时代为(135.4±1.4)Ma,岩石地球化学表现为高硅、高铝、低钙、相对富碱、钙碱性及过铝质特征;稀土元素总量很低,以轻稀土元素为主;微量元素富集Cs、Rb、U、Ta、Nb、Zr、Hf,相对亏损Ba、Ti,Zr/Hf、Nb/Ta比值低且集中.幕阜山地区稀有金属成矿可分为2期:第1期稀有金属成矿时代约145 Ma,与燕山早期岩浆活动有关;第2期稀有金属成矿时代135～125 Ma,为主成矿期,该期稀有金属伟晶岩与燕山晚期的二云母二长花岗岩存在成因联系,两者为同源岩浆连续结晶分异过程中不同阶段的产物.稀有金属富集成矿经历了岩浆-热液两阶段作用,Be、Nb、Ta、Li、Rb、Cs等稀有元素的富集多发生于岩浆结晶分异晚期,热液作用使Ta、Li、Rb、Cs再次富集.