Groundwater chemistry and mass transfers in the Independence aquifer,central Mexico,by using multivariate statistics and mass-balance models

In the light of progressive depletion of groundwater reservoir and water quality deterioration of the Independence aquifer, an investigation on chemical data of dissolved major and minor constituents in 246 recent groundwater samples was performed. The main objective was the detection of processes responsible for the geochemical evolution and mineralization throughout the area. Multivariate techniques revealed different sources of solutes (a) dissolution of calcium and magnesium carbonate minerals, (b) weathering of acid volcanic minerals, (c) alteration of manganese containing alkaline silicates, (d) leaching of halite deposits of meteoric origin, (e) contamination from agricultural and urban wastewaters, and (f) evaporative effects due to intensive irrigation. Although nitrate contamination is associated with pollution from intensive cultivated areas, natural contamination plays an important role in the study area. The investigation reveals that weathering of acid volcanic rocks (rhyolite) and oxidation of arsenic bearing sulfide minerals are the responsible processes for high fluorine (up to 16 mg/l) and arsenic (up to 0.12 mg/l) contents, respectively, exceeding the Mexican maximum admissible concentration for drinking water. Except for kaolinite, all recharge processes are dissolution oriented (CO₂, calcite, dolomite, K-feldspar, plagioclase). Silicate precipitation (amorphous silica and chalcedony) is of growing importance in discharge zones. Cation exchange is not an important issue in the whole study area.     

Surface gravitational field and topography changes induced by the Earth’s fluid core motions

Using a Love number formalism, the elastic deformations of the mantle and the mass redistribution gravitational potential within the Earth induced by the fluid pressure acting at the core–mantle boundary (CMB) are computed. This pressure field changes at a decadal time scale and may be estimated from observations of the surface magnetic field and its secular variation. First, using a spherical harmonic expansion, the poloidal and toroidal part of the fluid velocity field at the CMB for the last 40 years is computed, under the hypothesis of tangential geostrophy. Then the associated geostrophic pressure, whose order of magnitude is about 1000 Pa, is computed. The surface topography induced by this pressure field is computed using Love numbers, and is a few millimetres. The mass redistribution gravitational potential induced by these deformations and, in particular, the zonal components of the related surface gravitational potential perturbation (J₂, J₃ and J₄ coefficients), are calculated. Overall perturbations for the J₂ coefficient of about 10^–10, for J₃ of about 10^–11 and for J₄ are found of about 0.3×10^–11. Finally, these theoretical results are compared with recent observations of the decadal variation of J₂ from satellite laser ranging. Results concerning J₂ can be described as follows: first, they are one order of magnitude too small to explain the observed decadal variation of J₂ and, second, they show a significant linear trend over the last 40 years, whose rate of decrease amounts to 7% of the observed value.     

Détermination indirecte des limites d'Atterberg par gravimétrie dynamique

This study presents a new method for Atterberg limits measurements using dynamic drying. Indeed, for some polluted clays, or clay mixtures, classical methods cannot be used. The principle of liquid $(W_{\mathrm{L}})$ and plasticity $(W_{\mathrm{P}})$ limits determination by this method is presented. Experimental values for classical clays are close to those obtained with Casagrande's methods, allowing for larger physical mud characterisation. To cite this article: C. Proust et al., C. R. Geoscience 336 (2004).     

Mental maps and travel behaviour: meanings and models

In this paper, the “mental map” concept is positioned with regard to individual travel behaviour to start with. Based on Ogden and Richards’ triangle of meaning (The meaning of meaning: a study of the influence of language upon thought and of the science of symbolism. International library of psychology, philosophy and scientific method. Routledge and Kegan Paul, London, 1966) distinct thoughts, referents and symbols originating from different scientific disciplines are identified and explained in order to clear up the notion’s fuzziness. Next, the use of this concept in two major areas of research relevant to travel demand modelling is indicated and discussed in detail: spatial cognition and decision-making. The relevance of these constructs to understand and model individual travel behaviour is explained and current research efforts to implement these concepts in travel demand models are addressed. Furthermore, these mental map notions are specified in two types of computational models, i.e. a Bayesian Inference Network (BIN) and a Fuzzy Cognitive Map (FCM). Both models are explained, and a numerical and a real-life example are provided. Both approaches yield a detailed quantitative representation of the mental map of decision-making problems in travel behaviour.     

The impact of extreme heat on morbidity in Milwaukee, Wisconsin

Given predictions of increased intensity and frequency of heat waves, it is important to study the effect of high temperatures on human mortality and morbidity. Many studies focus on heat wave-related mortality; however, heat-related morbidity is often overlooked. The goals of this study are to examine the historical observed relationship between temperature and morbidity (illness), and explore the extent to which observed historical relationships could be used to generate future projections of morbidity under climate change. We collected meteorological, air pollution, and hospital admissions data in Milwaukee, Wisconsin, for the years 1989–2005, and employed a generalized additive model (GAM) to quantify the relationship between morbidity (as measured by hospital admissions) and high temperatures with adjustment for the effects of potential confounders. We also estimated temperature threshold values for different causes of hospital admissions and then quantified the associated percent increase of admissions per degree above the threshold. Finally, the future impact of higher temperatures on admissions for the years 2059–2075 was examined. Our results show that five causes of admission (endocrine, genitourinary, renal, accidental, and self-harm) and three age groups (15–64, 75–84, >85 years) were affected by high temperatures. Future projections indicate a larger number of days above the current temperature threshold leading to an increase in admissions. Our results indicate that climate change may increase heat-related hospital admissions in the US urban mid-West and that health systems should include heat wave planning.     

A new design of the LAPS land surface scheme for use over and through heterogeneous and non-heterogeneous surfaces: Numerical simulations and tests

Numerical simulations and tests with the recently redesigned land–air parameterization scheme (LAPS) are presented. In all experiments, supported either by one-point micrometeorological, 1D or 3D simulations, the attention has been directed to: (1) comparison of simulation outputs, expressing the energy transfer over and through heterogeneous and non-heterogeneous surfaces, versus observations and (2) analysis of uncertainties occurring in the solution of the energy balance equation at the land–air interface. To check the proposed method for aggregation of albedo, “propagating hole” sensitivity tests with LAPS over a sandstone rock grid cell have been performed with the forcing meteorological data for July 17, 1999 in Baxter site, Philadelphia (USA). Micrometeorological and biophysical measurements from the surface experiments conducted over crops and apple orchard in Serbia, Poland, Austria and France were used to test the operation of LAPS in calculating surface fluxes and canopy environment temperatures within and above plant covers of different densities. In addition, sensitivity tests with single canopy covers over the Central Europe region and comparison against the observations taken from SYNOP data using 3D simulations were made. Validation of LAPS performances over a solid surface has been done by comparison of 2 m air temperature observations against 5-day simulations over the Sahara Desert rocky ground using 3D model. To examine how realistically the LAPS simulates surface processes over a heterogeneous surface, we compared the air temperature measured at 2 m and that predicted by the 1D model with the LAPS as the surface scheme. Finally, the scheme behaviour over urban surface was tested by runs over different parts of a hypothetical urban area. The corresponding 1D simulations were carried out with an imposed meteorological dataset collected during HAPEX-MOBILHY experiment at Caumont (France). The quantities predicted by the LAPS compare well with the observations and the various subcomponents of the scheme appear to operate realistically.     

Titan's surface at 2.2-cm wavelength imaged by the Cassini RADAR radiometer: Calibration and first results

The first comprehensive calibration and mapping of the thermal microwave emission from Titan's surface is reported based on radiometric data obtained at 2.2-cm wavelength by the passive radiometer included in the Cassini Radar instrument. The data reported were accumulated from 69 separate observational segments in Titan passes from Ta (October 2004) through T30 (May 2007) and include emission from 94% of Titan's surface. They are diverse in the key observing parameters of emission angle, polarization, and spatial resolution, and their reduction into calibrated global mosaic maps involved several steps. Analysis of the polarimetry obtained at low to moderate resolution (50+ km) enabled integration of the radiometry into a single mosaic of the equivalent brightness temperature at normal incidence with a relative precision of about 1 K. The Huygens probe measurement of Titan's surface temperature and radiometry obtained on Titan's dune fields allowed us to infer an absolute calibration estimated to be accurate to a level approaching 1 K. The results provide evidence for a surface that is complex and varied on large scales. The radiometry primarily constrains physical properties of the surface, where we see strong evidence for subsurface (volume) scattering as a dominant mechanism that determines the emissivity, with the possibility of a fluffy or graded-density surface layer in many regions. The results are consistent with, but not necessarily definitive of a surface composition resulting from the slow deposition and processing of organic compounds from the atmosphere.     

Martian gravity field model and its time variations from MGS and Odyssey data

We present results of several years of research and data processing aimed at modelling the Mars gravity field and its longest wavelength time variations. The new solution includes tracking data from Mars Global Surveyor (MGS) from 1998 to 2006 (end of mission) and from Mars Odyssey from 2002 to the spring of 2008; this is the longest analyzed data set from these two orbiter missions as compared to previous works. The new model has been obtained by a team working in Europe, independently from the works of groups at NASA Jet Propulsion Laboratory (JPL) and Goddard Space Flight Center (GSFC), also with totally independent software. Observations consist in two and three-way Doppler measurements (also one way for MGS), and range tracking data collected by the Deep Space Network and have been processed in 4 day arcs, taking into account all disturbing forces of gravitational and non-gravitational origins; for each arc the state vector, drag and solar pressure model multiplying factors, and angular momentum dump parameters are adjusted. The static field (MGGM08A) is represented in spherical harmonics up to degree and order 95 and is very close to previously published models (in terms of spectral components and also over specific features); correlations with the global Mars topography are established and apparent depths of compensation by degree are derived. Lumped zonal harmonics of degree two and three are solved for every 10 days, exhibiting variations in line with previous results (including authors’ ones); the work also shows the difficulty of finding clean signatures (annual and semi-annual) for the zonal coefficient of second degree. The k₂ Love number is also derived from the ensemble of data, as well as from subsets of them; values between 0.110 and 0.130 are found, which are consistent with the existence of a Martian fluid core of significant radius.     

Lander radioscience for obtaining the rotation and orientation of Mars

The paper presents the concept, the objectives, the approach used, and the expected performances and accuracies of a radioscience experiment based on a radio link between the Earth and the surface of Mars. This experiment involves radioscience equipment installed on a lander at the surface of Mars. The experiment with the generic name lander radioscience (LaRa) consists of an X-band transponder that has been designed to obtain, over at least one Martian year, two-way Doppler measurements from the radio link between the ExoMars lander and the Earth (ExoMars is an ESA mission to Mars due to launch in 2013). These Doppler measurements will be used to obtain Mars’ orientation in space and rotation (precession and nutations, and length-of-day variations). More specifically, the relative position of the lander on the surface of Mars with respect to the Earth ground stations allows reconstructing Mars’ time varying orientation and rotation in space.Precession will be determined with an accuracy better by a factor of 4 (better than the 0.1% level) with respect to the present-day accuracy after only a few months at the Martian surface. This precession determination will, in turn, improve the determination of the moment of inertia of the whole planet (mantle plus core) and the radius of the core: for a specific interior composition or even for a range of possible compositions, the core radius is expected to be determined with a precision decreasing to a few tens of kilometers.A fairly precise measurement of variations in the orientation of Mars’ spin axis will enable, in addition to the determination of the moment of inertia of the core, an even better determination of the size of the core via the core resonance in the nutation amplitudes. When the core is liquid, the free core nutation (FCN) resonance induces a change in the nutation amplitudes, with respect to their values for a solid planet, at the percent level in the large semi-annual prograde nutation amplitude and even more (a few percent, a few tens of percent or more, depending on the FCN period) for the retrograde ter-annual nutation amplitude. The resonance amplification depends on the size, moment of inertia, and flattening of the core. For a large core, the amplification can be very large, ensuring the detection of the FCN, and determination of the core moment of inertia.The measurement of variations in Mars’ rotation also determines variations of the angular momentum due to seasonal mass transfer between the atmosphere and ice caps. Observations even for a short period of 180 days at the surface of Mars will decrease the uncertainty by a factor of two with respect to the present knowledge of these quantities (at the 10% level).The ultimate objectives of the proposed experiment are to obtain information on Mars’ interior and on the sublimation/condensation of CO₂ in Mars’ atmosphere. Improved knowledge of the interior will help us to better understand the formation and evolution of Mars. Improved knowledge of the CO₂ sublimation/condensation cycle will enable better understanding of the circulation and dynamics of Mars’ atmosphere.