镉—5—Br—PADAP—溴化十六烷基三甲基铵—十八醇聚氧乙烯(20)醚显色体系的研究及应用

本文研究了镉-5-Br-PADAP-溴化十六烷基三甲基铵-peregalo显色体系的光谱特征,显色条件,络合物的组成、干扰及其消除。实验证明该法灵敏度高,ε=1.3×10~5l·mol~(-1)·cm~(-1)。选择性较好,显色酸度范围较宽pH=8.0-9.5,络合物最大吸收波长为560nm,镉在0-10μg/25ml的含量范围内服从比尔定律。经标准水样、工业废水及生活用水验证,不经分离可测定水中PPb级的微量镉。     

~(218)Po法寻找隐伏铀矿体初见成效

本文介绍了一种寻找隐伏铀矿体的快速测氡方法,即~(218)Po法。作者叙述了该法的工作原理、特点以及找矿效果,并阐述了~(218)Po法寻找隐伏铀矿体的可能性。最后着重叙述了~(218)Po法测量结果的解释方法。通过野外试验,作者认为:~(218)Po法不仅可以寻找隐伏铀矿体,而且能够定量预测盲矿体的埋藏深度与规模。     

Origin and distribution of tonsteins in late permian coal seams of Southwestern China

We have surveyed the areal and stratigraphic distribution of tonsteins in Late Permian coalfields of southwestern China over an area of several hundred thousand square kilometers. We studied the relationship between tonstein distribution and sedimentary environment. Based on mineralogical and petrographic data, we have concluded that these tonsteins originated as air-fall volcanic ashes. Following accumulation in the peat swamps, in situ alteration of the vitric and lithic components took place under acidic conditions, leading to the formation of kaolinite.Based on petrologic, mineralogic, and chemical analytical data, we have determined that the application of mineralogic and geochemical criteria for tonsteins may be useful in correlating coal beds, predicting coal qualities and reconstructing related sedimentary paleoenvironmental conditions.     

Simple-Shear Rheological Properties of Shallow Clay Layer in Shanghai

This paper presets the results of simple-shear rheological tests for the shallow clay layer in Shanghai and the rheological parameters of this clay layer, such as shear parameter, viscosity and long-term strength etc. , by using the obtained relationship among stress, strain and time. The test results show that with certain density and water content of the clay and shear stress less than the yield value, the relationship between shear stress and shear strain for the same shear duration can be obtained by superposition theorem. Because of its linearity, likewise, the relationship between long-term shear flow rate and shear stress also hold true thus, from the linear portion of the curves mentioned above the shear modulus G and viscosity η can be obtained . however , when shear stress is beyond a certain yield value, the curve becomes non-linear. This yield value can be regarded as long-term strength of the soil . In rheological experiments these parameters are all functions of time.     

向量场的经验正交展开及其应用

本文提出了一种向量场经验正交展开的方法。我们对N×T个离散点上的向量所构成的一个N×T维矩阵,设法寻找一组称为经验正交函数的向量,使其中每一个分量都在均方意义下最接近矩阵的每一列。这组向量可以从特征方程确定。对于有N列元素的矩阵(注意每一个元素都是一个向量),有不少于N个经验正交函数分量。用这些分量所作向量场的正交展开级数收敛很快。给出的展开实际例子说明:向量场经验正交展开,可以比一般标量场经验正交展开,取得更好的效果。     

Sorption of radioactive contaminants by sediment from the Kara Sea

The purpose of this study is to quantify some of the parameters needed to perform near-field modelling of sites in the Kara Sea that were impacted by the disposal of radioactive waste. The parameters of interest are: the distribution coefficients (Kd) for several important radionuclides, the mineralogy of the sediment, and the relationship of Kd to liquid-to-solid ratio. Sediment from the Kara Sea (location: 73 degrees 00'N, 58 degrees 00'E) was sampled from a depth of 287 m on August 23/24, 1992. Analysis of the material included mineralogy, grain size and total organic carbon (TOC). Uptake kinetics were determined for 85Sr, 137Cs, 241Am, 99Tc, 1251, 232U and 210Pb and distribution coefficients (Kd) were determined for these radionuclides using batch type experiments. Sorption isotherms, developed for 137Cs, 85Sr and 99Tc, were linear in each case. Increasing the liquid-to-solid ratio strongly increased uptake of 137Cs and moderately increased uptake of 99Tc. Analysis for anthropogenic radionuclides indicated the presence only of 239/240Pu in the sediment with the highest activity (at the top section of the core) being 0.420 Bq kg(-1). Other anthropogenic radionuclides were below detection limits.     

桂林暴雨天气的多普勒雷达径向速度分析与应用

利用桂林新一带天气雷达径向速度产品资料对2004年发生在桂林的强暴雨过程及其暴雨个例的径向速度平面位置显示产品（PPI）特征的多样性进行分析发现，利用径向速度变化可判断中尺度对流的发展，可对桂林暴雨提前做出预报。     

强震地面运动的超随机特性研究

简述了几种常用的地震动平稳随机模型，这几种地震动平稳随机模型的功率谱是一组光滑的函数，相应的自相关函数基本上是指数衰减的振荡函数，且很快衰减到零；但是真实地震动的归一化自相关函数则有一较显著的随机噪声项，这个随机噪声的幅值为0．15左右，这就是本文中所说的超随机特性。目前常用的地震动平稳随机模型没有考虑这个随机噪声项及其对结构反应的影响。本文将真实地震动的自相关函数分解为一确定性函数和一随机噪声的叠加，并对自相关函数中的噪声部分进行了分析，得出两条重要性质。本文的研究结果表明地震动加速度时程的平方和(SS)比峰值加速度(PGA)更好地量度了地震地面运动强度。由于归一化自相关函数的随机噪声部分所对应的功率谱的随机波动成分对频率的积分为零，即归一化自相关函数的噪声部分对地震动总功率或平方和的贡献为零，因此自相关函数的随机噪声项对地震动的幅值影响不大，但自相关函数的随机噪声项明显改变了地震动功率谱在频域上的分布特征，因此会对结构反应产生一定的影响。由于篇幅所限详细内容将在下一篇文章中作进一步探讨。     

考虑高振型影响的结构层间位移能力谱分析方法

工程界普遍采用的能力谱分析方法是建立在结构单自由度简化假设基础上，利用结构基本振型来进行能力分析。虽然此简化假设可以为工程界提供一种简便的分析方法，但从其分析效果来看，简化方法并不能很好地反映结构真实地震反应。高振型对结构局部变形的影响在分析结构动力反应特性中是很重要的因素，不应忽略掉。基于上述对现有能力谱分析方法不足之处的考虑，从提高结构能力谱分析方法的准确性出发，本文在Chopra能力谱分析方法的基础之上，根据我国振型分解反应谱思想，在能力谱分析方法中引入了结构高振型的影响分析，并提出了考虑结构高振型影响的结构层间位移能力谱分析方法的一般步骤。通过平面框架结构体系的算例分析，说明上述推荐方法在改进能力谱分析精度上的有效性。