地质样品中微量金银的在线分离富集方法

提出用ＶＳ－Ⅱ型强碱性阴离子交换纤维定量富集、硫脲解脱，流动注射在线分离富集—火焰原子吸收光谱法测定地质样品中痕量金银的分析方法。该方法检出限低，金为１．４μｇ／ｍＬ，银为０．３５μｇ／ｍＬ，相对标准偏差均小于２％，采样频率为１２０次／ｈ，用于地质样品中痕量金银的直接测定，结果令人满意。     

地脉动测试技术若干问题的讨论

讨论了地脉动的测试技术以及测试工作中应该重视而且容易被忽视的问题 ,并就地脉动幅值域和频率域特性参数提出不同的看法     

用二维冰雹云模式预报桂西北地区降雹

建立了二维准弹性对流云模式，利用其对百色、河池两地区1971～1998年期间的冰雹天气进行事后模拟，结果表明该模式对桂西北地区冰雹天气具有一定的预报能力。     

近50年中国地面气候变化基本特征

采用国家基准气候站和基本气象站的地面资料,系统地分析了中国大陆地区1951年以来近地表主要气候要素演化的时间和空间特征。结果表明,中国近50 a来年平均地表气温变暖幅度约为1.1℃,增温速率接近0.22℃/(10 a),比全球或半球同期平均增温速率明显偏高。地表气温增暖主要发生在最近的20余年,其季节和空间特征与前人分析结论基本一致。降水量变化趋势对所取时间段和区域范围敏感。1951年以来全国平均降水量变化趋势不明显,但1956年以来略有增加。降水变化的空间特征明显而相对稳定,东北北部、包括长江中下游的东南部地区和西部广大地区降水增加,而华北地区以及东北东南部和西北东部地区降水明显减少。分析还发现,近50a来全国平均的日照时数、平均风速、水面蒸发等气候要素均呈显著下降趋势,但积雪地带的最大积雪深度却有所增加。中国日照时间和水面蒸发量变化的空间特征很相似,减少最明显的地区均发生在华北和华东,新疆次之。影响中国年代以上尺度气候变化的因子错综复杂,人类活动引起的大气中温室气体浓度增高可能在一定程度上影响了中国近50 a来的气候,但考虑到尚存的不确定性,目前仍不能给出明确结论。中国东部大部分地区日照时间和水面蒸发量减少可能均起源于人为排放的气溶胶影响,平均风速减弱也有利于水面蒸发量下降,而在西部地区云量和降水量的变化可能更重要。     

Alteration of hydrological processes and streamflow with juniper (Juniperus virginiana) encroachment in a mesic grassland catchment

To understand the effect of woody plant encroachment on hydrological processes of mesic grasslands, we quantified infiltration capacity in situ, the temporal changes in soil water storage, and streamflow of a grassland catchment and a catchment heavily encroached by juniper (Juniperus virginiana, eastern redcedar) in previously cultivated, non‐karst substrate grasslands in north‐central Oklahoma for 3 years. The initial and steady‐state infiltration rates under the juniper canopy were nearly triple to that of the grassland catchment and were intermediate in the intercanopy spaces within the encroached catchment. Soil water content and soil water storage on the encroached catchment were generally lower than on the grassland catchment, especially when preceding the seasons of peak rainfall in spring and fall. Frequency and magnitude of streamflow events were reduced in the encroached catchment. Annual runoff coefficients for the encroached catchment averaged 2.1%, in contrast to 10.6% for the grassland catchment. Annual streamflow duration ranged from 80 to 250 h for the encroached catchment compared with 600 to 800 h for the grassland catchment. Our results showed that the encroachment of juniper into previously cultivated mesic grasslands fundamentally alters catchment hydrological function. Rapid transformation of mesic grassland to a woodland state with juniper encroachment, if not confined, has the potential to drastically reduce soil water, streamflow and flow duration of ephemeral streams in the Southern Great Plains. Copyright © 2013 John Wiley & Sons, Ltd.     

Solar-, monsoon- and Kuroshio-influenced thermocline depth and sea surface salinity in the southern Okinawa Trough during the past 17,300 years

Factors influencing millennial-scale variability in the thermocline depth (vertical mixing) and sea surface salinity (SSS) of the southern Okinawa Trough (OT) during the past 17,300 years were investigated based on foraminifer oxygen isotope records of the surface dweller Globigerinoides ruber sensu stricto and the thermocline dweller Pulleniatina obliquiloculata in the AMS ¹⁴C dated OKT-3 core. The thermocline depth is influenced by surface thermal buoyancy (heat) flux, in turn controlled by the annual mean insolation at 30°N and the strength of the East Asian winter monsoon (EAWM). Strong insolation and weak EAWM tend to increase buoyancy gain (decrease buoyancy loss), corresponding to shallow thermocline depths, and vice versa. Regional SSS is influenced by the global ice volume, the Kuroshio Current (KC), and vertical mixing. A deep thermocline coincides with a high SSS because strong vertical mixing brings more, saltier subsurface KC water to the surface, and vice versa. Local SSS (excluding the global ice volume effect) became lower in the northern OT than in the southern OT after ~9.2 ka, implying that Changjiang diluted water had stronger influence in the northern sector. SSS show no major changes during the Bølling/Allerød and Younger Dryas events, probably because the KC disturbed the North Atlantic signals. This argues against earlier interpretations of sea surface temperature records of this core. Wavelet and spectral analyses of the Δδ¹⁸O_P-G (δ¹⁸O of P. obliquiloculata minus G. ruber s.s.) and δ¹⁸O_local records display 1,540-, 1,480-, 1,050-, 860-, 640-, and 630-year periods. These are consistent with published evidence of a pervasive periodicity of 1,500 years in global climate as well as EAWM and KC signatures, and a fundamental solar periodicity of 1,000 years and intermediary derived periodicity of 700 years.     

Hydrothermal Fluid Sources of the Fengjia Barite–fluorite Deposit in Southeast Sichuan,China: Evidence from Fluid Inclusions and Hydrogen and Oxygen Isotopes

The Fengjia barite–fluorite deposit in southeast Sichuan is a stratabound ore deposit which occurs mainly in Lower Ordovician carbonate rocks. Here we present results from fluid inclusion and oxygen and hydrogen isotope studies to determine the nature and origin of the hydrothermal fluids that generated the deposit. The temperature of the ore‐forming fluid shows a range of 86 to 302 °C. Our detailed microthermometric data show that the temperature during mineralization of the fluorite and barite in the early ore‐forming stage was higher than that during the formation of the calcite in the late ore‐forming stage. The salinity varied substantially from 0.18% to 21.19% NaCl eqv., whereas the density was around 1.00 g/cm³. The fluid composition was mainly H₂O (>91.33%), followed by CO₂, CH₄ and traces of C₂H₆, CO, Ar, and H₂S. The dominant cation was Na⁺ and the dominant anion Cl^‐, followed by Ca²⁺, SO₄^2‐, K⁺, and Mg²⁺, indicating a mid–low‐temperature, mid‐low‐salinity, low‐density NaCl–H₂O system. Our results demonstrate that the temperature decreased during the ore‐forming process and the fluid system changed from a closed reducing environment to an open oxidizing environment. The hydrogen and oxygen isotope data demonstrate that the hydrothermal fluids in the study area had multiple sources, primarily formation water, as well as meteoric water and metamorphic water. Combined with the geological setting and mineralization features we infer that the stratabound barite–fluorite deposits originated from mid–low‐temperature hydrothermal fluids and formed vein filling in the fault zone.