壳幔混染作用——下扬子区早中生代玄武岩同位素地质特征

下扬子区中生代（231Ma）玄武质火山岩全岩εNd（t）值-8.62～1.92,87Sr/86Sr 值0.7074～0.7179，206Pb/204Pb值为17.786～18.323。岩石中含有前寒武纪捕虏晶锆石。研究表明玄武质岩石可能是由亏损地幔与元古宙地壳岩石混染作用的结果。     

扬子地台钾镁煌斑岩 Nd、Sr、Pb 同位素特征

扬子地台周缘钾镁煌斑岩 Nd、Sr同位素特征介于南非Ⅰ、Ⅱ型金伯利岩和西澳与北美钾镁煌斑岩两种变化趋势之间，不同岩区间同位素组成差异反映地台周边构造性质不同，Pb同位素特征表明晚太古代地幔岩石圈具U亏损特征。     

辽西中生代火山岩岩浆成因——稀土元素配分及同位素定量模式

本文通过对辽西及邻区中生代盆地火山岩稀土元素配分特征的研究及模拟运算，探讨了其岩浆成因及过程。结果显示南北岩区岩浆成因不同，南岩区岩源为MORB地幔和长期富集型幔熔融混合而成，北岩区为MORB和近期亏损型地幔熔融混合而成。     

草簇状石墨烯片限域Pd纳米粒子及其催化应用(英文)

通过氨基离子液体改性石墨烯,并将其固载于堇青石表面,作为负载型Pd催化剂的载体.所制备的Pd催化剂经加氢老化后,表面石墨烯呈草簇状结构,将Pd纳米粒子限域于片层内,有效防止了Pd的流失和团聚.在重要的工业反应对羧基苯甲醛(4-CBA)加氢中,此结构催化剂与传统的钯碳催化剂相比,表现出很好的稳定性     

Typical basin-fill sequences and basin migration in Yanshan, North China--Response to Mesozoic tectonic transition

Basin-fill sequences of Mesozoic typical basins in the Yanshan area, North China may be divided into four phases, reflecting lithosphere tectonic evolution from flexure (T3), flexure with weak rifting (J1+2), tectonic transition (J3), and rifting (K). Except the first phase, the other three phases all start with lava and volcaniclastic rocks, and end with thick coarse clastic rocks and/or conglomerates, showing cyclic basin development rather than simple cyclic rift mechanism and disciplinary basin-stress change from extension to compression in each phase. Prototype basin analysis, based on basin-fill sequences, paleocurrent distribution and depositional systems, shows that single basin-strike and structural-line direction controlling basin development had evidently changed from east-west to northeast in Late Jurassic in the Yanshan area, although basin group still occurred in east-west zonal distribution. Till Early Cretaceous, main structural-line strike controlling basins just turned to northeast by north in the studied area.     

Soil respiration in tropical seasonal rain forest in Xishuangbanna, SW China

With the static opaque chamber and gas chromatography technique, from January 2003 to January 2004 soil respiration was investigated in a tropical seasonal rain forest in Xishuangbanna, SW China. In this study three treatments were applied, each with three replicates: A (bare soil), B (soil+litter), and C (soil+litter+seedling). The results showed that soil respiration varied seasonally, low from December 2003 to February 2004, and high from June to July 2004. The annual average values of CO2 efflux from soil respiration differed among the treatments at 1% level, with the rank of C (14642 mgCO2· m-2. h-1)＞B (12807 mgCO2· m-2. h-1)＞A (9532 mgCO2· m-2. h-1). Diurnal variation in soil respiration was not apparent due to little diurnal temperate change in Xishuangbanna. There was a parabola relationship between soil respiration and soil moisture at 1% level. Soil respiration rates were higher when soil moisture ranged from 35% to 45%. There was an exponential relationship between soil respiration and soil temperature (at a depth of 5cm in mineral soil) at 1% level. The calculated Q1o values in this study,ranging from 2.03 to 2.36, were very near to those of tropical soil reported. The CO2 efflux in 2003was 5.34 kgCO2· m-2. a-1 from soil plus litter plus seedling, of them 3.48 kgCO2· m-2. a-1 from soil (accounting for 62.5%), 1.19 kgCO2· m-2. a-1 from litter (22.3%) and 0.67 kgCO2·m-2. a-1 from seedling (12.5%).     

Delayed geochemical hazard: Concept, digital model and case study

Delayed Geochemical Hazard (DGH briefly) presents the whole process of a kind of serious ecological and environmental hazard caused by sudden reactivation and sharp release of long-term accumulated pollutant from stable species to active ones in soil or sediment system due to the change of physical-chemical conditions (such as temperature, pH, Eh, moisture, the concentrations of organic matters, etc.) or the decrease of environment capacity. The characteristics of DGH are discussed. The process of a typical DGH can be expressed as a nonlinear polynomial. The points where the derivative functions of the first and second orders of the polynomial reach zero, minimum and maximum are keys for risk assessment and harzard pridication.The process and mechanism of the hazard is due to the transform of pollutant among different species principally. The concepts of "total releasable content of pollutant", TRCP, and "total concentration of active specie", TCAS, are necessarily defined to describe the mechanism of DGH. The possibility of the temporal and spatial propagation is discussed. Case study shows that there exists a transform mechanism of "gradual release" and "chain reaction" among the species of the exchangeable and the bounds to carbonate, iron and manganese oxides and organic matter, thus causing the delayed geochemical hazard.     

Chemical forms of heavy metal contaminants in sediments of Miyun reservoir

The chemical forms, spatial distribution and sources of As, Hg, Cd, Pb and Zn in sediments of the Miyun reservoir were studied. The results of sequential extraction demonstrate that most of As, Pb and Zn were bound to the residual fraction, Hg was associated with the sulfide fraction while Cd was associated with the carbonate fraction and the residual fraction. On the vertical profiles the concentrations of the heavy metals in total and each fractions mostly decreased with increasing depths in sediments, suggesting that the heavy metals input from the upstream watershed increases yearly. Summation of the residual fraction, the sulfide fraction and the carbonate fraction accounts for 60.03%―85.60% of the total heavy metal contents in the sediments, which represent the geochemical background values of the elements and relate closely to soil erosion. Results of the main factor analysis show that most sediments of the reservoir come from the upstream soil erosion, the point source pollution and domestic waste. Moreover, the microbial activities taking place on the sediment-water interface are also one of the major factors to cause the increasing content of the organic matter fraction and the iron-manganese oxide fraction. Environmental change of the reservoir water could make the removability of the heavy metals increase, leading to the increase of their concentrations in pore water in sediments, and imperiling water quality of the reservoir.     

沙坡头没蒿和柠条叶片δ13C 和 N 含量的季节变化特征

通过对腾格里沙漠东南缘沙坡头人工固沙区油蒿和柠条叶片稳定碳同位素分辨率（△）和N 含量的测定，研究了不同种植方式下油蒿和柠条叶片△ 和 N 含量的季节变化及其关系。结果表明：在不同种植方式下，两种植物的△ 与 N 含量在不同月份之间均存在显著差异。油蒿叶片 △ 极显著高于柠条的：在不同种植方式下，油蒿单种下 △ 显著高于混种，柠条则反之。 油蒿叶片 N 含量极显著低于柠条的：不同种植方式下柠条叶片 N 含量无显著差异，而单种油蒿叶片 N 含量则显著低于混种。在 △ 与 N 含量的关系中，柠条叶片 △ 与 N 在两种生境、单种和混种下均极显著正相关，雨明柠条叶片 N 含量可以作为其 △ 与 N 含量的季节变化及其关系在不同微生境有所差异。     

Effect of the Initial Vortex Structure on Intensity Change During Eyewall Replacement Cycle of Tropical Cyclones: A Numerical Study

This study investigates the effect of the initial tropical cyclone (TC) vortex structure on the intensity change during the eyewall replacement cycle (ERC) of TCs based on two idealized simulations using the Weather Research and Forecasting (WRF) model. Results show that an initially smaller TC with weaker outer winds experienced a much more drastic intensity change during the ERC than an initially larger TC with stronger outer winds. It is found that an initially larger TC vortex with stronger outer winds favored the development of more active spiral rainbands outside the outer eyewall, which slowed down the contraction and intensification of the outer eyewall and thus prolonged the duration of the concentric eyewall and slow intensity evolution. In contrast, the initially smaller TC with weaker outer winds corresponded to higher inertial stability in the inner core and weaker inertial stability but stronger filamentation outside the outer eyewall. These led to stronger boundary layer inflow, stronger updraft and convection in the outer eyewall, and suppressed convective activity outside the outer eyewall. These resulted in the rapid weakening during the formation of the outer eyewall, followed by a rapid re-intensification of the TC during the ERC. Our study demonstrates that accurate in- itialization of the TC structure in numerical models is crucial for predicting changes in TC intensity during the ERC. Additionally, monitoring the activity of spiral rainbands outside the outer eyewall can help to improve short-term intensity forecasts for TCs experiencing ERCs.