Oxidation state of the atmosphere and crust of Venus from pioneer Venus results

Recent spacecraft observations of Venus permit a detailed model of sulfur chemistry in the atmosphere-lithosphere system. Pioneer Venus experiments confirm that, as predicted, COS and H₂S are dominant over SO₂ in the lower atmosphere, and that the equilibrium concentrations of S₂ and S₃ are significant. Many criteria serve to bracket the oxidation state of the crust: it is nearly certain that the S₂^2?/SO₄^2? buffer regulates the oxygen fucagity, and that FeO is at least as abundant as Fe₂O₃ in crustal silicates. A highly oxidized crust (as, for example, would result from O₂ absorption complementary to escape of vast amounts of H₂) is incompatible with the gas-phase sulfur chemistry. If the Pioneer Venus mass spectrometer estimates of the abundance of sulfur gases are correct, Earth-like models for the bulk composition of Venus are seriously in error, and a far lower FeO content is required for Venus.     

Fluid inclusions in high-grade gneisses of the Kapuskasing structural zone,Ontario: metamorphic fluids and uplift/erosion path

Fluid inclusions in quartz grains from five samples of high-grade rocks (two paragneisses, an amphibolite, a mafic gneiss and a tonalite dike) from the 2.7 Ga Kapuskasing structural zone (KSZ), Ontario, were examined with petrographic, microthermometric and laser Raman techniques. Three types of fluid inclusions were observed: CO₂-rich, H₂O-rich and mixed CO₂-H₂O. CO₂-rich fluid inclusions are pseudosecondary or secondary in nature and are generally pure CO₂; a few contain varying amounts of CH₄·H₂O-rich fluid inclusions are secondary in nature, contain variable amounts of dissolved salts, and generally contain daughter crystals. Mixed CO₂-H₂O fluid inclusions occur where trails of H₂O-rich inclusions intersect trails of CO₂-rich inclusions. Isochores for high density (p=1.03 g/cm³) pseudosecondary, pure CO₂ inclusions intersect the lower pressure portion of the estimated P-T field for high-grade metamorphism, implying that pure CO₂ was the peak metamorphic fluid. The variable CH₄ content of CO₂ inclusions within graphite-bearing samples suggests that CH₄ was introduced locally after the formation of the CO₂ inclusions; however the origin of the CH₄ remains problematic. An aqueous fluid clearly penetrated the gneisses after the peak metamorphism (during uplift/erosion), forming secondary inclusions and contributing to the minor retrogressive hydration observed in these rocks. The presence of the pseudosecondary, high-density CO₂ inclusions in quartz crystals in the KSZ rocks constrains the uplift/ erosion path for the KSZ to one of simultaneous decrease in pressure and temperature.     

Isotopic anomalies of noble gases in meteorites and their origins—III. LL-chondrites

Nine LL-chondrites were studied by a selective etching technique, to characterize the noblegas components in three mineral fractions: HF-HCl-solubles (silicates, metal, troilite, etc.; comprising ～ 99% of the meteorite), chromite and carbon (～ 0.3–0.7%) and Q (a poorly characterized mineral defined by its solubility in HNO₃, comprising ～ 0.05% of the meteorite but containing most of the Ar, Kr, Xe and a neon component of ${}^{20}\text{Ne}{}^{22}\text{Ne}\text{= 10.9 ± 0.8}$). The ${}^{20}\text{Ne}{}^{36}\text{Ar}$ ratio in Q falls wi petrologic type and rising ³⁶Ar content, as expected for condensation from a cooling solar nebula, but contrary to the trend expected for metamorphic losses. Chondrites of different petrologic types therefore cannot all be derived from the same volatile-rich ancestor, but must have formed over a range of temperatures, with correspondingly different intrinsic volatile contents.The CCFXe (carbonaceous chondrite fission) component varies systematically with petrologic type. The most primitive LL3s (Krymka, Bishunpur, Chainpur) contain substantial amounts of CCFXe in chromite-carbon, enriched relative to primordial Xe as shown by high ${}^{136}\text{Xe}{}^{132}\text{Xe}$ (0.359–0.459, vs 0.310 for primordial Xe). These are accompanied by He and by Ne with ${}^{20}\text{Ne}{}^{22}\text{Ne}\text{≈ 8.0}$ and by variable amounts of a xenon component enriched in the light isotopes. The chromite in these meteorites is compositionally peculiar, containing substantial amounts of Fe(III). These meteorites, as well as Parnallee (LL3) and Hamlet (LL4) also contain CCFXe in phase Q, heavily diluted by primordial $\text{Xe}\text{(}{}^{136}\text{Xe}{}^{132}\text{Xe}\text{= 0.317–0.329)}$. On the other hand, LL5s and 6s (Olivenza, St. Séverin, Manbhoom and Dhurmsala) contain no CCFXe in either mineral. This deficiency must be intrinsic rather than caused by metamorphic loss, because Q in these meteorites still contains substantial amounts of primordial Ne.If CCFXe comes from a supernova, then its distribution in LL-chondrites requires three presolar carrier minerals of the right solubility properties, containing three different xenon components in certain combinations. These minerals must be appropriately distributed over the petrologic types, together with locally produced Q containing primordial gases, and they must be isotopically normal, in contrast to the gases they contain. On the other hand, if CCFXe comes from fission of a volatile superheavy element, then its decrease from LL3 to LL6 can be attributed to progressively less complete condensation from the solar nebula. Ad hoc assumptions must of the host phase Q, its association with ferrichromite and the origin of the associated xenon component enriched in the light isotopes.Soluble minerals in LL3s and LL4s contain a previously unobserved, solar xenon component, which, however, is not derived from the solar wind. Three types of ‘primordial’ xenon thus occur side-by-side in different minerals of the same meteorite: strongly fractionated Xe in ferrichromite and carbon, lightly fractionated Xe in phase Q, and ‘solar’ Xe in solubles. Because the first two can apparently be derived from the third by mass fractionation, it seems likely that all were trapped from the same solar nebula reservoir, but with different degrees of mass fractionation.     

Back analysis of landslide susceptibility zonation mapping for the 2005 Kashmir earthquake: an assessment of the reliability of susceptibility zoning maps

The October 2005 earthquake triggered several thousand landslides in the Lesser Himalaya of Kashmir in northern Pakistan and India. Analyses of ASTER satellite imagery from 2001 were compared with a study undertaken in 2005; the results show the extent and nature of pre- and co-/post-seismic landsliding. Within a designated study area of ~2,250 km², the number of landslides increased from 369 in 2001 to 2,252 in October 2005. Assuming a balanced baseline landsliding frequency over the 4 years, most of the new landslides were likely triggered by the 2005 earthquake and its aftershocks. These landslides mainly happened in specific geologic formations, along faults, rivers and roads, and in shrubland/grassland and agricultural land. Preliminary results from repeat photographs from 2005 and 2006 after the snowmelt season reveal that much of the ongoing landsliding occurred along rivers and roads, and the extensive earthquake-induced fissuring. Although the susceptibility zoning success rate for 2001 was low, many of the co-/post-seismic landsliding in 2005 occurred in areas that had been defined as being potentially dangerous on the 2001 map. While most of the area in 2001 was (very) highly susceptible to future landsliding, most of the area in 2005 was only moderate to low susceptible, that is, most of the landsliding in 2005 actually occurred in the potentially dangerous areas on the 2001 map. This study supports the view that although susceptibility zoning maps represent a powerful tool in natural hazard management, caution is needed when developing and using such maps.     

Enteroviruses in mussels and marine sediments and depuration of naturally accumulated viruses by green lipped mussels (Perna canaliculus)

Surveys were carried out over 16 months to assess the distribution of enteroviruses of human origin in sediments and mussels near two sewage outfalls on the North Taranaki Coast, New Zealand. Enteroviruses were present in high numbers in both sediments and shellfish near the New Plymouth sewage outfall with maximum virus levels of 32 000 pfu 100 g^‐1 of wet mussel tissue and 59 pfu 100 g^‐1 of wet sediment material. Viruses were recovered occasionally from sediments and mussels near the Waitara Borough outfall. Coxsackievirus B4 was the predominant virus type isolated but CB5 and Poliovirus types 1, 2, and 3 were also recovered. Attempts to depurate virus‐contaminated New Plymouth mussels, by keeping them in water for 8 days with daily water replacement, did not achieve a significant reduction in virus numbers.     

Modification of the polyethylene glycol 6000 precipitation method for recovering human and indicator viruses from oysters and mussels

Human viruses are a common contaminant of shellfish affected by human sewage wastes. They are difficult to detect as they are not easily separated from shellfish tissue. This paper describes a modification of the polyethylene glycol (PEG) precipitation technique for recovery of enteroviruses and F‐specific bacteriophages from the Pacific oyster (Crassostrea gigas) and the green‐lipped mussel (Perna canaliculus). Modifications adopted were the use of only the digestive gland tissue for virus extraction, resuspension of the primary PEG pellet in 4 volumes of eluent, and the introduction of a secondary PEG precipitation to reconcentrate the virus containing extract. The recovery rate of the virus extraction process was not affected by introduction of the secondary concentration step (overall recovery remained at 60–70% of the virus input). The advantages of reduction of tissue residue in the extract, smaller final volume, and the ability to process 2–3 times the number of individual shellfish for the same effort, improve the practicality of the method.     

From oblique subduction to intra-continental transpression: Structures of the southern Kermadec-Hikurangi margin from multibeam bathymetry,side-scan sonar and seismic reflection

The southern Kermadec-Hikurangi convergent margin, east of New Zealand, accommodates the oblique subduction of the oceanic Hikurangi Plateau at rates of 4–5 cm/yr. Swath bathymetry and sidescan data, together with seismic reflection and geopotential data obtained during the GEODYNZ-SUD cruise, showed major changes in tectonic style along the margin. The changes reflect the size and abundance of seamounts on the subducting plateau, the presence and thickness of trench-fill turbidites, and the change to increasing obliquity and intracontinental transpression towards the south. In this paper, we provide evidence that faulting with a significant strike-slip component is widespread along the entire 1000 km margin. Subduction of the northeastern scrap of the Hikurangi Plateau is marked by an offset in the Kermadec Trench and adjacent margin, and by a major NW-trending tear fault in the scarp. To the south, the southern Kermadec Trench is devoid of turbidite fill and the adjacent margin is characterized by an up to 1200 m high scarp that locally separates apparent clockwise rotated blocks on the upper slope from strike-slip faults and mass wasting on the lower slope. The northern Hikurangi Trough has at least 1 km of trench-fill but its adjacent margin is characterized by tectonic erosion. The toe of the margin is indented by 10–25 km for more than 200 km, and this is inferred to be the result of repeated impacts of the large seamounts that are abundant on the northern Hikurangi Plateau. The two most recent impacts have left major indentations in the margin. The central Hikurangi margin is characterized by development of a wide accretionary wedge on the lower slope, and by transpression of presubduction passive margin sediments on the upper slope. Shortening across the wedge together with a component of strike-slip motion on the upper slope supports an interpretation of some strain partitioning. The southern Hikurangi margin is a narrow, mainly compressive belt along a very oblique, apparently locked subduction zone.     

Finite element modelling of three-phase flow in deforming saturated oil reservoirs

A numerical simulation is presented for three-dimensional three-phase fluid flow in a deforming saturated oil reservoir. The mathematical formulation describes a fully coupled governing equation systen which consists of the equilibrium and continuity equations for three immiscible fluids flowing in a porous medium. An elastoplastic soil model, based on a Mohr–Coulomb yield surface, is used. The finite element method is applied to obtain simultaneous solutions to the governing equations where displacement and fluid pressures are the primary unknowns. The final discretized equations are solved by a direct solver using fully implicit procedures. The developed model is used to investigate the problems of three-phase fluid flow in a deforming saturated oil reservoir.