Low boundary layer response and temperature dependence of nitrogen and phosphorus releases from oxic sediments of an oligotrophic lake

The effects of temperature, diffusive boundary-layer thickness, and sediment composition on fluxes of inorganic N and P were estimated for sediment cores with oxidized surfaces from nearshore waters (2?C10?m) of a montane oligotrophic lake. Fluxes of N and P were not affected by diffusive boundary-layer thickness but were strongly affected by temperature. Below 16?°C, sediments sequestered small amounts of P and released small amounts of N. Above 16?°C, the seasonal maximum water temperature, sediments were substantial sources of N (NH₄ ⁺?CN?=?2?C24?mg?m^?2 d^?1; NO₃ ^??+?NO₂ ^??CN?=?2?C5?mg?m^?2 d^?1) and P (0.1?C0.4?mg?m^?2 d^?1), indicating potential responsiveness of sediment?Cwater nutrient exchange, and of corresponding phytoplankton growth, to synoptic warming.     

Modelling the martian atmosphere

Stephen R Lewis shows how to model the climate of Mars, touching on the physics and dynamics of general circulation models, and the wealth of information that such models both need and produce – useful to climatologists on Earth as well as engineers planning future Mars missions.     

Time‐Lapse Electrical Geophysical Monitoring of Amendment‐Based Biostimulation

Biostimulation is increasingly used to accelerate microbial remediation of recalcitrant groundwater contaminants. Effective application of biostimulation requires successful emplacement of amendment in the contaminant target zone. Verification of remediation performance requires postemplacement assessment and contaminant monitoring. Sampling‐based approaches are expensive and provide low‐density spatial and temporal information. Time‐lapse electrical resistivity tomography (ERT) is an effective geophysical method for determining temporal changes in subsurface electrical conductivity. Because remedial amendments and biostimulation‐related biogeochemical processes often change subsurface electrical conductivity, ERT can complement and enhance sampling‐based approaches for assessing emplacement and monitoring biostimulation‐based remediation. Field studies demonstrating the ability of time‐lapse ERT to monitor amendment emplacement and behavior were performed during a biostimulation remediation effort conducted at the Department of Defense Reutilization and Marketing Office (DRMO) Yard, in Brandywine, Maryland, United States. Geochemical fluid sampling was used to calibrate a petrophysical relation in order to predict groundwater indicators of amendment distribution. The petrophysical relations were field validated by comparing predictions to sequestered fluid sample results, thus demonstrating the potential of electrical geophysics for quantitative assessment of amendment‐related geochemical properties. Crosshole radar zero‐offset profile and borehole geophysical logging were also performed to augment the data set and validate interpretation. In addition to delineating amendment transport in the first 10 months after emplacement, the time‐lapse ERT results show later changes in bulk electrical properties interpreted as mineral precipitation. Results support the use of more cost‐effective surface‐based ERT in conjunction with limited field sampling to improve spatial and temporal monitoring of amendment emplacement and remediation performance.     

Kinetics of removal of iron colloids from estuaries

Laboratory experiments indicate that colloidal Fe is aggregated in estuarine waters by a second-order kinetic mechanism. The corresponding rate coefficient is proportional to the square of the salinity. A simple theoretical formulation is presented to describe the distribution of Fe in an estuary, based on observed second-order kinetics. The distribution depends on a single parameter whose value may be determined from measurements of the physical characteristics of the estuary. The theoretical expression accurately predicts observed distributions of Fe in a variety of estuaries, suggesting general applicability.     

The Mackenzie Delta: sedimentary processes and facies of a high-latitude, fine-grained delta

The Mackenzie Delta is a large fine‐grained delta deposited in a cold arctic setting. The delta has been constructed upon a flooding surface developed on a previous shelf‐phase delta. There are three principal depositional zones: the subaerial delta plain, the distributary channel mouth region and the subaqeous delta. The subaerial delta plain is characterized by an anastomosing system of high‐sinuosity channels and extensive thermokarst lake development. This region is greatly influenced by the annual cycle of seasonal processes including winter freezing of sediments and channels, ice‐jamming and flooding in the early spring and declining river stage during the summer and autumn. Deposition occurs on channel levees and in thermokarst lakes during flood events and is commonly rhythmic in nature with discrete annual beds being distinguishable. In the channel mouth environment, deposition is dominated by landward accretion and aggradation of mouth bars during river‐ and storm surge‐induced flood events. The subaqeous delta is characterized by a shallow water platform and a gentle offshore slope. Sediment bypassing of the shallow‐water platform is efficient as a result of the presence of incised submarine channels and the predominance of suspension transport of fine‐grained sediments. Facies of the shallow platform include silty sand with climbing ripple lamination. Offshore facies are dominated by seaward‐fining fine sand to silt tempestites. Sea‐ice scouring and sediment deformation are common beyond 10 m water depth where bioturbated muds are the predominant facies. The low angle profile of the shallow‐water platform is interpreted to be the combined response of a fine‐grained delta to (1) storm sediment dispersal; (2) autoretreat as a result of the increasing subaerial and subaqeous area of deposition as the delta progrades out of its glacial valley; (3) limited water depth above the underlying flooding surface; and (4) efficient nearshore bypassing of sediment through subice channels at the peak of spring discharge. Several indicators of the cold climate can be used as criteria for the interpretation of ancient successions, including thermokarst lake development, submarine channel scours, freeze–thaw deformation and ice‐scour deformation structures. Permafrost inhibits compaction subsidence and, together with the shallow‐water setting, also limits autocyclic lobe switching. The cold climate can thus influence stratal architecture by favouring the development of regional‐scale clinoform sets rather than multiple, smaller scale lobes separated by autocyclic flooding surfaces.     

Development of Iron Speciation Reference Materials for Palaeoredox Analysis

The development and application of geochemical techniques to identify redox conditions in modern and ancient aquatic environments has intensified over recent years. Iron (Fe) speciation has emerged as one of the most widely used procedures to distinguish different redox regimes in both the water column and sediments, and is the main technique used to identify oxic, ferruginous (anoxic, Fe(II) containing) and euxinic (anoxic, sulfidic) water column conditions. However, an international sediment reference material has never been developed. This has led to concern over the consistency of results published by the many laboratories that now utilise the technique. Here, we report an interlaboratory comparison of four Fe speciation reference materials for palaeoredox analysis, which span a range of compositions and reflect deposition under different redox conditions. We provide an update of extraction techniques used in Fe speciation and assess the effects of both test portion mass, and the use of different analytical procedures, on the quantification of different Fe fractions in sedimentary rocks. While atomic absorption spectroscopy and inductively coupled plasma‐optical emission spectrometry produced comparable Fe measurements for all extraction stages, the use of ferrozine consistently underestimated Fe in the extraction step targeting mixed ferrous–ferric minerals such as magnetite. We therefore suggest that the use of ferrozine is discontinued for this Fe pool. Finally, we report the combined data of four independent Fe speciation laboratories to characterise the Fe speciation composition of the reference materials. These reference materials are available to the community to provide an essential validation of in‐house Fe speciation measurements.     

The chemistry of sublimates collected directly from lava fountains at Kilauea Volcano,Hawaii

During 1970, it was occasionally feasible to collect sublimate from directly above the lava fountain in the crater of Mauna Ulu on the east rift zone of Kilauea Volcano, when the level of the lava pool had dropped within the crater. Collecting equipment was suspended down the steep wall to a position above the fountain. Collections were made on quartz wool held within open-ended quartz tubes and, for silica detection, on stainless steel wool in a stainless steel tube. The main components in the sublimate were, in order of decreasing concentration for the best sample, Na, Ca, Al, Fe, Mg, K, B, Si, Ti, Zn, H⁺, NH₄⁺, Cu, Ni in the form of sulfates, chlorides and fluorides.In order to investigate the forms in which the sublimate ions occur under different conditions of temperature and oxidation, the equilibrium compositions of the compounds most likely to be present were calculated. This was done for those important components for which thermodynamic data are available, using a computer program to calculate the minimum free energy for the mixture. The results indicate that, for primary conditions of high temperature and low oxygen partial pressure, the halides were the most likely form of the metallic compounds. Particulate sulfates appear under increasing oxidizing conditions caused by the access of air. These conclusions were reinforced by collections made from holes drilled through the thin crust of a lava lake formed during the same eruption.     

Carbon content and carbonate 13C abundances in the Early Precambrian Swaziland sediments of South Africa

Carbon content (0.02–0.68% organic), carbonate content (0–69.7%) and carbonate ¹³C abundances (${}^{\mathrm{?}}\text{7.5?+2.3‰}$) were obtained on samples from the Swaziland sediments of South Africa, which are among the oldest known sedimentary rocks on earth (> 3·10⁹ years old). The carbon chemistry of these sediments may serve as evidence for early life and/or for products of chemical evolution. The variation of organic and carbonate carbon concentrations in different sedimentary horizons seems to be controlled by differences in depositional and diagenetic histories. The carbonate δ ¹³C values did not vary significantly from the ordinary range of Phanerozoic limestone values.     

A mixed mode rock fracture model for the prediction of crack path

Crack propagation in rocks is simulated by using a displacement substitution method based on a mixed mode fracture criterion. The main advantage of this model is that it can distinguish between mode I and mode II stress intensity factors simultaneously. A typical finite element program is used to compute displacements adjacent to the crack tip. The maximum circumferential tensile stress is adopted as a ‘yield surface’ for the calculation of the load factor in each crack increment. Pure mode I and mixed mode examples have been analysed to validate the capability of the model. Copyright © 1999 John Wiley & Sons, Ltd.