NN detectability in Pluto’s atmosphere

Based on the vapor pressure behavior of Pluto’s surface ices, Pluto’s atmosphere is expected to be predominantly composed of N₂ gas. Measurement of the N₂ isotopologue ¹⁵N/¹⁴N ratio within Pluto’s atmosphere would provide important clues to the evolution of Pluto’s atmosphere from the time of formation to its present state. The most straightforward way of determining the N₂ isotopologue ¹⁵N/¹⁴N ratio in Pluto’s atmosphere is via spectroscopic observation of the ¹⁴N¹⁵N gas species. Recent calculations of the 80–100 nm absorption behavior of the ¹⁴N₂ and ¹⁴N¹⁵N isotopologues by Heays et al. (Heays, A.N. et al. [2011]. J. Chem. Phys. 135, 244301), Lewis et al. (Lewis, B.R., Heays, A.N., Gibson, S.T., Lefebvre-Brion, H., Lefebvre, R. [2008]. J. Chem. Phys. 129, 164306); Lewis et al. (Lewis, B.R., Gibson, S.T., Zhang, W., Lefebvre-Brion, H., Robbe, J.-M. [2005]. J. Chem. Phys. 122, 144302), and Haverd et al. (Haverd, V.E., Lewis, B.R., Gibson, S.T., Stark, G. [2005]. J. Chem. Phys. 123, 214304) show that the peak magnitudes of the ¹⁴N₂ and ¹⁴N¹⁵N absorption bandhead cross-sections are similar, but the locations of the bandhead peaks are offset in wavelength by ∼0.05–0.1 nm. These offsets make the segregation of the ¹⁴N₂ and ¹⁴N¹⁵N absorption signatures possible. We use the most recent N₂ isotopologue absorption cross-section calculations and the atmospheric density profiles resulting from photochemical models developed by Krasnopolsky and Cruickshank (Krasnopolsky, V.A., Cruickshank, D.P. [1999]. J. Geophys. Res. 104, 21979–21996) to predict the level of solar light that will be transmitted through Pluto’s atmosphere as a function of altitude during a Pluto solar occultation. We characterize the detectability of the isotopic absorption signature per altitude assuming ¹⁴N¹⁵N concentrations ranging from 0.1% to 2% of the ¹⁴N₂ density and instrumental spectral resolutions ranging from 0.01 to 0.3 nm. Our simulations indicate that optical depth of unity is attained in the key ¹⁴N¹⁵N absorption bands located between 85 and 90 nm at altitudes ∼1100–1600 km above Pluto’s surface. Additionally, an ¹⁴N¹⁵N isotope absorption depth ∼4–15% is predicted for observations obtained at these altitudes at a spectral resolution of ∼0.2–0.3 nm, if the N₂ isotopologue ¹⁵N/¹⁴N percent ratio is comparable to the 0.37–0.6% ratio observed at Earth, Titan and Mars. If we presume that the predicted absorption depth must be at least 25% greater than the expected observational uncertainty, then it follows that a statistically significant detection of these signatures and constraint of the N₂ isotopologue ¹⁴N/¹⁵N ratio within Pluto’s atmosphere will be possible if the attainable observational signal-to noise (S/N) ratio is ?9. The New Horizons (NH) Mission will be able to obtain high S/N, 0.27–0.35 nm full-width half-max 80–100 nm spectral observations of Pluto using the Alice spectrograph. Based on the NH/Alice specifications we have simulated 0.3 nm spectral resolution solar occultation spectra for the 1100–1600 km altitude range, assuming 30 s integration times. These simulations indicate that NH/Alice will obtain spectral observations within this altitude range with a S/N ratio ∼25–50, and should be able to reliably detect the ¹⁴N¹⁵N gas absorption signature between 85 and 90 nm if the ¹⁴N¹⁵N concentration is ∼0.3% or greater. This, additionally, implies that the non-detection of the ¹⁴N¹⁵N species in the 1100–1600 km range by NH/Alice may be used to reliably establish an upper limit to the N₂ isotopologue ¹⁵N/¹⁴N ratio within Pluto’s atmosphere. Similar results may be derived from 0.2 to 0.3 nm spectral resolution observations of any other N₂-rich Solar System or exoplanet atmosphere, provided the observations are attained with similar S/N levels.     

Climate science in climate security scenarios

The climate is changing and this will have consequences across the globe, affecting all areas of the natural and human environment in complex ways. One tool for exploring the complex relationship between climate change and security is to use a scenariobased approach as means to develop plausible rather than probable narratives. This approach can explore the range of uncertainty, and help policymakers to visualise the potential consequences of climate change. Scenario methodology has been most comprehensively developed for use in business planning and there are some differences in the way scenarios work for climate security. The most notable is the fact that there is a physical modelling basis for climate projections. This means that the uncertainty range associated with at least this one aspect of the scenario can be systematically sampled. This paper reviews how scenarios have been used in the climate security literature to date, in particular in the grey literature. The integration of climate projections is explored in detail, as the main distinguishing feature of climate security scenarios over other scenario types. Few climate security scenarios have been developed to date, but all those included in this review, regardless of the differences in national conditions, regional climate change and potential responses, came to very similar conclusions. This was despite differences in the changes in climate and non-climate drivers, or differences in the scenario approach and audience. A more systematic and scientific approach to developing the scenario drivers and narratives is recommended, and successfully embedding changes in climate within the socio-economic context, through better integration of inter-disciplinary expertise, is critical.     

Geographical imaginaries: Articulating the values of geography

This paper explores the concept of ‘geographical imaginaries’ in New Zealand geography. It reflects on the genealogy of the concept and on the work it might perform in the world. At a time when the purpose and contribution of geography in schools is under question and the discipline is under severe strain at universities, we ask whether the idea of ‘geographical imaginaries’ offers a conceptual platform for demonstrating the potential for geography to offer meaning in the complex world of 21st‐century New Zealand and whether it will help teachers to foster geographic thought in classrooms. In short, we argue for the merits of working with the idea of geographical imaginaries in classrooms and for utilising it to interrogate accounts of the geographical gaze and its values. This, we argue, offers opportunities to catalyse geographical thought, highlight the potential of thinking geographically, and open up a thinking space in which geography teachers can examine their pedagogy and enhance the purpose of their work. This would provide a platform for building a more imaginative and more politically and culturally relevant geography at school.     

Impact of interacting bark structure and rainfall conditions on stemflow variability in a temperate beech-oak forest,central Germany

ABSTRACT

Trees concentrate rainfall to near-stem soils via stemflow. When canopy structures are organized appropriately, stemflow can even induce preferential flow through soils, transporting nutrients to biogeochemically active areas. Bark structure significantly affects stemflow, yet bark-stemflow studies are primarily qualitative. We used a LaserBark to compute bark microrelief (MR), ridge-to-furrow amplitude (R) and slope (S) metrics per American Society of Mechanical Engineering standards (ASME-B46.1–2009) for two morphologically contrasting species (Fagus sylvatica L. (European beech), Quercus robur L. (pendunculate oak)) under storm conditions with strong bark water storage capacity (BWSC) influence in central Germany. Smaller R and S for F. sylvatica significantly lowered BWSC, which strongly and inversely correlated to maximum funnelling ratios and permitted stemflow generation at lower rain magnitudes. Larger R and S values in Q. robur reduced funnelling, diminishing stemflow drainage for larger storms. Quercus robur funnelling and stemflow was more reliant on intermediate rain intensities and intermittency to maintain bark channel-dependent drainage pathways. Shelter provided by Q. robur’s ridged bark also appears to protect entrained water, lengthening mean intrastorm dry periods necessary to affect stemflow. Storm conditions where BWSC plays a major role in stemflow accounted for much of 2013’s rainfall at the nearest meteorological station (Wulferstedt).

Editor M.C. Acreman; Associate editor not assigned     

Photochemical production and decomposition of particulate organic carbon in a freshwater stream

Irradiation of dissolved organic carbon (DOC) of terrestrial origin that is freshly released to surface waters can produce particulate organic carbon (POC). Laboratory experiments with stream water were conducted to determine POC and particulate metals formation during exposure to artificial solar radiation comparable to surface intensity. The results showed that decreases in DOC concentration were accompanied initially by increasing and later by decreasing POC concentrations. Data were fit to first order kinetics models to compare rates of POC formation and loss with DOC and absorbance loss, and to better understand how metals might be involved in photochemical POC formation. This abiotic mechanism may be important for the transfer of allochthonous DOC and metals to sediments in temperate aquatic systems.     

Zonal winds at high latitudes on Venus: An improved application of cyclostrophic balance to Venus Express observations

Recent retrievals of zonal thermal winds obtained in a cyclostrophic regime on Venus are generally consistent with cloud tracking measurements at mid-latitudes, but become unphysical in polar regions where the values obtained above the clouds are often less than or close to zero. Using a global atmospheric model, we show that the main source of errors that appear in the polar regions when retrieving the zonal thermal winds is most likely due to uncertainties in the zonal wind intensity in the choice of the lower boundary condition.Here we suggest a new and robust method to better estimate the lower boundary condition for high latitudes, thereby improving the retrieved zonal thermal winds throughout the high latitudes middle atmosphere. This new method is applied to temperature fields derived from Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) data on board the Venus Express spacecraft. We obtain a zonal thermal wind field that is in better agreement with other, more direct methods based on either retrieving the zonal winds from cloud tracking or from direct measurements of the meridional slope of pressure surfaces.     

Coevolution of hydrology and topography on a basalt landscape in the Oregon Cascade Range,USA

Young basalt terrains offer an exceptional opportunity to study landscape and hydrologic evolution through time, since the age of the landscape itself can be determined by dating lava flows. These constructional terrains are also highly permeable, allowing one to examine timescales and process of geomorphic evolution as they relate to the partitioning of hydrologic flowpaths between surface and sub‐surface flow. The western slopes of the Cascade Range in Oregon, USA are composed of a thick sequence of lava flows ranging from Holocene to Oligocene in age, and the landscape receives abundant precipitation of between 2000 and 3500 mm per year. On Holocene and late Pleistocene lava landscapes, groundwater systems transmit most of the recharge to large springs (≥0·85 m³ s^?1) with very steady hydrographs. In watersheds >1 million years old, springs are absent, and well‐developed drainage networks fed by shallow subsurface stormflow produce flashy hydrographs. Drainage density slowly increases with time in this basalt landscape, requiring a million years to double in density. Progressive hillslope steepening and fluvial incision also occur on this timescale. Springs and groundwater‐fed streams transport little sediment and hence are largely ineffective in incising river valleys, so fluvial landscape dissection appears to occur only after springs are replaced by shallow subsurface stormflow as the dominant streamflow generation mechanism. It is proposed that landscape evolution in basalt terrains is constrained by the time required for permeability to be reduced sufficiently for surface flow to replace groundwater flow. Copyright © 2010 John Wiley & Sons, Ltd.     

He Iwi Kotahi Tatou Trust: Post-development practices in Moerewa,Northland

This paper examines community development projects in Moerewa, a small town in Te Tai Tokerau (central Northland) decimated by industrial decline in the late 1980s. It builds on a series of conversations with Ngahau Davis of He Iwi Kotahi Tatou Trust, which has sought to revitalise Moerewa by challenging conventional understandings of development. The paper is part of an on-going engagement with the Trust, which includes involving it with a second year undergraduate field course. In the paper, we argue for the political and theoretical potential of post-development inquiry and practice in communities like Moerewa.     

Prediction of the arrival of peak nitrate concentrations at the water table at the regional scale in Great Britain

A simple process‐based approach to predict regional‐scale loading of nitrate at the water table was implemented in a GIS for Great Britain. This links a nitrate input function, unsaturated zone thickness, and lithologically dependent rate of nitrate unsaturated zone travel to estimate arrival time of nitrate at the water table. The nitrate input function is the loading at the base of the soil and has been validated using unsaturated zone porewater profiles. The unsaturated zone thickness uses groundwater levels based on regional‐scale observations infilled by interpolated river base levels. Estimates of the rate of unsaturated zone travel are attributed from regional‐scale hydrogeological mapping. The results indicate that peak nitrate loading may have already arrived at the water table for many aquifers, but that it has not where the unsaturated zone is relatively thick There are contrasting outcomes for the two main aquifers which have similar unsaturated zone velocities, the predominantly low relief Permo‐Triassic sandstones, and the Chalk, which forms significant topographic features. For about 60% of the Chalk, the peak input has not yet reached the water table and will continue to arrive over the next 60 years. The methodology is readily transferable and provides a robust method for estimating peak arrival time for any diffuse conservative pollutant where an input function can be defined at a regional scale and requires only depth to groundwater and a hydrogeological classification. The methodology is extendable in that if additional information is available this can easily be incorporated into the model scheme. British Geology Survey © NERC 2011. Hydrological Process © 2011 John Wiley & Sons, Ltd