Carbonatites and ultrabasic-alkaline rocks of the maimecha-kotui region, N. Siberia

The structural position, geology, petrography, petrochemistry, and petrogenesis of one of the world's greatest carbonatite provinces situated in North Siberia are recorded. Three groups of Late Permian-Early Triassic magmatites are briefly discussed: effusives, dikes, and intrusives of complex central type. Carbonatite and congenetic rocks are related to kimberlites, but are genetically unrelated to tholeiitic basalts and trachybasalts. The genetic development and diagnostic features of ultrabasic-alkaline rocks and carbonatites are formulated.     

The eastern extent of the Barents–Kara ice sheet during the Last Glacial Maximum based on seismic-reflection data from the eastern Kara Sea

We present sub-bottom profiling (sparker and Parasound) results from the eastern Kara Sea, on the Eurasian Arctic margin, which enable the identification of the Last Glacial Maximum (LGM) ice extent. The analysed profiles show that glacigenic diamicton is ubiquitous at the seafloor, east of about 95°E and 78°N. The eastern margin of this diamicton is expressed in a conspicuous morainic ridge at the entrance to the Vilkitsky Strait, and to the south the diamicton projection aligns with the LGM limit mapped at the north-western Taymyr. The bottom of the Voronin Trough further north is also covered with diamicton and has numerous erosional bedforms, indicating a streamlined flow of grounded ice along the trough. Accurate dating of the diamicton is not attainable, but the correlation of pre-diamict sediments to well-dated sections in the Laptev Sea, and available ¹⁴C ages from sediments on top of the diamicton, indicate its LGM age. These results support the palaeogeographic reconstruction that assumes the extension of the LGM Barents–Kara ice sheet as far east as Taymyr. This configuration implies that LGM ice blocked the drainage of the Ob and Yenisey rivers on the Kara shelf. This inference is consistent with the presence of large (>100 km wide) lenses of basin infill adjacent to the southern margin of the diamicton. However, the limited distribution of the eastern Kara ice lobe, not extending on Severnaya Zemlya, suggests that the ice was fairly thin and short-lived: insufficient for the accumulation of the gigantic proglacial lakes that occurred during earlier glaciations.     

Viability of pyrite pulled metabolism in the ‘iron-sulfur world’ theory: Quantum chemical assessment

The viability of pyrite-pulled metabolism in the ‘iron-sulfur world’ theory was assessed using a simple model of iron-nickel sulfide (Fe-Ni-S) surface and data obtained from quantum chemical calculations. We have investigated how the individual reactions in the carbon fixation cycle (carboxylic acids formation) on an Fe-Ni-S surface could have operated to produce carboxylic acids from carbon oxide and water. The proposed model cycle reveals how the individual reactions might have functioned and provides the thermodynamics of each step of the proposed pathway. The feasibility of individual reactions, as well the whole cycle was considered. The reaction of acetic acid production from CH₃SH and CO on an Fe-Ni sulfide surface was revealed to be endergonic with a few partial steps having positive Gibbs free energy. On the other hand, the pyrite formation was found to be slightly exergonic. The significance of the catalytic activity of transition metal sulfides in generation of acetic acid was shown. The Gibbs free energy values indicate that the acetic acid synthesis is unfavorable to proceed on the studied Fe-Ni-S model under simulated conditions. The importance of these results in terms of a primordial chemistry on iron-nickel sulfide surfaces is discussed.     

A Long-Term Decrease of the Mid-Size Segmentation Lengths Observed in the He <Emphasis Type="SmallCaps">ii</Emphasis> (30.4 nm) Solar EUV Emission

Power spectra of segmentation-cell length (a dominant length scale of EUV emission in the transition region) from full-disk He?ii extreme ultraviolet (EUV) images observed by the Extreme ultraviolet Imaging Telescope (EIT) onboard the Solar and Heliospheric Observatory (SOHO) and the Atmospheric Imaging Assembly (AIA) onboard the Solar Dynamics Observatory (SDO) during periods of quiet-Sun conditions for a time interval from 1996 to 2015 were analyzed. The spatial power as a function of the spatial frequency from about 0.04 to 0.27 (EIT) or up to 0.48 (AIA) Mm^?1 depends on the distribution of the observed segmentation-cell dimensions – a structure of the solar EUV network. The temporal variations of the spatial power reported by Didkovsky and Gurman (Solar Phys. 289, 153, 2014) were suggested as decreases at the mid-spatial frequencies for the compared spectra when the power curves at the highest spatial frequencies of 0.5 pix^?1 were adjusted to match each other. This approach has been extended in this work to compare spectral ratios at high spatial frequencies expressed in the solar spatial frequency units of Mm^?1. A model of EIT and AIA spatial responses allowed us to directly compare spatial spectral ratios at high spatial frequencies for five years of joint operation of EIT and AIA, from 2010 to 2015. Based on this approach, we represent these ratio changes as a long-term network transformation that may be interpreted as a continuous dissipation of mid-size network structures to the smaller-size structures in the transition region. In contrast to expected cycling of the segmentation-cell dimension structures and associated spatial power in the spectra with the solar cycle, the spectra demonstrate a significant and steady change of the EUV network. The temporal trend across these structural spectra is not critically sensitive to any long-term instrumental changes, e.g. degradation of sensitivity, but to the change of the segmentation-cell dimensions of the EUV network structure.     

Parameterization of iron and manganese cycling in the Black Sea suboxic and anoxic environment

New and published data on the distribution and speciation of manganese and iron in seawater are analyzed to identify and parameterize major biogeochemical processes of their cycling within the suboxic (15.6σ_t16.2) and anoxic layers (σ_t16.2) of the Black Sea. A steady-state transport-reaction model is applied to reveal layering and parameterize kinetics of redox and dissolution/precipitation processes. Previously published data on speciation of these elements in seawater are used to specify the nature of the transformations. Two particulate species of iron (Fe(III) hydroxide and Fe(II) sulfide) are necessary to adequately parameterize the vertical profile of suspended iron, while three particulate species (hydrous Mn(IV) oxide, Mn(II) sulfide, and Mn(II) carbonate) are necessary to describe the profile of suspended manganese. In addition to such processes as mixing and advection, precipitation, sinking, and dissolution of manganese carbonate are found to be essential in maintaining the observed vertical distribution of dissolved Mn(II). These results are used to interpret the observed difference in the form of vertical distribution for dissolved Mn(II) and Fe(II). Redox transformations of iron and manganese are coupled via oxidation of dissolved iron by sinking suspended manganese at σ_t16.2±0.2 kg m⁻³. The particulate manganese, necessary for this reaction, is supplied through oxidation of dissolved Mn(II). The best agreement with observations is achieved when nitrate, rather than oxygen, is set to oxidize dissolved Mn(II) in the lower part of the suboxic layer (15.90σ_t16.2). The results support the idea that, after sulfides of these metals are formed, they sink with particulate organic matter. The sinking rates of the particles and specific rates of individual redox and dissolved-particulate transformations have been estimated by fitting the vertical profile of the net rate.     

峨眉火成岩省内带岩浆硫化物含矿岩体橄榄石的成因意义

岩浆镍-铜-铂族元素(PGE)硫化物矿床是峨眉火成岩省地幔柱活动形成的两个重要的成矿系列之一[1～3].目前已发现的与峨眉火成岩省相关的40余个镍-铜-铂族元素硫化物矿床(或矿点)中,多数分布在内带[3,4].它们可分为:1)富Ni、Cu而贫PGE的Ni-Cu型(如力马河和清水河);2)富Ni,Cu且PGE中等的Ni-Cu-PGE型(如清矿山和黄草坪);3)贫Ni、Cu富PGE的PGE型(如金宝山和杨合武).