A detailed paleomagnetic survey of the type location for the Gilsa geomagnetic polarity event

A total of 163 cores have been taken from a maximum of 40 separate lavas in three separate sections of the Jökuldalur, southwest of Egilsstadir, Iceland, and subjected to paleomagnetic analysis and some K-Ar dating. Previous work on the sections by McDougall and Wensink (1966) led to the establishment of the Gilságeomagnetic polarity event, with an age of about 1.60 m.y., during the reversed polarity Matuyama epoch. This earlier study described a possible reversely magnetized lava separating the Gilsáevent from a second normal polarity lava, perhaps representing the Olduvai event. Such a possibility was subsequently a source of speculation from diverse sources concerning the polarity history for the lower Matuyama. The present study indicates clearly that there is no second normal polarity event represented in the sections. Only one normal polarity event is therefore represented in the lower Matuyama of the Jökuldalur, and the age of the lavas involved is confirmed to be approximately 1.58 ± 0.08 m.y. Because of uncertainties in the interpretation of the original K-Ar results from Olduvai Gorge, it is still not possible to be certain that the Olduvai and Gilsáevents are separated in time. An incidental result of the survey is evidence to show that, contrary to recent suggestions by Einarsson (1972), there is no substantial hiatus between the major lower parts of the section and lavas believed to represent extrusions after a regional tilting and peneplanation.     

A simple LMS‐based approach to the structural health monitoring benchmark problem

A structure's health or level of damage can be monitored by identifying changes in structural or modal parameters. However, the fundamental modal frequencies can sometimes be less sensitive to (localized) damage in large civil structures, although there are developing algorithms that seek to reduce this difficulty. This research directly identifies changes in structural stiffness due to modeling error or damage using a structural health monitoring method based on adaptive least mean square (LMS) filtering theory. The focus is on computational simplicity to enable real‐time implementation. Several adaptive LMS filtering based approaches are used to analyze the data from the IASC–ASCE Structural Health Monitoring Task Group Benchmark problem. Results are compared with those from the task group and other published results. The proposed methods are shown to be very effective, accurately identifying damage to within 1%, with convergence times of 0.4–13.0 s for the twelve different 4 and 12 degree of freedom benchmark problems. The resulting modal parameters match to within 1% those from the benchmark problem definition. Finally, the methods developed require 1.4–14.0 Mcycles of computation and therefore could easily be implemented in real time. Copyright © 2004 John Wiley & Sons, Ltd.     

Residues of toxaphene decrease in estuarine fish after removal of contaminated sediments

To determine if toxaphene residues in edible fish tissue decreased after removal of contaminated sediments from an estuarine site in 1999, 51 composite samples representing six finfish species were collected in 2001 and analyzed using gas chromatography with electron capture and negative ion mass spectrometric detection. The grand mean total toxaphene residue concentration on a wet weight basis (ΣTOX_wet) was 1,400 ± 3,500 ng g⁻¹ (range: < 18 to 18,000 ng g⁻¹) and was positively correlated with extractable lipid. On a lipid basis, the mean ΣTOX_lip was 26 ± 33 μg g¹, which decreased with increasing distance from the study site. Although benthically-oriented species, such as spot (Leiostomus xanthurus) and striped mullet (Mugil cephalus), exhibited higher mean ΣTOX_wet than those of higher trophic level fish, mean ΣTOX_lip were not significantly different among species. The grand mean ΣTOX for 2001 was 3.8 (wet) and 2.6 (lipid) times less than corresponding preremedial action (1997) concentrations, suggesting that bioavailable toxaphene residues in this system have been reduced. Forage species, such as croaker (Micropogonias undulatus), mullet, and spot, preferentially accumulate toxaphene residues in this system and may serve as vectors of organochlorine contaminants in the estuarine and coastal ocean food web.     

Geology and geochemistry of Jurassic pelagic sediments, Scisti silicei Formation, southern Apennines, Italy

A better understanding of genesis and palaeoenvironmental setting of the Scisti silicei Formation (Lagonegro units, southern Italy) was achieved by means of geochemical analysis integrated with new stratigraphic information. Data show that major and trace element geochemistry of ancient clay-rich beds and banded cherts add new insights into the Mesozoic evolution of the Lagonegro basin. Sedimentary contributions to Jurassic shales sampled during this study were mainly derived from two major sources: (i) a dominant terrigenous fine-grained component, having affinity with average upper continental crust that had not undergone intense weathering and (ii) biogenic siliceous material. The latter component occurs in clay-rich layers from the “basal member” of the Scisti silicei Formation.

Composition varies up section and accounts for changes in the detrital supply due to bathymetric oscillations. The compositional variations from the basal to the overlying member are consistent with a distal source passing in time to a more “proximal” source, as indicated by sharp changes in the concentrations of detrital elements (Ti, Zr and Nb). It is likely that increased detrital input occurred through turbidity current deposition. Finally, the chemical features of the clay-rich layers from the upper cherty portion of the studied succession imply a progressive deepening of the basin.

The lack of any mafic and hydrothermal contributions in the Jurassic shales as well as the continental nature of detrital input suggests that the Lagonegro basin was located between two carbonate platforms, in accordance with the classical restoration of the African–Apulian palaeomargin. Thus, the basin acted as a preferential sink connected to the African cratonic areas through a southern entry point.     

Late Holocene local vegetation dynamics in the marsh of Gravgaz(southwest Turkey)

Late Holocene local vegetation succession is reconstructed in twodifferent sites in a small-scale open marsh ecosystem in southwest Turkey.This is done by comparison of the fossil local pollen assemblage zones in twocores with the local pollen data of 40 surface samples from the marsh. Thepollen data are supplemented with sedimentological and archaeological data. Theinsertion of the mean pollen data of the local pollen zones as passive samplesinto the canonical correspondence analysis triplot of the modern samples allowsus to detect modern analogues for the fossil pollen zones. From this numericalcomparative approach it is concluded that the marsh area was relatively dryuntil ca 2500 BP. After 2500 BP the area shifts towards a wet area dominated bySparganium and/or Typha angustifolia. A diversification of the marsh vegetationstarts at ca 2400/2300 BP. The area around one core site seems to have beensituated in an area with slowly flowing source water, whereas the other coresite is likely to have been characterised by damp conditions. The steadilyincreasing dryness of the marsh area starts after ca 680 BP. The drying upappears to be associated with recent agricultural and grazing pressure.     

The CM carbonaceous chondrite regolith Diepenveen

A carbonaceous chondrite was recovered immediately after the fall near the village of Diepenveen in the Netherlands on October 27, 1873, but came to light only in 2012. Analysis of sodium and poly‐aromatic hydrocarbon content suggests little contamination from handling. Diepenveen is a regolith breccia with an overall petrology consistent with a CM classification. Unlike most other CM chondrites, the bulk oxygen isotopes are extremely ¹⁶O rich, apparently dominated by the signature of anhydrous minerals, distributed on a steep slope pointing to the domain of intrinsic CM water. A small subset plots closer to the normal CM regime, on a parallel line 2 ‰ lower in δ¹⁷O. Different lithologies in Diepenveen experienced varying levels of aqueous alteration processing, being less aqueously altered at places rather than more heated. The presence of an agglutinate grain and the properties of methanol‐soluble organic compounds point to active impact processing of some of the clasts. Diepenveen belongs to a CM clan with ~5 Ma CRE age, longer than most other CM chondrites, and has a relatively young K‐Ar resetting age of ~1.5 Ga. As a CM chondrite, Diepenveen may be representative of samples soon to be returned from the surface of asteroid (162173) Ryugu by the Hayabusa2 spacecraft.     

Identification and Explanation of a Change in the Groundwater Regime using Time Series Analysis

Time series analysis is applied to identify and analyze a transition in the groundwater regime in the aquifer below the sand ridge of Salland in the Netherlands, where groundwater regime refers to the range of head variations throughout the seasons. Standard time series analysis revealed a discrepancy between modeled and observed heads in several piezometers indicating a possible change in the groundwater regime. A new time series modeling approach is developed to simulate the transition from the initial regime to the altered regime. The transition is modeled as a weighted sum of two responses, one representing the initial state of the system, the other representing the altered state. The inferred timing and magnitude of the change provided strong evidence that the transition was the result of significant dredging works that increased the river bed conductance of the main river draining the aquifer. The plausibility of this explanation is corroborated by an analytical model. This case study and the developed approach to identify a change in the groundwater regime are meant to stimulate a more systematic application of time series analysis to detect and understand changes in groundwater systems which may easily go unnoticed in groundwater flow modeling.     

The impact of climate change on the bulk and clay geochemistry of fluvial residual channel infillings: the late Weichselian and Early Holocene River Meuse sediments (The Netherlands)

Fine-grained fluvial residual channel infillings are likely to reflect systematic compositional changes in response to climate change, owing to changing weathering and geomorphological conditions in the upstream drainage basin. Our research focuses on the bulk sediment and clay geochemistry, laser granulometry and clay mineralogy of Late-glacial and Early Holocene River Meuse (Maas) unexposed residual channel infillings in northern Limburg (The Netherlands). We demonstrate that residual channel infillings register a systematic bulk and clay compositional change related to climate change on a 1–10 k-yr time-scale. Late-glacial and Holocene climatic amelioration stabilised the landscape and facilitated prolonged and intense chemical weathering of phyllosilicates and clay minerals due to soil formation. Clay translocation and subsequent erosion of topsoils on Palaeozoic bedrock and loess deposits increased the supply of smectite and vermiculite within River Meuse sediments. Smectite plus vermiculite contents rose from 30–40% in the Pleniglacial to 60% in the Late Allerød and to 70–80% in the Holocene. Younger Dryas cooling and landscape instability caused almost immediate return to low smectite and vermiculite contents. Following an Early Holocene rise, within about 5000 yr, a steady state supply is reached before 5 ka (Mid-Holocene). Holocene sediments therefore contain higher amounts of clay that are richer in high-Al, low-K and low-Mg vermiculites and smectites compared with Late (Pleni-)glacial sediments. The importance of clay mineral provenance and loess admixture in the River Meuse fluvial sediments is discussed. © 1998 John Wiley & Sons, Ltd.