Evidence for hybridisation in the Tynong Province granitoids,Lachlan Fold Belt,eastern Australia

The role of mafic–felsic magma mixing in the formation of granites is controversial. Field evidence in many granite plutons undoubtedly implies interaction of mafic (basaltic–intermediate) magma with (usually) much more abundant granitic magma, but the extent of such mixing and its effect on overall chemical features of the host intrusion are unclear. Late Devonian I-type granitoids of the Tynong Province in the western Lachlan Fold Belt, southeast Australia, show typical evidence for magma mingling and mixing, such as small dioritic stocks, hybrid zones with local host granite and ubiquitous microgranitoid enclaves. The latter commonly have irregular boundaries and show textural features characteristic of hybridisation, e.g. xenocrysts of granitic quartz and K-feldspars, rapakivi and antirapakivi textures, quartz and feldspar ocelli, and acicular apatite. Linear (well defined to diffuse) compositional trends for granites, hybrid zones and enclaves have been attributed to magma mixing but could also be explained by other mechanisms. Magmatic zircons of the Tynong and Toorongo granodiorites yield U–Pb zircon ages consistent with the known ca 370 Ma age of the province and preserve relatively unevolved ?_Hf (averages for three samples are +6.9, +4.3 and +3.9). The range in zircon ?_Hf in two of the three analysed samples (8.8 and 10.1 ?_Hf units) exceeds that expected from a single homogeneous population (～4 units) and suggests considerable Hf isotopic heterogeneity in the melt from which the zircon formed, consistent with syn-intrusion magma mixing. Correlated whole-rock Sr–Nd isotope data for the Tynong Province granitoids show a considerable range (0.7049–0.7074, ?_Nd +1.2 to –4.7), which may map the hybridisation between a mafic magma and possibly multiple crustal magmas. Major-element variations for host granite, hybrid zones and enclaves in the large Tynong granodiorite show correlations with major-element compositions of the type expected from mixing of contrasting mafic and felsic magmas. However, chemical–isotopic correlations are poorly developed for the province as a whole, especially for ⁸⁷Sr/⁸⁶Sr. In a magma mixing model, such complexities could be explained in terms of a dynamic mixing/mingling environment, with multiple mixing events and subsequent interactions between hybrids and superimposed fractional crystallisation. The results indicate that features plausibly attributed to mafic–felsic magma mixing exist at all scales within this granite province and suggest a major role for magma mixing/mingling in the formation of I-type granites.     

Air–Sea/Land Interaction in the Coastal Zone

Atmospheric turbulence measurements made at the U.S. Army Corps of Engineers Field Research Facility (FRF) located on the Atlantic coast near the town of Duck, North Carolina during the CASPER-East Program (October–November 2015) are used to study air–sea/land coupling in the FRF coastal zone. Turbulence and mean meteorological data were collected at multiple levels (up to four) on three towers deployed at different landward distances from the shoreline, with a fourth tower located at the end of a 560-m-long FRF pier. The data enable comparison of turbulent fluxes and other statistics, as well as investigations of surface-layer scaling for different footprints, including relatively smooth sea-surface conditions and aerodynamically rough dry inland areas. Both stable and unstable stratifications were observed. The drag coefficient and diurnal variation of the sensible heat flux are found to be indicators for disparate surface footprints. The drag coefficient over the land footprint is significantly greater, by as much as an order of magnitude, compared with that over the smooth sea-surface footprint. For onshore flow, the internal boundary layer in the coastal zone was either stable or (mostly) unstable, and varied dramatically at the land-surface discontinuity. The offshore flow of generally warm air over the cooler sea surface produced a stable internal boundary layer over the ocean surface downstream from the coast. While the coastal inhomogeneities violate the assumptions underlying Monin–Obukhov similarity theory (MOST), any deviations from MOST are less profound for the scaled standard deviations and the dissipation rate over both water and land, as well as for stable and unstable conditions. Observations, however, show a poor correspondence with MOST for the flux-profile relationships. Suitably-averaged, non-dimensional profiles of wind speed and temperature vary significantly among the different flux towers and observation levels, with high data scatter. Overall, the statistical dependence of the vertical gradients of scaled wind speed and temperature on the Monin–Obukhov stability parameter in the coastal area is weak, if not non-existent.     

Naturaliste Plateau: constraints on the timing and evolution of the Kerguelen Large Igneous Province and its role in Gondwana breakup

Volcanism associated with the Kerguelen Large Igneous Province is found scattered in southwestern Australia (the ca 136 to ca 130 Ma Bunbury Basalts, and ca 124 Ma Wallaby Plateau), India (ca 118 Ma Rajmahal Traps and Cona Basalts), and Tibet (the ca 132 Ma Comei Basalts), but apart from the ～70 000 km² Wallaby Plateau, these examples are spatially and volumetrically minor. Here, we report dredge, geochronological and geochemical results from the ～90 000 km² Naturaliste Plateau, located ～170 to ～500 km southwest of Australia. Dredged lavas and intrusive rocks range from mafic to felsic compositions, and prior geophysical analyses indicate these units comprise much of the plateau substrate. ⁴⁰Ar/³⁹Ar plagioclase ages from mafic units and U–Pb zircon ages from silicic rocks indicate magmatic emplacement from 130.6 ± 1.2 to 129.4 ± 1.3 Ma for mafic rocks and 131.8 ± 3.9 to 128.2 ± 2.3 Ma for silicic rocks (2σ). These Cretaceous Naturaliste magmas incorporated a significant component of continental crust, with relatively high ⁸⁷Sr/⁸⁶Sr (up to 0.78), high ²⁰⁷Pb/²⁰⁴ Pb ratios (15.5–15.6), low ¹⁴³Nd/¹⁴⁴Nd (0.511–0.512) and primitive-mantle normalised Th/Nb of 11.3 and La/Nb of 3.97. These geochemical results are consistent with the plateau being underlain by continental basement, as indicated by prior interpretations of seismic and gravity data, corroborated by dredging of Mesoproterozoic granites and gneisses on the southern plateau flank. The Cretaceous Naturaliste Plateau igneous rocks have signatures indicative of extraction from a depleted mantle, with trace-element and isotopic values that overlap with Kerguelen Plateau lavas reflect crustal contamination. Our chemical and geochronological results therefore show the Naturaliste Plateau contains evidence of an extensive igneous event representing some of the earliest voluminous Kerguelen hotspot magmas. Prior work reports that contemporaneous correlative volcanic sequences underlie the nearby Mentelle Basin, and the Enderby Basin and Princess Elizabeth Trough in the Antarctic. When combined, the igneous rocks in the Naturaliste, Mentelle, Wallaby, Enderby, Princess Elizabeth, Bunbury and Comei-Cona areas form a 136–124 Ma Large Igneous Province covering >244 000 km².     

The nature and origin of pigments in black opal from Lightning Ridge,New South Wales,Australia

Abstract

Black opal (opal-AG) owes its dark coloration to a fine-grained pigment commonly inferred to be mainly carbon, yet chemical compositions for black opals suggest there may be additional components. Here we search for such components in pigment concentrates prepared by dissolving black opal nodules (nobbies) from Lightning Ridge (NSW) in hydrofluoric acid, using electron microscopy (scanning electron microscopy, transmission electron microscopy), X-ray diffraction and laser-ablation ICP-MS. The results demonstrate the presence of sulfides—predominantly pyrite and chalcopyrite, with minor galena and Ti-oxide phases, as additional components of the pigment. ATR-FTIR analysis indicates the presence of C=O and C–H groups, consistent with an organic origin. Transmission electron microscopy images of pigment show variously deformed, originally spherical ～100?nm particles rich in sulfide and carbon, which are interpreted as thin coatings of pigment on now dissolved opaline silica spheres. Laser-ablation ICP-MS analysis identifies remnant silica in pigment concentrates, which may be interpreted as opaline silica surviving HF treatment protected as inclusions in sulfides. When examined within the context of petrographic observations from more than 1000 opal nodules (nobbies) at Lightning Ridge, these new results suggest that pigment carbon and sulfides in the nodules formed microbially under initially anoxic groundwater conditions, within pre-existing cavities concurrently being filled with silica sol ultimately derived from chemical weathering of feldspar-rich volcaniclastic sediment. Intensely black pigment layers observed at the floor of many nodules indicate settling of dark, high-density (sulfide–Ti-oxide-rich) pigment within cavities, with the implication that sulfate-reducing bacterial (SRB) activity commences early during the silica sol-gel ripening process. Microbial activity may persist until after the cavity has completely filled with the silica sol, as illustrated by abundant black opals with uniformly distributed pigment. Pigment formed at this stage may no longer be able to settle out within the ripening and increasingly viscous silica gel, thus forming pigmentation throughout the opal cavity. The existence of ‘amber’, pigment-poor opal with intensely black basal pigment layers is interpreted as signalling a lack of sulfate to sustain further SRB activity, or a change to more oxidising conditions, possibly related to interaction with surface waters within a downward-penetrating weathering front. A change in redox conditions would shut off activity of SRB and thus sulfide pigment production and allow development of aerobic microbial activity as described by others.     

Analyses of primary remanence vector data from a large collection of lava flows: towards improved methodology in paleo-geomagnetism

Research into the properties of past geomagnetic fields (paleo-geomagnetism) has been carried out worldwide for over half a century. This research utilizes rocks which are to a varying degree inadequate for that purpose, and evaluation of the results is therefore not always on firm ground. One resource which can be utilized to constrain several aspects of the interpretation of other paleo-geomagnetic data, consists of stable primary remanence vectors in large homogeneous collections of dated fresh lava flows. We outline how the available remanence data from several thousand lavas in Iceland may be analysed in a semi-quantitative way to test some of current results, methodology and concepts of paleo-geomagnetism. Among topics where such analysis provides new insights, are the geomagnetic polarity time scale, the frequency distribution of virtual geomagnetic poles in latitude and longitude, and the relative intensity of the magnetic field as a function of virtual pole latitude. Comparison of the scatter in remanence intensities and in absolute paleointensity determinations on Icelandic lavas indicates, along with other evidence, that quality criteria for the latter are in need of revising. It is also confirmed here that long-term changes have occurred in the amplitude of the geomagnetic secular variation; they should be taken into account in studies on other properties of the paleo-geomagnetic field.     

Molecular staging of marine medaka: a model organism for marine ecotoxicity study

Oryzias melastigma, also called O. dancena, is becoming a very useful model for estuarine and marine ecotoxicity studies. With O. melastigma being adopted by ILSI Health and Environmental Science Institute (HESI) for embryo toxicity testing, improved knowledge of biomarker based embryonic development becomes especially important for mechanism-based toxicity evaluations. Using whole mount in situ hybridization and immunostaining techniques together with widely used molecular markers, this study describes the molecular development of marine medaka embryos, focusing on the brain, eye, heart, pectoral fin, pancreas, liver, muscle and neuron system. These organs are targets of environmental pollutants that disrupt normal embryonic development in medaka and other fish.     

Analytical and numerical analysis of tides and salinities in estuaries; part I: tidal wave propagation in convergent estuaries

Analytical solutions of the momentum and energy equations for tidal flow are studied. Analytical solutions are well known for prismatic channels but are less well known for converging channels. As most estuaries have a planform with converging channels, the attention in this paper is fully focused on converging tidal channels. It will be shown that the tidal range along converging channels can be described by relatively simple expressions solving the energy and momentum equations (new approaches). The semi-analytical solution of the energy equation includes quadratic (nonlinear) bottom friction. The analytical solution of the continuity and momentum equations is only possible for linearized bottom friction. The linearized analytical solution is presented for sinusoidal tidal waves with and without reflection in strongly convergent (funnel type) channels. Using these approaches, simple and powerful tools (spreadsheet models) for tidal analysis of amplified and damped tidal wave propagation in converging estuaries have been developed. The analytical solutions are compared with the results of numerical solutions and with measured data of the Western Scheldt Estuary in the Netherlands, the Hooghly Estuary in India and the Delaware Estuary in the USA. The analytical solutions show surprisingly good agreement with measured tidal ranges in these large-scale tidal systems. Convergence is found to be dominant in long and deep-converging channels resulting in an amplified tidal range, whereas bottom friction is generally dominant in shallow converging channels resulting in a damped tidal range. Reflection in closed-end channels is important in the most landward 1/3 length of the total channel length. In strongly convergent channels with a single forward propagating tidal wave, there is a phase lead of the horizontal and vertical tide close to 90^o, mimicking a standing wave system (apparent standing wave).     

Design charts for elastic pile shortening in the equivalent top–down load–settlement curve from a bidirectional load test

With a rigid pile assumption, the equivalent top–down load–settlement curve constructed from the results of a bidirectional or bottom–up pile load test does not fully consider the total elastic shortening when all the load components from skin-friction and end-bearing are applied downward at the pile head. In effect, the equivalent curve constructed by the original method suggested from the Osterberg test showed a much stiffer curve compared to the top–down curve. Design charts are provided in this paper from the results of a parametric study on bored piles in order to approximately evaluate the λ-factor that is used to estimate the top–down pile shortening from the bottom–up shortening due to the skin-friction component of the load. It has been shown that the λ-factor varies with the distribution of the undrained shear strength profile, pile slenderness ratio, and mobilization of the skin-friction resistance. In addition, the pile shortening due to the end-bearing load component is added to the top settlements by treating the pile as an elastic column. A modified method for the construction of the equivalent top–down load–settlement curve is presented that considers the elastic pile shortening and validated with the measured top–down load–settlement curve from pile load tests.     

Development without Intervention: A Successful Self‐Reliance Initiative of Rural Development and Urban Growth in The Sudan

We investigate the complex relationship between small‐scale farming, urban‐rural remittances and rural development. We highlight a successful, innovative self‐reliance approach in which traditional farmers changed their mode of production, improved their income, and enhanced rural development, including urbanization, in Shubbola village of western Sudan. The major initial driver was investment from remittances by family members who had migrated to urban centers, thus overcoming the problem of access to credit/capital. Consequently, the increased use of tractor technology helped farmers overcome agricultural labor shortages, and increase their farm size and productivity. Increased income from remittances and farming broadened economic and social improvements, including lifestyle and the built environment. In the process, Shubbola has grown into a viable and vibrant town, providing its residents with diverse socioeconomic services and modern infrastructure. This case illustrates the potential of development from within with minimal direct input from the government, nongovernmental organizations, and international donors.     

Source identification of polycyclic aromatic hydrocarbons in sediments of a creek around a flow station

Sources of the sixteen polycyclic aromatic hydrocarbons (PAHs) in the United States Environmental Protection Agency priority pollutants list were determined in sediments of Kolo Creek using diagnostic ratios of parent PAHs[phenanthrene/phenanthrene + anthracene; fluoranthene/fluoranthene + pyrene; benz(a) anthracene/benz(a) anthracene + chrysene and indeno(1,2,3-d)pyrene/indeno(1,2,3-cd)pyrene + benzo(ghi)pyrelene]. The study was conducted over four seasons (dry, late dry, rainy and late rainy seasons). Applying cross plots of the diagnostic ratios revealed that PAHs in Kolo Creek sediment have pyrogenic origins except in the rainy season that had petrogenic origins. Comparison of diagnostic ratio values obtained from this study with literature values enabled the further classification into types of pyrogenic and/or petrogenic sources. While the pyrogenic sources of PAHs were mainly as a result of Grass/Wood combustion, the petrogenic PAHs were as result of drained diesel and lubricating oil. The predicted sources corresponded with the prevailing human activities in the vicinity, especially samples collected near a petrol station and an abattoir. This study further affirms the simplicity and accuracy of the use of diagnostic ratios for PAHs source prediction.