超微量钐同位素的热表面电离质谱分析

采用双带测量方式,法拉第杯和离子计数器同时接收与跳峰接收相结合,建立了超微量钐同位素的热表面电离质谱的测量方法。优化了制样程序和质谱测量程序,研究了蒸发带电流对离子流强度的影响,考察了从纳克至微克不同样品用量的测量效果及其中Nd、Eu干扰核素的情况。对4 ng~2μg的天然丰度钐样品进行了同位素比值分析,相对标准偏差均小于1.1%。     

延边闹枝铜金矿床的矿物流体包裹体特征与成矿作用研究

闹枝铜金矿床是延边内生金铜矿集区内的典型矿床之一,矿体主要为含金黄铜矿黄铁矿石英脉型。笔者运用显微测温、激光拉曼探针,对其矿物内的流体包裹体进行了系统研究。实验结果表明:①流体包裹体的类型主要为气液两相包裹体,其次为纯气相、富气相包裹体及纯液相包裹体,还有少量含子晶的多相包裹体;②流体包裹体的均一温度为150～410℃,与黄铁绢英岩、石英-黄铁矿、石英-多金属硫化物及石英方解石脉4个矿化蚀变阶段相对应的流体包裹体的均一温度分别为350～410℃、290～350℃、210～290℃、150～210℃;③流体包裹体的盐度w(NaCleq)为1.74%～20.97%,Ⅰ、Ⅱ、Ⅲ、Ⅳ矿化阶段成矿流体的盐度w(NaCleq)分别为2.396%～5.548%、2.24%～8.68%、1.74%～20.97%和6.3%;④流体包裹体的气体成分主要为H2O和CO2。结合前人的研究成果,笔者进一步确定该矿床的成矿流体具有深源岩浆热流体性质,在流体上升过程中曾发生过弱的沸腾作用,并在硫化物石英脉、多金属硫化物石英脉、方铅矿脉以及石英方解石脉形成过程中,伴有少量地下水或大气水的加入。     

Investigation of the sulfur speciation during chalcopyrite leaching by moderate thermophile Sulfobacillus thermosulfidooxidans

The surface sulfur speciation of chalcopyrite leached by moderately thermophilic Sulfobacillus thermosulfidooxidans was investigated by employing scanning electron microscopy (SEM), X-ray diffraction (XRD) and sulfur K-edge X-ray absorption near edge structure spectroscopy (XANES), accompanying with the leaching behavior elucidation. Leaching experiment showed that there was an optimum range of the redox potential for chalcopyrite dissolution. Leaching products were found accumulating during the leaching process, which might be jarosite according to the XRD analysis. The sulfur K-edge spectra indicated that chalcocite might be the intermediate sulfur compound under a critical redox potential, which might explain the existence of optimum range of the redox potential and provide an evidence for the two-step leaching model of chalcopyrite at low Eh. In addition, the results of sulfur K-edge spectra showed jarosite would accumulate on mineral surface, which might be the main component of the passivation layer.     

郯庐断裂带南段构造演化与邻区成矿作用——从年代学资料得到的启示

郯庐断裂带为我国东部北北东—北东向岩石圈深大断裂带。在其南段的邻区,分布有胶东金矿区、鲁西铁金矿区以及长江中下游的铁铜(金)成矿带和苏北油气田等矿产。从已获得大量测年资料分析,可将构造—岩浆—成矿事件分为3个阶段:1)早期(800～550 Ma):自元古宙泛古陆裂解和随之而来的加里东期古地震和局部海西期喷流作用,证实地壳运动早已拉开了它的"构造活动序幕",此阶段继承和构建了华北克拉通岩石圈先存的构造薄弱带,从成矿作用而论,此阶段可称为"成矿预备场地";2)主期(1 80～110 Ma):在三叠纪期间,扬子板块和华北板块陆—陆碰撞和中生代西太平洋板块向欧亚板块俯冲等,造就了现今郯庐断裂与分支断裂的构造格架。其中主峰形成时间为140～120 Ma±,在这个阶段广泛有钙碱性系列、富钾高锶钙碱系列、碱性系列岩浆和后期成矿热液,沿着有利构造空间剧烈活动和成矿就位。本区壳幔混熔型和壳源同熔型花岗岩,是地壳减薄和下地壳拆沉、底侵的产物,而不是单一的构造运动的结果。此阶段可称为断裂构造—岩浆活动—成矿作用的鼎盛期;3)晚期(60Ma～现代):沿东西向与北北东向(或北东向)断裂交汇处,存在橄榄玄武岩喷侵,为石油和天然气的形成提供了热源和物源,此期可称其为构造—岩浆活动的衰变期。     

东海陆架盆地伸展率和压缩率及构造跃迁

东海陆架盆地位于欧亚板块的东南缘和西太平洋活动大陆边缘,本文选取了东海陆架盆地主要凹陷的17条地震剖面,采用平衡剖面技术,计算了主要凹陷新生代不同演化阶段的伸展率和压缩率。分析表明,东海陆架盆地构造演化总体由西向东跃迁。晚白垩世至晚古新世东海陆架盆地裂陷中心在西部坳陷带,始新世东迁至东部坳陷带,上新世东迁至东海陆架盆地东侧的冲绳海槽盆地。古新世中后期东海陆架盆地西部坳陷带北侧昆山凹陷反转;中新世东部坳陷带的西湖凹陷反转。东海陆架盆地西部坳陷带与东部坳陷带构造演化不同,证明了东海陆架盆地的东西分带。西部坳陷带北部的长江坳陷和南部的台北坳陷构造演化不同,东部坳陷带北部的西湖凹陷和南部的钓北凹陷构造演化不同,证明了东海陆架盆地的南北分块。     

新疆哈图-包古图金铜矿集区锆石年龄及成矿特点

晚古生代,新疆西准噶尔地区发生了强烈的构造-岩浆活动和广泛的金、铜成矿作用,形成了哈图-包古图大型金铜矿集区。锆石SHRIMP U-Pb年龄测量表明,含矿闪长岩体形成于312.3±2.2Ma～332.0±2.8Ma,矿集区岩浆活动及其成矿作用发生在石炭纪。哈图-包古图矿集区成矿作用有4个显著特点:(1)地幔流体活动强烈;(2)构造应力转化快速;(3)拉斑系列和钙碱性系列岩浆成矿;(4)多种矿化类型集中发育等。哈图-包古图矿集区发育石英脉型-蚀变岩型金矿床、斑岩型铜矿床和同期的石英脉型-蚀变岩型金矿床以及热液脉型铜金矿床的成矿系列。     

临沂市开发区土地集约利用评价工作分析

土地集约利用评价成果对增强政府调控土地利用的能力,构建资源节约型社会,促进经济社会可持续发展都具有重要的意义。该文在分析及评价临沂市开发区土地利用现状、结构的基础上,提出了合理化建议,对促进临沂市土地可持续利用具有重要意义。     

Assessment of the risk of rockfalls in Wu Gorge, Three Gorges, China

In 2007 and 2008, six big damaging rockfalls occurred at four sites in Wu Gorge, the second gorge of the Three Gorges, China. Detailed surveys and aerial-photographic interpretation identified 104 potentially dangerous rock masses. This paper reviews previous rock-mass risk ratings, examines dangerous rock-mass structure and presents a new assessment system for rockfall risk (ASRFR) in the Wu Gorge area. The ASRFR considers 15 factors: seven factors for hazard and eight factors for consequence. Relative importance weights for these factors are ascertained using an analytic hierarchy process. Using an equation to calculate the risk, the 104 dangerous rock masses were divided into three risk groups: high risk (33 sites), medium risk (33 sites) and low risk (38 sites). The ASRFR analysis can be used to divide the shipping route through the Wu Gorge into seven courses each of one of three classes: safe-route regions, yellow-alarm regions and red-alarm regions. The system provides geological information and a rockfall-risk management tool for local government and the shipment-route department.     

测井-地震多属性密度曲线重构反演技术及应用

为了提高波阻抗反演的分辨率,在密度资料对反演结果产生重要影响的基础上,利用岩心、测井及地震资料,从岩石物理性质-测井响应-地震响应角度分析,提出应用测井-地震多属性密度曲线重构技术合成拟密度曲线,其结果用全井连续取心样品测试分析数据验证的平均误差为0.05 g/cm3.应用反演效果分析表明,反演结果吻合率从重构前的78%提高到重构后的86%,密度曲线重构反演技术提高了反演精度和分辨率.     

Implication of coupled natural and human systems in sustainable rangeland ecosystem management in HKH region

The sustainable development of rangeland ecosystems, the vital ecosystems providing many important ecosystem services for millions of people in the Hindu Kush-Himalaya region is presently confronted with a number of challenges. A coupled natural and human systems approach is needed to facilitate effective collaboration among social scientists, bio/physical scientists, and management practitioners to better understand how people interact with the environment in which they live. In pursuing this argument, three existing case studies, i.e. Indigenous rangeland management in Himalayan Nepal, Cultivated Grassland Systems in Eastern Qinghai-Tibetan Plateau, and Grassland Restoration in Central Qinghai-Tibetan Plateau were synthesized in this paper to address the importance of coupled natural and human systems in promoting sustainable rangeland ecosystem management in the Hindu Kush-Himalaya (HKH) region. It was concluded although the research sites and objectives were very different, that these three case studies had many commonalities that addressed the complex interactions and feedbacks between natural and human systems, and highlighted the integration of various tools and techniques from the ecological and social sciences, as well as other disciplines, in sustainable rangeland management. These case studies have offered unique interdisciplinary insights into complexities that cannot be gained from ecological or social research alone. The results from these case studies can be applied to many other coupled systems at local, national, and global levels.