The electrification of flowing gases by mechanical abrasion of mineral surfaces

In the past, a number of workers have shown that both charged and neutral particles are released from inorganic materials during fracture and abrasion. In this work we show that charge can be transported by electrification of flowing gases over a surface undergoing abrasion. These results are relevant to possible mechanisms of a number of observed electrical phenomena associated with fault motion and earthquake activity. Received: 14 July 1997 / Revised, accepted: 2 January 1998     

Migration and dispersion of trace elements in the rock–soil–plant system in areas underlain by black shales and slates of the Okchon Zone, Korea

The Okchon black shale in Korea provides a typical example of natural geological materials enriched with potentially toxic elements. The Chung-Joo, Duk-Pyung, Geum-Kwan, I-Won, Bo-Eun and Chu-Bu areas are underlain by these black shales and slates of the Guryongsan Formation or the Changri Formation, which are parts of the Okchon Group in the central part of the southern Korean Peninsula. In order to investigate the enrichment levels and dispersion patterns of potentially toxic elements in the rock–soil–plant system, environmental geochemical surveys were undertaken in the above six study areas in the Okchon Zone. After appropriate preparation, rock and soil samples were analyzed for potentially toxic elements by instrumental neutron activation analysis (INAA) and inductively coupled plasma atomic emission spectrometry (ICP-AES), and plant samples by atomic absorption spectrometry (AAS). In particular, Ba, Cd, Mo, V and U in Okchon black shales are highly enriched, and their mean concentrations are significantly higher than those in black slates. These elements are geochemically associated, and might be enriched simultaneously. The highest mean concentrations of 42.0 μg g⁻¹ As, 2100 μg g⁻¹ Ba, 10.9 μg g⁻¹ Cd, 213 μg g⁻¹ Mo, 83 μg g⁻¹ U, 938 μg g⁻¹ V and 394 μg g⁻¹ Zn are found in black shales from the Duk-Pyung area. Mean concentrations of As, Mo and U in soils overlying black shales occurring in the Duk-Pyung area (30 μg g⁻¹ As, 24 μg g⁻¹ Mo and 50 μg g⁻¹ U) and Chu-Bu area (39 μg g⁻¹ As, 15 μg g⁻¹ Mo and 27 μg g⁻¹ U) are higher than the permissible level. Enrichment index values of the six study areas decrease in the order of Duk-Pyung > Chu-Bu > Bo-Eun > Chung-Joo > Geum-Kwan = I-Won areas. Relationships between trace element concentrations in soils and plants are significantly correlated, and the biological absorption coefficients (BAC) in plants are in the order of Cd > Zn = Cu > Pb, which suggests that Cd is more bioavailable to plants than the other elements. Cadmium concentrations in plant species decrease in the order of chinese cabbage > red pepper > soybean = sesame > rice stalk > corn > rice grain. From the result of sequential extraction analysis of soils, relatively high proportions of Cu, Pb and Zn are present as residual fractions, and that of Cd as non-residual fractions. Cadmium occurs predominantly as exchangeable/water-acid soluble phase in soils, and this is in agreement with the findings of high Cd concentrations in plants.     

A classification system for the assessment of slope stability of terrains along highway routes in Jordan

 The establishment of comprehensive development plans, in general, and the proper selection of highway routes, in particular, require an assessment of landslides or instability hazards in the project sites. The frequent landslides that occurred along the routes of major highways in Jordan, and particularly along the Amman-Na'ur-Dead Sea highway and Irbid-Jerash-Amman highway, have substantially increased the cost of construction and caused a considerable delay in the completion of work. The study of many landslides that occurred in the last 25 years along the highway routes and in the sites of some major civil engineering projects in Jordan has led to the recognition of major factors that affect the stability of slopes, and thus the safety and economics of these projects. The geological formation, structural features, topographic characteristics, geometry, and climatic conditions were adopted as the basis for the classification of terrains in terms of their stability. Each factor has been assigned a rating to indicate its relative contribution to the overall stability according to engineering judgment and past experience. The areas have been classified into 5 groups according to their total stability rate. The simplicity, comprehensiveness, and accuracy are the main characteristics of the proposed classification. Its significance stems from its helpfulness as a guide to the geotechnical and highway engineers in assessing the overall stability of the alternative routes of proposed highway projects. Received: 3 December 1996 · Accepted: 29 April 1997     

Clustering stochastic point process model for flood risk analysis

Since the introduction into flood risk analysis, the partial duration series method has gained increasing acceptance as an appealing alternative to the annual maximum series method. However, when the base flow is low, there is clustering in the flood peak or flow volume point process. In this case, the general stochastic point process model is not suitable to risk analysis. Therefore, two types of models for flood risk analysis are derived on the basis of clustering stochastic point process theory in this paper. The most remarkable characteristic of these models is that the flood risk is considered directly within the time domain. The acceptability of different models are also discussed with the combination of the flood peak counted process in twenty years at Yichang station on the Yangtze river. The result shows that the two kinds of models are suitable ones for flood risk analysis, which are more flexible compared with the traditional flood risk models derived on the basis of annual maximum series method or the general stochastic point process theory. Received: September 29, 1997     

Incoherent scatter radar observations of AGW/TID events generated by the moving solar terminator

Observations of traveling ionospheric disturbances (TIDs) associated with atmospheric gravity waves (AGWs) generated by the moving solar terminator have been made with the Millstone Hill incoherent scatter radar. Three experiments near 1995 fall equinox measured the AGW/TID velocity and direction of motion. Spectral and cross-correlation analysis of the ionospheric density observations indicates that ST-generated AGWs/TIDs were observed during each experiment, with the more-pronounced effect occurring at sunrise. The strongest oscillations in the ionospheric parameters have periods of 1.5 to 2 hours. The group and phase velocities have been determined and show that the disturbances propagate in the horizontal plane perpendicular to the terminator with the group velocity of 300–400 m s^–1 that corresponds to the ST speed at ionospheric heights. The high horizontal group velocity seems to contradict the accepted theory of AGW/TID propagation and indicates a need for additional investigation.     

Spectral classification methods in monitoring small local events by the Israel seismic network

We use the dense Israel Seismic Network (ISN) to discriminate between low magnitude earthquakes and explosions in the Middle East region. This issue is important for CTBT monitoring, especially when considering small nuclear tests which may be conducted under evasive conditions. We explore the performance of efficient discriminants based on spectral features of seismograms using waveforms of 50 earthquakes and 114 quarry and underwater blasts with magnitudes 1.0–2.8, recorded by ISN short-period stations at distances up to 200 km. The single-station spectral ratio of the low and high-frequency seismic energy shows an overlap between explosions and earthquakes. After averaging over a subnet of stations, the resolving power is enhanced and the two classes of events are separated. Different frequency bands were tested; the (1–3 Hz)/(6–8 Hz) ratio provided the best discriminant performance. We also estimated normalized r.m.s. spectral amplitudes in several sequential equal frequency windows within the 1–12 Hz band and applied multiparametric automatic classification procedures (Linear Discrimination Function and Artificial Neural Network) to the amplitudes averaged over a subnetwork. A leave-one-out test showed a low rate of error for the multiparametric procedures. An innovative multi-station discriminant is proposed, based on spectral modulation associated with ripple-firing in quarry blasts and with the bubbling effect in underwater explosions. It utilizes a distinct azimuth-invariant coherency of spectral shapes for different stations in the frequency range (1–12 Hz). The coherency is measured by semblance statistics commonly used in seismic prospecting for phase correlation in the time domain. After modification, the statistics applied to the network spectra provided event separation. A new feature of all the above mentioned procedures is that they are based on smoothed (0.5 Hz window), instrument-corrected FFT spectra of the whole signal; they are robust to the accuracy of onset time estimation and, thus well suited to automatic event identification.     

Genesis of the Hussainiyat ironstone deposit, Western Desert, Iraq

The Hussainiyat ironstone deposit (Jurassic) is mainly pisolitic, intraclastic and concretionary in texture, associated with kaolinite mudstones and/or with quartzose sandstone. The ironstone consists mainly of goethite, hematite, kaolinite and quartz. The deposits were derived from a variety of parent rocks that included low- and medium-rank metamorphics, intermediate igneous rocks and pre-existing sediments of the Nubio-Arabian Shield. The source rocks suffered deep chemical weathering in the hinterland, and the products (Fe-oxyhydroxides, kaolinite and quartz) were later transported by rivers to the depositional site. Iron was mostly carried in association with the clay fraction and organic matter. Several genetic processes were involved in the ironstone formation. Iron concretions were mostly formed by bacterial build-up in swamps and marshes, and were subsequently embedded in kaolinitic mud. Large-scale development of groundwater laterite blanket (ferricrete) occurred later in the overbanks and floors of wadis, under oxidizing pedogenic conditions. During this stage iron was mobilized from the kaolinitic deposits and migrated upward in dry seasons and, to a lesser extent, downward in wet seasons. Pisolites and oolites grew in situ in the kaolinitic soil at the upper limit of the fluctuating water table. This ferricrete blanket had a wide and continuous extension within an elongated paleodepression. Seasonal heavy rain periods resulted in the flow of ephemeral streams and rivers, where major parts of this ferricrete was reworked and deposited with quartz sand and mud clasts as channel deposits. The original pisolitic-colloform ironstone was reworked continuously to form a semi-continuous sheet. In such wet seasons, additional Fe-enrichment took place as cementing materials or overgrowths. Received: 28 April 1995 / Accepted: 10 July 1997     

“Extreme boiling” model for variable salinity of the Hokko low-sulfidation epithermal Au prospect, southwestern Hokkaido, Japan

The Hokko prospect is located in the Minamikayabe area southwestern Hokkaido, Japan, where gold-bearing quartz veins of Pliocene age are exposed at the surface. The alteration mineral assemblage is typical of low-sulfidation epithermal systems, with the quartz veins associated with adularia alteration overprinted on Late Miocene propylitic alteration. Fluid inclusion studies of the vein quartz reveal mean homogenization temperatures of approximately 220 °C, and the co-existence of low-salinity (<2 wt.% NaCl equivalent) and moderate salinity (2 to 12 wt.% NaCl equivalent) fluid inclusions within the same veins. The moderate salinity fluid inclusions (2–12 wt.% NaCl equivalent) typically have relatively low homogenization temperatures between 150° to 200 °C. The results obtained from stable isotope analysis of  δ¹⁸O in quartz vein material showed a gradual decrease in  δ¹⁸O signatures with increasing depth. The majority of the samples have calculated fluid source signatures (δ¹⁸O_H2O) between −8.0 and −10.0‰, but there is a significant change in the composition above 185 m drill depth. The shallower samples in particular show a wide range of oxygen isotope signatures that are associated with the moderate salinity fluid inclusions. We interpret that low-salinity inclusions within the Hokko system represent the composition of the liquid phase of the fluid, before boiling, and that the moderate-salinity inclusions are representative of the residual liquid phase, after extensive non-adiabatic boiling and vapor loss in an open system. This mechanism resulted in the entrapment of fluids with variable salinities at the same time, and in close proximity to each other. This is also reflected in the  δ¹⁸O_H2O values which become more variable and heavier where the moderate-salinity inclusions occur. Deposition of ore minerals within the Hokko vein system also occurred at this time as a result of boiling and gas loss. Received: 30 May 1997 / Accepted: 6 January 1998     

A study of transient variations in the Earth’s electromagnetic field at equatorial electrojet latitudes in western Africa (Mali and the Ivory Coast)

In the framework of the French-Ivorian participation to the IEEY, a network of 10 electromagnetic stations were installed at African longitudes. The aim of this experiment was twofold: firstly, to study the magnetic signature of the equatorial electrojet on the one hand, and secondly, to characterize the induced electric field variations on the other hand. The first results of the magnetic field investigations were presented by Doumouya and coworkers. Those of the electric field experiment will be discussed in this study. The electromagnetic experiment will be described. The analysis of the electromagnetic transient variations was conducted in accordance with the classical distinction between quiet and disturbed magnetic situations. A morphological analysis of the recordings is given, taking into consideration successively quiet and disturbed magnetic situations, with the results interpreted in terms of the characterization of external and internal sources. Particular attention was paid to the effects of the source characteristics on the induced field of internal origin, and to the bias they may consequently cause to the results of electromagnetic probing of the Earth; the source effect in electromagnetic induction studies. During quiet magnetic situations, our results demonstrated the existence of two different sources. One of these, the S_R^E source, was responsible for most of the magnetic diurnal variation and corresponded to the well-known magnetic signature of the equatorial electrojet. The other source (the S_R*^E source) was responsible for most of the electric diurnal variation, and was also likely to be an ionospheric source. Electric and magnetic diurnal variations are therefore related to different ionospheric sources, and interpreting the electric diurnal variation as induced by the magnetic field diurnal variation is not relevant. Furthermore, the magnetotelluric probing of the upper mantle at dip equator latitudes with the electromagnetic diurnal variation is consequently impossible to perform. In the case of irregular variations, the source effect related to the equatorial electrojet is also discussed. A Gaussian model of equatorial electrojet was considered, and apparent resistivities were computed for two models of stratified Earth corresponding to the average resistive structure of the two tectonic provinces crossed by the profile: a sedimentary basin and a cratonic shield. The apparent resistivity curves were found to depend significantly on both the model used and the distance to the center of the electrojet. These numerical results confirm the existence of a daytime source effect related to the equatorial electrojet. Furthermore, we show that the results account for the observed differences between daytime and night-time apparent resistivity curves. In particular, it was shown that electromagnetic probing of the Earth using the classical Cagniard-Tikhonov magnetotelluric method is impossible with daytime recordings made at dip latitude stations.